第十二章醛酮不飽和ppt課件

1、HOROOCH3CHOOHCH3OHOHCH3OOHHORRORCH2CH3OCH3OCH3酸催化CH2CH3OCH3OCH3堿催化CH2CH3OHCH3O-CH2OH-CH-CH3OCH2CH2-CH3OOH2CH3CH3OCH2CH3OCH3OHCH2CH3OH+CH2HCH2-CH3OH+CH3CH3OH+H+CH2CH3OCH3CH3OCH3CH3abCH3OCH3CH3COHCH3CHCHC-Na+CH3OCH3CH3CH3OHCH3CH3LiOCH3LiOCH3C-Na+HORHCNRHOCNHORRHOCNC-NRHO-CNOH2RCH-HOCNONaHSO3ONaO3SCH3O

2、CH3R2NHCH3CH3ONR2HORClHRROClCH3OCH3CH3CuLiCH3CH3CH3CH3OOROHRMgClCH3OCH3RMgClCH3CH3ORCu+CH3OCH3CH3CH3OHNaBH4CH3OCH3CH3CH3OHLiAlH4CH3OCH3CH3CH3OPd/CH2CH3OCH3CH3CH3OLi/NH3CH3OCH3CH3OCH3H2NiCH3OCH3CH3OHCH3H2NiCH3CH3CH3COOHOCH3CH3OHCHCH3CH3ABCH3CH3CH3OCH3CH3CH3CH3CHCH3CH3CDCH3CH3CH3COOHOCH3CH3OHCHCH3CH3A

3、BCH3CH3CH3OCH3CH3CH3CH3CHCH3CH3CDCH3CH3OCH3CH2O-KHCH3CH3OCH3CH3OCH3O-OH2CH3CH3OCH3CHNCH3CH3OCH3CNOH3+CH3CH3OCH3COOHCH3CH3OCH3CH2O-KHCH3CH3OCH3CH3OCH3O-OH2CH3CH3OCH3CH3CH3O-CH3CH3OH3+CH3CH3OHCH3CH3LiCH3CH3CH3OCH3CH2O-KHCH3CH3OCH3CH3OCH3O-OH2CH3CH3OCH3OH3+CH3CH3CH3OCH3CH3CH3OCH3CH3MgClCH3Mg+Cl-H5C2OC2

4、H5Ag+CH3CH3OCH3CH2O-KHCH3CH3OCH3CH3OCH3O-OH2CH3CH3OCH3CH3CH3O-CH3CH3LiCH3CH3CH3ClCH3CH3SOCl2LiCH3CH3CH3CH3CH3CH3OOOO對苯醌對苯醌 p-quinone p-quinone 鄰苯醌鄰苯醌o-quinoneo-quinone或或1 1，4-4-苯醌苯醌 或或1 1，2-2-苯醌苯醌OO2 2，6-6-萘醌萘醌2,6-naphthoquinone2,6-naphthoquinoneOOOO9 9，10-10-蒽醌蒽醌Anthra-9,10-quinoneAnthra-9,10-quino

5、ne9 9，10-10-菲醌菲醌Phenanthrene-Phenanthrene-9,10-dione9,10-dionenaphthalene-2,6-dioneOOH2SO3OHOH對亞硝基苯酚4-nitrosophenolOOH2NOHNOOHNOOH對苯醌單肟 P-quinone mono-oximeOOHXOHOHXOOHXOOClHOHOHClOOHCl2-chloro-1,4-benze diolOOHCNOHOHCNOOHCNOOOCH3HOHOHOCH3OOHOCH3對苯醌和甲醇的反響對苯醌和甲醇的反響OORMgBrOROHOHOHROOOHOHROOROHOHnCH3CHOOHCH3OHOHCH3OOHCH3CHOOHNH2NHRCH3NNHRNNHRCH3CHOOHCH3OHCOOH+HIO4CH3OOHCH3OOHCH2O+HIO4HIO4CH3CHOOHCH3CHOCH3CH3OOHCH3OCH3OHCH3OOHOCH3OHOHO HOHO HFe2+OOHOOHCHOCN-RCHON+SRRROOHRCOOEtNaRRONaONaH+CH3CH3OOHOHOHOCH3OH 鄰-羥基苯甲醛水楊醛 對-羥基苯乙酮OHOH