化學(xué)品安全知識(shí)培訓(xùn)

化學(xué)品安全知識(shí)培訓(xùn)It’spreventingaccidentsandinjurieswhileusingchemicalsintheworkplace.在工作場(chǎng)所使用化學(xué)品時(shí)防止事故及傷害的發(fā)生。什么是化學(xué)品安全?4maintypesofchemicals四種主要類型的化學(xué)品3waystobeexposedinchemicalshazards三種可能暴露途徑HowdoIknowwhattherisksare?了解危害所在Containerlabels容器標(biāo)簽MaterialSafetyDataSheets(MSDS)物質(zhì)安全數(shù)據(jù)表Colorandnumbercodedlabelsystem顏色和數(shù)字編號(hào)標(biāo)簽系統(tǒng)Knowingthechemicalriskandhazards,takethenecessarystepsandsafeguardstopreventfromgettinghurt了解化學(xué)品危險(xiǎn)性和危害，采取必要措施和安全裝置來(lái)預(yù)防受傷AlwayswearyourPPE一直佩戴合適PPESafetyworkpractices安全工作實(shí)務(wù)Followsafetyworkpractices跟蹤它們Knowemergencyprocedure明了緊急處理程序Helpcontrolchemicalhazards協(xié)助控制化學(xué)品危害Topic討論話題4MainTypes

ofChemicals

四種主要類型的化學(xué)品

canputyouatrisk...

可以使你處于危險(xiǎn)之中…Thesedestroybodytissues-eyes,respiratorysystemandskin-oncontact.通過接觸,會(huì)損害人體組織部-眼睛,呼吸系統(tǒng)和皮膚腐蝕性的Thesearepoisonsthatcancauseillnessordeath.這些是可能致病或致死的毒物.有毒試劑Theseliquidsandgasescatchfireeasilyandburnquicklyorexplode.這些液體和氣體極易著火,燃燒迅速和爆炸可燃的或易燃的Thesechemicalsburn,explodeorgiveofftoxicgasesifdropped,heatedormixedwithcertainothersubstances.跌落,加熱或與其它某種物質(zhì)混合,這些化學(xué)品會(huì)燃燒,爆炸或釋放有毒氣體.反應(yīng)性的三種可能暴露于化學(xué)品危害的途徑?

INHALEDintheformofdust,gasorvapors以粉塵,氣體或蒸汽的形式吸入.?SWALLOWED-especiallyifyoueatorsmokearoundchemicals.吞入-尤其當(dāng)你在化學(xué)品周圍吃東西或抽煙時(shí)?

ABSORBEDthroughtheskinorsplashedintotheeyes通過皮膚或?yàn)R入眼睛而吸收

HowdoIknowwhatthe

RISKSare?

我怎樣知道危害是什么?ContainerLabels

容器標(biāo)簽Tellyou:告訴你:TheChemical’sIdentity化學(xué)品的身份

-itsnameortradename名字或商品名

PhysicalHazards物理危害

-ifthechemicalisexplosive,corrosive,etc..此化學(xué)品是否是爆炸性的,腐蝕性的,等等..TheDegreeofRisk危險(xiǎn)程度

-asignalwordsuchas“CAUTION!”,“WARNING”or“DANGER!”willtellyou.(“DANGER!”indicatesthemostseverhazard,“CAUTION!”theleast.)一個(gè)信號(hào)詞,如“注意!”,“警告”或“危險(xiǎn)!”會(huì)告訴你.(“危險(xiǎn)”表明危害嚴(yán)重,“注意”最輕.

HealthHazards健康危害

-ifthechemicaliscancer-causing,toxic,radioactive,etc..表明此化學(xué)品是否致癌,有毒或放射性的

Precautionstotake需采取的措施

-howtoavoidinjuryorillness,suchas“washthoroughlyafterhandling”,or“useonlyinawell-ventilatedroom”.如何避免傷害或疾病,如“接觸后徹底洗手”,或“在通風(fēng)良好的房間里使用“

HowtoHandle,StoreandDisposeofChemicals

如何處置,儲(chǔ)藏和處理化學(xué)品.safemethodsandPPEtouseduringtheseprocedures.在這些操作中的安全方法及PPE.SpecialSymbols特殊標(biāo)識(shí)arealsousedonmanylabelstohelpyourecognizethekindofhazardthechemicalcouldpresentifyou’renotcareful.被用于許多標(biāo)簽上,可幫助你識(shí)別由于不小心而導(dǎo)致的化學(xué)品危害的種類.You’llfindthesesymbolsonlabelsofcontainersthathavebeenshippedbytruck,rail,orair.你會(huì)在由卡車,火車或飛機(jī)運(yùn)輸?shù)娜萜魃系臉?biāo)簽上找到這些圖案SpecialSignalWords

特殊標(biāo)識(shí)文字areusedonmanylabelstotellyouquicklyhowdangerousthechemicalcouldbe.用于許多標(biāo)簽上,很快告訴你化學(xué)品可能有多危險(xiǎn).Thecommonsignalwordsandtheirmeaningsare:常用標(biāo)識(shí)文字極其含義如下:DANGER

