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ReactionsofCarbon

NucleophileswithCarbonyl

CompoundsProf.YueChen(陳悅)Oct.31th,2019

ReactionsofCarbon

Nucleophi12.4.1.1.OlefinationReactionsInvolvingPhosphoniumYlides2.4.1.1.OlefinationReactions22.4.1.1.OlefinationReactionsInvolvingPhosphoniumYlides2.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions2.4.1.1.OlefinationReactions32.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.Wadsworth-Emmonsreaction-UsuallyEisomerformed2.4.1.2.OlefinationReactions42.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactions52.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactions62.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactions72.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactions82.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactions92.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactions102.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompoundsPetersonreaction2.4.2.Reactionsof-Trimethyl112.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompounds2.4.2.Reactionsof-Trimethyl122.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompounds2.4.2.Reactionsof-Trimethyl132.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompounds2.4.2.Reactionsof-Trimethyl142.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompounds2.4.2.Reactionsof-Trimethyl152.4.3.TheJuliaOlefinationReaction2.4.3.TheJuliaOlefinationR162.4.3.TheJuliaOlefinationReaction2.4.3.TheJuliaOlefinationR172.4.3.TheJuliaOlefinationReaction2.4.3.TheJuliaOlefinationR182.5.ReactionsProceedingbyAddition-Cyclization2.5.ReactionsProceedingbyA192.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat202.5.1.SulfurYlidesandRelatedNucleophiles2.1.2.5.1.SulfurYlidesandRelat212.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat222.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat232.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat242.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat252.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat262.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat272.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat282.5.1.SulfurYlidesandRelatedNucleophiles2.5.2.NucleophilicAddition-Cyclizationof-Haloesters2.5.1.SulfurYlidesandRelat292.5.2.NucleophilicAddition-Cyclizationof-Haloesters2.5.2.NucleophilicAddition-C302.6.ConjugateAdditionbyCarbonNucleophiles2.6.1.ConjugateAdditionofEnolates2.6.ConjugateAdditionbyCar312.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE322.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE332.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE342.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE352.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE362.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE372.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE382.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE392.6.2.ConjugateAdditionwithTandemAlkylation2.6.2.ConjugateAdditionwith402.6.3.ConjugateAdditionbyEnolateEquivalents2.6.3.ConjugateAdditionbyE412.6.3.ConjugateAdditionbyEnolateEquivalentsAtendencytofavorantidiastereoselectivity,regardlessofthesilylenoletherconfiguration2.6.3.ConjugateAdditionbyE422.6.3.ConjugateAdditionbyEnolateEquivalents2.6.4.ControlofFacialSelectivityinConjugateAdditionReactions2.6.3.ConjugateAdditionbyE432.6.4.ControlofFacialSelectivityinConjugateAdditionReactions2.6.4.ControlofFacialSelec442.6.4.ControlofFacialSelectivityinConjugateAdditionReactions2.6.4.ControlofFacialSelec452.6.4.ControlofFacialSelectivityinConjugateAdditionReactions2.6.4.ControlofFacialSelec462.6.4.ControlofFacialSelectivityinConjugateAdditionReactions2.6.4.ControlofFacialSelec472.6.4.ControlofFacialSelectivityinConjugateAdditionReactions2.6.4.ControlofFacialSelec482.6.4.ControlofFacialSelectivityinConjugateAdditionReactions2.6.4.ControlofFacialSelec492.6.5.ConjugateAdditionofOrganometallicReagents2.6.5.ConjugateAdditionofO502.6.6.ConjugateAdditionofCyanideIon2.6.6.ConjugateAdditionofC512.6.6.ConjugateAdditionofCyanideIon2.6.6.ConjugateAdditionofC52docin/sanshengshiyuandoc88/sanshenglu

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ReactionsofCarbon

NucleophileswithCarbonyl

CompoundsProf.YueChen(陳悅)Oct.31th,2019

ReactionsofCarbon

Nucleophi542.4.1.1.OlefinationReactionsInvolvingPhosphoniumYlides2.4.1.1.OlefinationReactions552.4.1.1.OlefinationReactionsInvolvingPhosphoniumYlides2.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions2.4.1.1.OlefinationReactions562.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.Wadsworth-Emmonsreaction-UsuallyEisomerformed2.4.1.2.OlefinationReactions572.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactions582.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactions592.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactions602.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactions612.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactions622.4.1.2.OlefinationReactionsInvolvingPhosphonateAnions.2.4.1.2.OlefinationReactions632.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompoundsPetersonreaction2.4.2.Reactionsof-Trimethyl642.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompounds2.4.2.Reactionsof-Trimethyl652.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompounds2.4.2.Reactionsof-Trimethyl662.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompounds2.4.2.Reactionsof-Trimethyl672.4.2.Reactionsof-TrimethylsilylcarbanionswithCarbonylCompounds2.4.2.Reactionsof-Trimethyl682.4.3.TheJuliaOlefinationReaction2.4.3.TheJuliaOlefinationR692.4.3.TheJuliaOlefinationReaction2.4.3.TheJuliaOlefinationR702.4.3.TheJuliaOlefinationReaction2.4.3.TheJuliaOlefinationR712.5.ReactionsProceedingbyAddition-Cyclization2.5.ReactionsProceedingbyA722.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat732.5.1.SulfurYlidesandRelatedNucleophiles2.1.2.5.1.SulfurYlidesandRelat742.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat752.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat762.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat772.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat782.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat792.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat802.5.1.SulfurYlidesandRelatedNucleophiles2.5.1.SulfurYlidesandRelat812.5.1.SulfurYlidesandRelatedNucleophiles2.5.2.NucleophilicAddition-Cyclizationof-Haloesters2.5.1.SulfurYlidesandRelat822.5.2.NucleophilicAddition-Cyclizationof-Haloesters2.5.2.NucleophilicAddition-C832.6.ConjugateAdditionbyCarbonNucleophiles2.6.1.ConjugateAdditionofEnolates2.6.ConjugateAdditionbyCar842.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE852.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE862.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE872.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE882.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE892.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE902.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE912.6.1.ConjugateAdditionofEnolates2.6.1.ConjugateAdditionofE922.6.2.ConjugateAdditionwithTandemAlkylation2.6.2.ConjugateAdditionwith932.6.3.ConjugateAdditionbyEnolateEquivalents2.6.3.ConjugateAdditionbyE942.6.3.ConjugateAdditionbyEnolateEquivalentsAtendencytofavorantidiastereoselectivity,regardlessofthesilylenoletherconfiguration2.6.3.ConjugateAdditionbyE952.6.3.ConjugateAdditionbyEnolateEquivalents2.6.4.ControlofFacialSelectivityinConjugate

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