-cancauseimmediateseriousinjuryordeath.危險(xiǎn)品-可導(dǎo)致立即嚴(yán)重傷害或死亡WARNING

-cancausepotentiallyseriousinjuryordeath.警告-可導(dǎo)致潛在的確傷害或死亡.CAUTION

-cancausepotentiallymoderateinjuryordeath.注意-可導(dǎo)致潛在的中度傷害或死亡.Hereisalistofsomeofthehealthhazardsyoumightfindonachemicallabel:以下是一些健康危害的列表,你可能在某一化學(xué)品標(biāo)簽上找到:ó

Carcinogen 致癌物質(zhì)ó

Highlytoxicagent高毒性試劑ó

Sensitizer敏化剤 ó

Hepatotoxin肝毒素ó

Nephrotoxin腎毒素 ó

Neurotoxin神經(jīng)毒素ó

Reproductivehazard生殖系統(tǒng)危害 ó

Irritant刺激物ó

Corrosive腐蝕劑Manyofthesetermsmaysoundverytechnical.ConsultMSDS,oraskyoursupervisororsafetypersonifyouhavequestions.許多這些專業(yè)術(shù)語(yǔ)可能聽起來(lái)很專業(yè).若有問題,查看MSDS,或咨詢你的主管或安全人員.PrecautionaryStatements

預(yù)防性申明Alabelmayalsotellyouwhatyoushoulddotoavoidproblems.Herearesomeexamples:標(biāo)簽可能也告訴你需做什么來(lái)避免問題.這兒有一些例子:

Donotbreathevaporsfromthisproduct.不要吸入這個(gè)產(chǎn)品的蒸汽

Useonlyinwell-ventilatedareas.只在通風(fēng)良好的情況下使用.Washthoroughlywithsoapafterhandling.接觸后用肥皂徹底洗手.Keepawayfromsparks,heat,andflame.遠(yuǎn)離火星,熱源和火源.Donotstorenearcombustiblematerials.不要將其儲(chǔ)藏在可燃材料附近.Keepcontainerclosedwhennotinuse.不用時(shí)保持容器密閉.Avoidcontactwithskin.避免皮膚接觸.Storeintightlyclosedcontainer.儲(chǔ)存在緊閉的容器中.Removeandwashcontaminatedclothingpromptly.及時(shí)脫去并清洗污染的衣物.Keepfromcontactwithclothingandothercombustiblematerials.避免與衣物或其它可燃物接觸.MATERIALSAFETYDATASHEETS

物質(zhì)安全數(shù)據(jù)表（MSDS）MaterialSafetyDataSheets(MSDS)aredesignedtohelpusunderstandhowtoworksafelywithchemicals.MSDS’swillhaveapproximately8to10sectionswhichexplaintheproperwaystouse,handleandstorechemicals.物質(zhì)安全數(shù)據(jù)表被用來(lái)幫助我們?nèi)绾伟踩靥幚砘瘜W(xué)品.MSDS大概會(huì)有8~10段,用來(lái)解釋使用,搬運(yùn)和儲(chǔ)藏化學(xué)品的正確的方法.MSDS’sprovideinformationregardingthehealthhazardsassociatedwiththeuseofchemicals,theprecautionarymeasurestofollow,andtheemergencyproceduresforspills,andfirstaid.MSDS’s提供與使用化學(xué)品有關(guān)的健康危害的信息,需遵循的預(yù)防措施,針對(duì)泄漏的緊急程序和緊急救護(hù).

ChemicalIdentification

化學(xué)品識(shí)別

Theintroductorysectionofthe MaterialSafetyDataSheets (MSDS)includesthechemicalmanufacturer’snameandemergencynumber,addressandemergencyphonenumber,thechemicalname,tradename,andchemicalformula.ThissectionhelpsyouidentifythechemicalontheMSDS.MSDS中的介紹部分包括化學(xué)品制造商,緊急號(hào)碼,地址和緊急電話,化學(xué)品名稱,商標(biāo),以及化學(xué)方程式.這部分幫助你識(shí)別MSDS上的化學(xué)品.Howtouseandunderstand

MaterialSafetyDataSheets

如何使用和理解MSDSHazardousIngredients有害成分Thissectionlistsanyhazardousingredientsfoundwithinthechemicalthatcanbehazardoustoyou.Inthissection,youmightalsoseethetermsTLV(ThresholdLimitValue)andPEL(PermissibleExposureLimit).這部分列出此化學(xué)品中所有的有害成分,同時(shí)，你有可能看到這些術(shù)語(yǔ)：TLV（閾值濃度限）和PEL（容許暴露限）。HazardousIngredients有害成分Bothtermsareusedtoexpresstheairborneconcentrationlevelsofachemicaltowhichmostpersonscanbesafelybeexposedduringanormalworkday.Anotherterm,C.A.S.(ChemicalAbstractSafety),willusuallybelistedinthissectionoftheMSDS.TheC.A.S.numbersidentifyspecificchemicalsaccordingtoinformationpublishedbytheAmericanChemicalSociety.這倆個(gè)術(shù)語(yǔ)是用來(lái)表示在一個(gè)正常工作日中，大多人能夠被允許接觸的空氣中所含化學(xué)品的濃度，在這個(gè)濃度范圍內(nèi)，人身是安全的.另一個(gè)術(shù)語(yǔ)是C.A.S(化學(xué)品文摘服務(wù))它通常被列入MSDS中,C.A.S碼通過美國(guó)化學(xué)協(xié)會(huì)發(fā)表的相關(guān)信息來(lái)定義特定的化學(xué)品.

PhysicalData

物性數(shù)據(jù)

Thissectionlistssuchimportant physicalpropertiesofthechemical asboilingpoint,vapordensity, percentvolatile,appearanceandodor,andothers.Thisinformationhelpsdeterminethedegreeofhazardsassociatedwiththechemicalindifferentworkenvironments.此章節(jié)列出化學(xué)品的一些重要物理性質(zhì)，譬如，沸點(diǎn)、蒸氣密度、揮發(fā)度、外觀、氣味及其它。這些信息幫助我們定義化學(xué)品在不同工作環(huán)境中的危害程度。PhysicalData物性數(shù)據(jù)Forexample,vapordensitydescribestheweightofavaporrelativelytoanequalvolumeofair(air=1).Ifachemicalhasavapordensityofgreaterthan1,thevaporwillbeheavierthanairandtendstofallandhugtheground.舉例來(lái)說，蒸氣密度描述的是相對(duì)于同樣體積的空氣（空氣密度=1）某種蒸氣的重量。如果說某個(gè)化學(xué)品的蒸氣密度大于1,此蒸氣會(huì)比空氣重，易于下沉，緊貼地面。Fire&ExplosionData消防和爆炸數(shù)據(jù)Thissectionhelpsyoudeterminethechemical’sflashpoint,whichisthetemperatureatwhichachemicalwillreleaseenoughflammablevaportoignite.Chemicalsthatigniteatorabove60oCareclassifiedascombustible;thosethatignitebelow60oCareclassifiedasflammable.此部分將幫助你了解化學(xué)品的閃點(diǎn)，在此溫度（閃點(diǎn)）下，化學(xué)品將揮發(fā)出足夠的可燃性蒸氣，導(dǎo)致著火。化學(xué)品在60攝氏或以上溫度自燃被稱為可燃的，在60攝氏以下被稱為易燃化學(xué)品。Fire&ExplosionData消防和爆炸數(shù)據(jù)Inaddition,thissectionusuallyliststhechemical’supperandlowerflammabilitylimits,propertypesofextinguishingmediarequiredtosafelyextinguishthefire(exampleCO2,water,foam,etc.),specialfirefightingprocedures,andanyunusualfireandexplosionhazardsassociatedwiththechemical.另外，此部分通常列有化學(xué)品爆炸上下限、合適的滅火介質(zhì)種類（例如，二氧化碳型、水型、泡沫型等等），特殊的滅火程序，和不常見的消防以及其它與該化學(xué)品相關(guān)聯(lián)的爆炸危害性。HealthHazardData健康危害數(shù)據(jù)Thissectiondescribesthehealtheffectsassociatedwithbeingoverexposedtothechemicalthroughingestion,inhalation,andskinoreyecontact.此部分描述的是某種化學(xué)品通過吞入、吸入、皮膚或眼睛接觸對(duì)健康的影響。HealthHazardData

健康危害數(shù)據(jù)Theinformationmayinclude:theacuteandchroniceffectsofoverexposuretothechemical,whetherthechemicalisknowncarcinogen,emergencyandfirstaidprocedurestofollowincaseofoverexposure,whetheroverexposuremayrequireimmediatemedicalattention,andmedicalconditionswhichmaybeaggravateduponcontactwiththechemical.Ifyouworkinanareawhereoverexposureislikely,safetyequipmentmaybeneededtoprotectyou.信息可能包括：過度暴露于某化學(xué)品（所產(chǎn)生的）急性和慢性影響。該化學(xué)品是否會(huì)致癌，應(yīng)急處置和急救程序是否被遵守以免過度暴露，過度暴露（后）是否需要進(jìn)行立即醫(yī)學(xué)觀察，以及可能的醫(yī)療禁忌，如果你的工作區(qū)域有暴露于化學(xué)品的可能性，（我們）可以用安全裝置來(lái)保護(hù)。

ReactivityData反應(yīng)性數(shù)據(jù)Theinformationcontainedinthissectionhelpsyoutodetermineifthechemicalwillreactwithotherchemicalsorconditions.Chemicalsthatarereactive(unstable)mayexplode,burnorreleasetoxicsubstancesundercertainconditions.該章節(jié)所包含的信息會(huì)幫助你了解該化學(xué)品是否會(huì)和其它化學(xué)品反應(yīng)或其反應(yīng)條件?？煞磻?yīng)的（不穩(wěn)定的）化學(xué)品在某種條件下可能爆炸、燃燒、釋放出有毒氣體。ReactivityData反應(yīng)性數(shù)據(jù)Inaddition,thissectionusuallytellsyouifthechemicalisstableorunstableandlistsanychemicalsorsubstancesthatmightbeincompatiblewiththechemical.另外,這部分通常會(huì)告訴你此化學(xué)品是否穩(wěn)定或與此化學(xué)品不相容的物質(zhì)。

SpillorLeakProcedures溢出或泄漏程序

Thissectionliststheproceduresto followwhenachemicalis accidentallyreleasedorspilled.Itwillalsocovertypesofclean-upandprotectiveequipmentneededtosafelycontainorcleanupaspillaswellasproperwaystodisposeofthechemical.此部分列出當(dāng)化學(xué)品意外釋放或溢出時(shí)應(yīng)遵循的程序。并包含為了安全地收集或清除泄漏所需的清除和保護(hù)設(shè)備以及處置化學(xué)品的正確方法。SpecialProtectionInformation特殊的保護(hù)信息Thissectionliststhetypesofspecialprotectiveequipment(respirators,gloves,eyeprotection,ventilation)thatisrecommendedtobeusedwhenworkingwiththechemical.這部分列出當(dāng)處理化學(xué)品時(shí)被推薦使用的特殊的保護(hù)設(shè)備（呼吸器，手套，眼睛保護(hù)及通風(fēng)）。SpecialProtectionInformation

特殊的保護(hù)信息Remember,therearevarioustypesofprotectiveequipmentthatarespeciallydesignedforcertaintasks.Consultwithyoursupervisortoensureyouareusingthecorrecttypefortheworkyouareperforming.記住，不同類型的保護(hù)設(shè)備被設(shè)計(jì)用于特定的任務(wù)。咨詢你的主管以確保你在將正確的保護(hù)設(shè)備用于你的工作中。SpecialPrecautions特殊的預(yù)防措施Thelastsectionusuallydiscussesspecialprecautionstobetakenduringhandlingandstorageofthechemical.AlsothislastsectionwillusuallydiscussanyotherhealthorsafetyconcernsthathavenotalreadybeenmentionedinothersectionoftheMSDS.最后部分通常討論在處置和儲(chǔ)存化學(xué)品時(shí)所需采取的特殊預(yù)防措施。并且這部分會(huì)討論在MSDS的其它部分未討論的任何其它的關(guān)于健康和安全的擔(dān)憂。顏色和數(shù)字CLASSIFICATIONANDCLASSLABELSFORHAZARDOUSSUBSTANCESSS286:PART1:1984

分類與標(biāo)識(shí)有害物質(zhì)Asystemofclassificationforhazardoussubstancesandaseriesofcautionlabelscorrespondingtothedesignatedclassesandsubdivisionsforuseinlandtransportationandstorage.是一個(gè)對(duì)有害物質(zhì)分類的系統(tǒng)，和根據(jù)指定的分類（進(jìn)行的）一系列警示標(biāo)識(shí)，以及陸地運(yùn)輸和存儲(chǔ)中使用的細(xì)則。Tofacilitatetheidentificationofhazardoussubstancesandthehazardsassociatedwiththeirtransport,handling,storageanddisposal,soastoreducetheriskoflife,healthandpropertyarisingfromthehazardouspropertiesofthegoods.為減少對(duì)生命、健康的危害和所導(dǎo)致的財(cái)產(chǎn)損失，要推進(jìn)人們對(duì)于有害物質(zhì)的認(rèn)識(shí)，以及在運(yùn)輸、使用、存儲(chǔ)和處理方面的危害。CLASSIFICATIONANDCLASSLABELSFORHAZARDOUSSUBSTANCESSS286:PART1:1984

分類與標(biāo)識(shí)有害物質(zhì)Labelsforhazardoussubstances

accordingtoclass

根據(jù)分類來(lái)標(biāo)識(shí)有害物質(zhì)Class1Explosives分類1爆炸物Classes1.1to1.5inaccordancewiththenatureofthehazard.Class2Gases:compressedordissolvedunderpressure分類2氣體：壓縮的和液化的2.1Flammablegases可燃?xì)怏w2.2Non-flammablegases非可燃?xì)怏w2.3Poisonous(toxic)gases有毒氣體Labelsforhazardoussubstances

accordingtoclass根據(jù)分類來(lái)標(biāo)識(shí)有害物質(zhì)Class3FlammableLiquids分類3可燃液體3.1Lowflashpointgroupofliquids

低閃點(diǎn)液體3.2Intermediateflashpointgroupofliquids中度閃點(diǎn)液體3.3Highflashpointgroupofliquids

高閃點(diǎn)液體3Labelsforhazardoussubstances

accordingtoclass根據(jù)分類來(lái)標(biāo)識(shí)有害物質(zhì)Class4Flammablesubstances分類4可燃固體(otherthanthoseofClasses1,2,3and5.2)

4.1Flammablesolids可燃固體4.2Substancesliabletospontaneouscombustion自燃物質(zhì)4.3Substanceswhich,oncontactwithwater,emitflammablegases接觸水能釋放可燃?xì)怏w的物質(zhì)Labelsforhazardoussubstances

accordingtoclass根據(jù)分類來(lái)標(biāo)識(shí)有害物質(zhì)Class5OxidizingAgents分類5氧化劑5.1Oxidizingagents(otherthanorganicperoxides)

氧化物劑（非有機(jī)過氧化物）5.2Organicperoxides

有機(jī)過氧化物L(fēng)abelsforhazardoussubstances

accordingtoclass根據(jù)分類來(lái)標(biāo)識(shí)有害物質(zhì)Class6Poisonous(toxic)orInfectiousSubstances分類6毒性物質(zhì)或傳染性物質(zhì)6.1Toxicsubstances

毒性物質(zhì)6.2Infectioussubstances

傳染性物質(zhì)Labelsforhazardoussubstances

accordingtoclass根據(jù)分類來(lái)標(biāo)識(shí)有害物質(zhì)Class7RadioactiveSubstances分類7放射性物質(zhì)CategoryI-White類別1-白色CategoryII-Yellow類別2-黃色CategoryIII-Yellow類別2-黃色Categoriesinaccordancewiththelevelofradiationemittedfromthecontainer根據(jù)放射物從容器輻射等級(jí)來(lái)分類Labelsforhazardoussubstances

accordingtoclass根據(jù)分類來(lái)標(biāo)識(shí)有害物質(zhì)Class8CorrosiveSubstances分類8腐蝕物質(zhì)Labelsforhazardoussubstances

accordingtoclass根據(jù)分類來(lái)標(biāo)識(shí)有害物質(zhì)NFPAHAZARDINDENTIFICATIONSYSTEM國(guó)家防火協(xié)會(huì)（美）危險(xiǎn)標(biāo)識(shí)體系TheNFPAsymbolforasubstancegivesquickvisualindicationofthedegreeofhazardassociatedwiththatsubstanceinthefieldsofhealth,flammabilityandreactivity.Italsoprovidesforanindicationofcertainotherspecialhazardswhichmaybeassociatedwithasubstance.某物的NFPA符號(hào)提供與該物有關(guān)的關(guān)于健康、可燃性、反應(yīng)性的非常直觀的危害等級(jí)指示，也會(huì)提供其相關(guān)聯(lián)物質(zhì)的某些特別危害性指示。HEALTH健康4Toodangeroustoentervapororliquid極其有害－不能接觸其氣體和液體3Extremelydangerous-Usefullprotectiveclothing非常有害－全面保護(hù)服2Hazardous-UsebreathingApparatus有害－戴呼吸器1Slightlyhazardous輕微有害0Likeordinarymaterial類似普通物質(zhì)3

FLAMMABLE可燃性4Extremely 2Igniteswhenflammable moderately

極其易燃

heated適度加熱即燃3Ignitesatnormal 1Mustbepreheatedtemperatures

toburn須預(yù)熱才致燃常溫即可點(diǎn)燃

0

Willnotburn

不能燃燒43REACTIVITY反應(yīng)性

4

Maydetonate-Vacateareaifmaterialsareexposedtofire可能引爆－撤離火區(qū)

3Strongshockorheatmaydetonate–Usemonitorsfrombehindexplosionresistantbarriers強(qiáng)烈震動(dòng)或加熱可引爆－在爆炸隔離欄外使用檢測(cè)器2Violentchemicalchangepossible-Usehosestreamsfromdistance可能有劇烈化學(xué)反應(yīng)－遠(yuǎn)距離使用水龍頭（撲火）1Unstableifheated-Usenormalprecautions加熱不穩(wěn)定－普通預(yù)防0Normallystable一般穩(wěn)定WAvoiduseofwater避免用水NFPASystemGuideforHazardousMaterialsNFPA體系有關(guān)于危害物的指導(dǎo)OXY423TheWHITEpartofthelabelishandleddifferentlyoneach:NFPA-typelabels在每份NPFA型標(biāo)簽的白色區(qū)域標(biāo)注有所不同WHITE=SpecificHazard白色＝特殊危害OXY =oxidizer氧化劑ACID =Acid酸ALK =Alkali堿COR =corrosive腐蝕物W =usenowater

不可用水

=Radioactive

放射物ExamplesofNFPASystemNPFA體系舉例CalciumCarbide Benzene電石苯NFPAHAZARDINDENTIFICATIONSYSTEM國(guó)家防火協(xié)會(huì)（美）危險(xiǎn)標(biāo)識(shí)體系HAZCHEMEMERGENCYACTIONCODESS286:PART3:1984危險(xiǎn)化學(xué)品標(biāo)識(shí)系統(tǒng)（英）緊急措施代碼TheHAZCHEMsystemisusedforconveyinginformationtoemergencyservicesinconnectionwiththetransportandhandlingofhazardoussubstances.

危險(xiǎn)品化學(xué)品標(biāo)簽系統(tǒng)用來(lái)傳達(dá)在傳輸和處理有害物質(zhì)時(shí)相關(guān)的緊急措施信息Thesystemprovidesforcorrectimmediateresponseactionintheeventoffireorspillagesoastominimizethehazardstopeopleandthelocalenvironment.該體系提供在發(fā)生火災(zāi)或泄漏時(shí)，為將對(duì)人員及地區(qū)環(huán)境的危害降至最低所需采取的正確和立即的響應(yīng)行為HAZCHEMEMERGENCYACTIONCODESS286:PART3:1984HAZCHEM緊急措施代碼800600DIETHYLAMINE二乙基胺11542YEINEMERGENCYDIAL999POLICEorFIREBRIGADEDUPONT(S)FIBRESPTELTDTEL:8694646SPECIALISTADVICEHAZCHEM危險(xiǎn)化學(xué)品標(biāo)識(shí)代碼UNNo.聯(lián)合國(guó)代碼39038010PVRSSTTWVXYYZZEVVFULLBABAforFIREonlyBABAforFIREonlyBAforFIREonlyBAforFIREonlyBABAFULLDILUTE稀釋CONTAIN堵漏CONSIDEREVACUATION考慮撤離UNNo.Hazchem1234JETS噴氣式FOG噴霧式FOAM泡沫式DRYAGENT干粉式FORFIREORSPILLAGE為消防與泄漏HazchemScaleHAZCHEM劃分NotesforGuidance

指導(dǎo)性注釋FOG噴霧Intheabsenceoffogequipmentafinespraymaybeused.缺乏噴霧器時(shí)，可使用細(xì)噴霧（來(lái)滅火）DRYAGENT干粉Watermustnotbyallowedtocomeintocontactwiththesubstanceatrisk.一定不能讓水接觸到危險(xiǎn)品。V劇烈的（反應(yīng)）Canbeviolentlyorevenexplosivelyreactive.能夠發(fā)生猛烈甚至爆炸性反應(yīng)FULL全面（保護(hù)）FullbodyprotectiveclothingwithBA.用帶呼吸設(shè)備的防護(hù)服進(jìn)行全面身體保護(hù)BA呼吸設(shè)備Breathingapparatusplusprotectivegloves.呼吸器外加防護(hù)手套DILUTE稀釋Maybewashedtodrainwithlargequantitiesofwater可用大量水沖洗至排水溝CONTAIN堵漏Preventbyanymeansavailable,spillagefromenteringdrainsorwatercourses.盡可能阻止泄漏至排水溝或（任何）水系統(tǒng)里CONSIDEREVACUATION考慮撤離Thisisthefirstpriority.Incaseofdoubtevacuateimmediatevicinityandrequestpoliceassistance.撤離會(huì)被優(yōu)先考慮，假設(shè)有所懷疑，立即撤離至附近地區(qū)，請(qǐng)求警方協(xié)助。TransportEmergencyCard運(yùn)輸應(yīng)急卡片IsaQUICKandSHORTinformationandinstructionforhandlingoftransportemergency.是一份快速和簡(jiǎn)明的信息，也是運(yùn)輸中緊急事件處置的指導(dǎo)TransportEmergencyCard

運(yùn)輸應(yīng)急卡片MATERIALIDENTIFICATION:DMAc物品名：二甲基乙胺ACETAMIDE,N,N-DIMETHYL乙酰胺DIMETHYLACETAMIDE二甲基乙胺MSDSDU000262UNno.NA, NANo.1993Colorless,clearliquid無(wú)色透明液體Faintammoniacalodour有窒息性氨味Class6.1(b)類別6.1（b)Date日期:22May19926NatureofHazard Combustible.Flushpoint:63degreeC.危害性質(zhì) Burningmayproduceobnoxiousandtoxicfumes Harmfulifinhaledorabsorbedthroughskin. Maycauseeyeandskinirritation.

易燃，閃點(diǎn)：63攝氏度，燃燒會(huì)產(chǎn)生難聞和有毒氣體吸入或經(jīng)由皮膚吸收有害，可刺激皮膚與眼睛。ProtectiveDevices Wearappropriateequipmenttopreventskin防護(hù)設(shè)備 andeyecontact:穿適當(dāng)防護(hù)設(shè)備以保護(hù)皮膚與眼睛

Chemicalsplashgogglesorfulllengthfaceshield. Butylgloves,apronandboots. Approvedrespiratorequippedwithorganicvapour catridgesiftherearespills. Ifspillsarebig(morethan20litre),useself-contained breathingapparatus

化學(xué)防濺護(hù)目鏡或全面罩，丁基橡膠手套，圍裙與靴子有有機(jī)氣體泄漏的地方要戴適當(dāng)?shù)膸в杏袡C(jī)氣體濾盒呼吸器，若有大量泄漏（超過20升），使用自攜式呼吸器。

EmergencyAction應(yīng)急措施

Stopthevehicleandengine.車輛勿進(jìn)，熄火

Nonakedlights.Nosmoking.無(wú)裸露照明燈，禁止吸煙

Markroadsandwarnotherroadusers.道路標(biāo)示，在其它道路設(shè)立警示標(biāo)牌

Wearprotectiveequipment.戴保護(hù)設(shè)備

Keeppublicawayfromdangerarea.使人員遠(yuǎn)離危險(xiǎn)區(qū)域

Keepupwind.（人員）處于上風(fēng)口Spillage泄漏

Useappropriatepersonalprotectiveequipment.使用適當(dāng)個(gè)人保護(hù)設(shè)備

Dikespillwithsand,earthorotherappropriatemeans.用沙子，泥土或其它適當(dāng)方法筑堤

Absorbwithsandorothernon-combustiblematerialandtransfertocoveredsteeldrumsforrecoveryordisposal.Flushawayremainingtraceswithwater.用沙子或其它不燃物吸收，再轉(zhuǎn)移至有蓋鐵桶以回收或進(jìn)一步處理。用水沖洗污染痕跡。

Storage儲(chǔ)存

Storeinwell-ventilatedarea.儲(chǔ)于良好通風(fēng)處

Keepcontainertightlyclosed.使容器密閉

Awayfromfoodanddrink.遠(yuǎn)離實(shí)物及飲料Fire消防

Allunprotectedpeopleshouldbefarremovedfromtheareaandupwind.所有沒有保護(hù)人員須遠(yuǎn)離此區(qū)域并處于上風(fēng)口

Wearself-containedbreathingapparatus.戴自攜式呼吸器FirstAid急救

Ifinhaled,removetofreshair,ifnotbreathing,giveartificialrespiration.Ifbreathingdifficult,giveoxygen.若吸入，移至新鮮空氣處。若不呼吸，實(shí)施人工急救。如果呼吸困難，給氧

Incaseofskinoreyecontact,washimmediatelywithwaterforatleast15minutes.CallPhysician.假設(shè)皮膚或眼睛有接觸，用水沖洗15分鐘，叫醫(yī)護(hù)人員。KnowingtheChemicalRiskandHazards…了解化學(xué)品危險(xiǎn)性及危害TaketheNecessaryStepsandSafeguardsToPreventFromGettingHurt采取必要措施與安全裝置來(lái)阻止（被）傷害It’syour“firstlineofdefense”againstchemicalhazards!這是你防止化學(xué)品傷害的第一道防線一直佩戴個(gè)人保護(hù)設(shè)備Yourjobmayrequire你工作中可能需要:

safetyglasseswithsideshields,有側(cè)面罩的安全眼睛

chemicalgoggles,化學(xué)護(hù)目鏡

orafaceshieldormask.面罩或面具

gloves手套

safetyshoesorboots安全鞋或靴子

aprons,coveralls,labcoatsorsuitsanapprovedrespirator-eitherair-purifyingorair-supplying.圍裙，防護(hù)服，實(shí)驗(yàn)服,合適的呼吸器－帶濾盒或自供空氣UsePPEthatfitsandthat’sappropriateforthehazardsyouface!

使用適當(dāng)PPE來(lái)保護(hù)你的臉以免受到傷害InspectPPE檢查PPEbeforeandafteruse.Checkfordirt,tearsandscratches.Replaceasneeded.使用前與使用后，檢查是否有污漬，破損，劃痕，需要時(shí)更換MaintainPPEPPE的維護(hù)byfollowingthemanufacturer’sinstructionsforaclean,dryareadesignatedforPPE依據(jù)供應(yīng)商的指導(dǎo)，為PPE指定一個(gè)清潔干燥的區(qū)域.Ifyouwanttohandleflammablessafely,minimizetheirfiredanger.安全地處理易燃品，要將火災(zāi)隱患降至最低

安全工作實(shí)務(wù)C

PPE個(gè)人保護(hù)設(shè)備

Besuretowearproper

protectiveclothingwhenhandlingflammableliquids.

確保在處理可燃液體穿戴合適的防護(hù)服

w

SafetyGoggles

安全防護(hù)鏡

-protecteyesfromsplashingorsprayingliquids,fumes.

保護(hù)眼睛以防被潑濺，霧蒸或煙薰安全工作實(shí)務(wù)w

LongSleevesandPants長(zhǎng)袖和長(zhǎng)褲

-protectskinfrompossibletoxiceffectsofflammableliquids.

保護(hù)皮膚以防可燃液體有毒w

GlovesandSpecialCreams手套和特殊面霜

-protect

handsfromchemicalirritation保護(hù)手以防化學(xué)刺激w

ProperWorkShoes合適的工作鞋

-giveyoumoresecurefooting,protectfeet.給你更安全的腳步保護(hù)安全工作實(shí)務(wù)NOTE注解:Removeclothingifyouspillorsplashflammableliquidonit.Flushskinwithwaterbeforeputtingonfreshclothing.Checkwithsupervisortofindoutifyoushouldreporttotheinfirmary.若衣服被潑或?yàn)R到可燃液體，脫下它，在穿上干凈衣服前沖洗你的皮膚。與你主管一起決定你是否需要報(bào)告醫(yī)方（以進(jìn)一步處理）安全工作實(shí)務(wù)C

FireExtinguishers滅火器

Knowwhichtypetousefortheflammablesyouhandle:usingthewrongtype(aninthewrongdirection)canspreadthefire.在處置易燃品時(shí)需知道哪種滅火器合適：類型用錯(cuò)（指導(dǎo)錯(cuò)誤）會(huì)助長(zhǎng)火勢(shì)。C

Ventilation通風(fēng)

Mixandhandleflammablesinwell-ventilatedareas.

在通風(fēng)良好的地方混料與處理易燃品安全工作實(shí)務(wù)CMixing混料

Mixflammableswithotherchemicalsonlywhenyou’resurethatit’ssafe.

在確信安全的前提下，再將易燃化學(xué)品與其它化學(xué)品混合。C

Grounding接地

Usegroundingwireswhenyoutransferflammables(pouringflammablescanproducestaticelectricitythatignitesthevapors).在傳送可燃物時(shí)使用接地線（流動(dòng)的易燃物會(huì)產(chǎn)生靜電，此靜電能夠點(diǎn)燃可燃物的揮發(fā)蒸氣。安全工作實(shí)務(wù)CNoSmoking禁止吸煙

Don’tsmoke,weld,cut,grind,ordoanythingthatproducesheatorsparksaroundflammables.在易燃品周圍不要吸煙、電焊、切割、碾磨、或進(jìn)行任何可產(chǎn)生熱/火花的作業(yè)。安全工作實(shí)務(wù)SafeWorkPracticesWhenWorkingWithSolvents

與溶劑打交道時(shí)的安全工作實(shí)務(wù)tKeepyourhandsawayfromyoureyeswhenusingsolvents.

使用溶劑時(shí)勿讓手碰及眼睛tKnowthelocationofthenearesteyewashstations.Incaseofexposure,flusheyesforatleast15minutestopreventpossiblelossofsight.了解最近洗眼器的位置，萬(wàn)一被濺，沖洗眼睛15分鐘以免有可能的失明tUseventilationsystems,fans,fumehoods,andotherengineeringcontrolsthathelptokeepyourexposurewithinsafelimits.使用通風(fēng)系統(tǒng)，風(fēng)扇，煙罩，以及其它一些工程控制來(lái)幫助你在安全范圍內(nèi)工作。tEvenwithgloveson,don’tputyourhandsintoasolvent.Usethetoolsprovided(awirebucket,tongs)todippartsintothesolvent.即使戴了手套，也不能將手伸進(jìn)溶液中，使用所提供的一些工具（金屬篩，夾具）將東西浸泡在溶液中。tWashyourhandswithsoapandwater(orskincleanser)aftereachshiftandbeforeyoueatorsmoke.每次完成任務(wù)后、吃飯或吸煙前要用肥皂和水（或皮膚清洗液）洗手Usethe3ARule:AlwaysAddAcidstowater

(notviceversa)whenmixingthemtoprevent

splashing,heatandboilingover.

使用3A規(guī)則：混合時(shí)總是加酸到水中（反之不行）以防潑濺、過熱和沸騰。Keepyourhandsawayfromyoureyeswhen

workingaroundcorrosives,andknowwhere

thenearesteyewashstationsareinyourworkarea.

在腐蝕物周圍工作注意不能讓手碰到眼睛，了解工作場(chǎng)所最近的洗眼器位置。SafeWorkPracticesWhenWorkingWithCorrosives

與腐蝕物打交道的安全工作實(shí)務(wù)

§Replaceyourcanisterorcartridgeasinstructed,anduseanyventilationsystemsorfansprovidedforyoursafety.根據(jù)指導(dǎo)更換你的濾毒罐或過濾盒使用任何提供安全的通風(fēng)系統(tǒng)或風(fēng)扇§Don’tcutorweldonmetalstillwetwithcorrosive:itmaycauseabreathinghazard.金屬上沾著濕的腐蝕物時(shí)不要進(jìn)行切割或焊接。這可能會(huì)導(dǎo)致呼吸危害?！霥ippartsslowlytopreventsplashes(no“slamdunking”).浸泡物體時(shí)要輕放以免濺出。（不要大手大腳）§Mixallcorrosivesslowly.混合時(shí)要慢§Washyourhandswithsoapandwater(ormildskincleanser)aftereachshiftandbeforeyoueatorsmoke.

每次完成任務(wù)后、吃飯或吸煙前要用肥皂和水（或皮膚清洗液）洗手FollowSAFEWORKPRACTICES!跟蹤安全工作實(shí)務(wù)StoringandDisposingofChemicals化學(xué)品存儲(chǔ)與處理Useonlyapprovedcontainers只使用被核準(zhǔn)的容器fortransportingorstoringchemicals.Makesurethey’relabeledproperly.為了運(yùn)輸或存儲(chǔ)化學(xué)品，需確認(rèn)它們被貼上合適的標(biāo)簽Storechemicalsinapproved,ventilatedareas在通風(fēng)處存儲(chǔ)經(jīng)核準(zhǔn)的化學(xué)品-awayfromheat,moistureandsunlight.遠(yuǎn)離熱量，潮濕及光線Closecontainersimmediately隨手蓋緊容器afteruse.使用后Don’tblockventilationductsorpipes不要堵塞通風(fēng)道或通風(fēng)管withchemicalcontainers給予化學(xué)容器通風(fēng)ChecktheMSDS檢查MSDStofindoutifit’ssafetostorespecificchemicalsnexttoeachother.每次找出是否能安全存儲(chǔ)下一個(gè)其它化學(xué)品Disposeofchemicalssafely安全處理化學(xué)品accordingtoapprovedproceduresonly.只能根據(jù)經(jīng)核準(zhǔn)了的程序（處理）Dispensehazardousliquidscarefully小心配制有害液體-useapproveddispensingdevicesandnozzles,anddripcansortraysasneeded.使用被許可的配制設(shè)備、噴嘴、盛漏桶或托盤，如果需要的話。FollowSAFEWORKPRACTICES!跟蹤安全工作實(shí)務(wù)Don’trelyonyoursenseofsmell不要依賴嗅覺totellyouifairbornechemicalsaredangerous.來(lái)辨別空氣里的化學(xué)品是否