江蘇省泄漏檢測與修復(fù)(LDAR)實(shí)施技術(shù)的指南

1省泄漏檢測與修復(fù)（）實(shí)施技術(shù)指南號），1

適圍用輸點(diǎn)無項(xiàng)目2

規(guī)引文3

術(shù)和義油油產(chǎn)發(fā)VOCs）線10Pa101.3kPa）260℃/

3.4有OHAPs響和。液0.3VOCs組20%的液VOCs物料封體漏口閥道備漏控制濃泄漏泄/

LDAR。校參％響VOCs濃的恢復(fù)VOCs讀的所需難/險面以外2致檢凈mol/mol（ppmv）。環(huán)mol/mol（ppmv）。4LDAR項(xiàng)建檢圖（PID析產(chǎn)品VOCs)的含于重量96.3kPa，/

備）錄同一操作ZL-0227。PIDID漏測展LDAR的VOCs定量檢OHAPs組2.5前測得的在(。/

4.3.2含μmol/mol2％4.3.3/蒸一/蒸一次4.3.4檢或大5點(diǎn)1所示25數(shù)低于3裝置邊界檢測位置1環(huán)境本底/

10cm/s2倍儀現(xiàn)設(shè)備表冒滴漏表列；/影表1：(單位，以)

漏4.4.1有檢后5業(yè)4.4.2/

4.4.3日）漏密VOCs排放量大于6月測4.5.1用前濃4.5.2-校/10%施LDAR項(xiàng)5目量證控管管LDAR質(zhì)量體5.2數(shù)/

數(shù)據(jù)2年：、所表3。、設(shè)、設(shè)。、不。、所、企圖無、企施前泄施LDAR后泄漏VOCs與、所、采6LDAR項(xiàng)目申2、、表6，環(huán)境月10/

表A：VOCs和OHAPsCAS號

英文名

化學(xué)品

沸點(diǎn)（℃

蒸氣壓（20℃下，Pa

VOCsOHAPs1,1,1-trichloroethan71-55-61,1,1-三氯乙烷74.013055.56√√e1,1,2-trichloroethan79-00-51,1,2-三氯乙烷113.72351.98√√e1,2,3-Trichlorobenze87-61-61,2,3-三氯苯218-21932.63√√ne1,2-dichloroethane107-06-21,2-二氯乙烷83.48219.95√√(EDC)122-66-7106-99-0123-91-1540-84-179-46-983-32-975-07-060-35-575-05-898-86-2107-02-879-06-179-10-7107-13-1107-05-162-53-371-43-298-07-7100-44-792-52-4542-88-175-25-275-15-056-23-579-11-8

1,2-Diphenylhydrazine1,3-Butadiene1,4-Diethyleneoxide2,2,4-Trimethylpentane2-NitropropaneAcenaphtheneAcetaldehydeAcetamideAcetonitrileAcetophenoneAcroleinAcrylamideAcrylicacidAcrylonitrileAllylchlorideAnilineBenzeneBenzotrichlorideBenzylchlorideBiphenylBis(chloromethy1)etherBromoformCarbondisulfideCarbontetrachlorideChloroaceticacid

1,2-二苯肼1,3-丁二烯1,4二惡烷2,2,4-三甲基戊烷2-硝基丙烷苊乙醛乙酰胺乙腈苯乙酮丙烯醛丙烯酰胺丙烯酸丙烯腈3-氯丙烯苯胺苯三氯化芐芐基氯聯(lián)苯雙氯甲醚三溴甲烷二硫化碳四氯化碳一氯乙酸

229-4.5131.799.238119-122231.220.4221.1581.6201.753231.7116.477.341.6184.380.1219-223179.4255.2182.414946.276.5189

4.54E-02238833.783905.945107.681732.221.2099156.724.049568.5335.9229485.540.166372.0811447.1140226.0142.749945.2343.76123.101.692951.24538.2439237.8712057.8018.58

√√√√√√√√√√√√√√√√√√√√√√√√√

√√√√√√√√√√√√√√√√√√√√√√√√/

108-90-767-66-3126-99-8

ChlorobenzeneChloroformChloroprene

氯苯三氯甲烷2-氯1,3-二烯

131.761.159.1

1197.9019416.3423499.98

√√√

√√√Cresolandcresylic108-39-4間甲酚202.214.22√√acid(m-)106-44-598-82-877-78-1

Cresolandcresylicacid(p)CumeneDimethylsulfate

對-酚異丙基苯硫酸二甲酯

201.9152.392188

8.25436.1261.77

√√√

√√√Epichlorohydrin106-89-8(l-Chloro-2,3-epoxypropane)

環(huán)氧氯丙烷116.11655.43√√140-88-5100-41-475-00-3106-93-4107-21-175-21-875-34-3

EthylacrylateEthylbenzeneEthylchlorideEthylenedibromideEthyleneglycolEthyleneoxideEthylidenedichloride(1.l-Dichloroethane)

丙烯酸乙酯乙苯氯乙烷1,2-二溴乙烷乙二醇環(huán)氧乙烷亞乙基二氯(1,1-氯乙烷)

100136.18612.2130.2197.210.3183.70

3909.83950.87133708.041346.057.57145672.5724288.18

√√√√√√√

√√√√√√√50-00-087-68-367-72-1110-54-378-59-1108-31-667-56-1

FormaldehydeHexachlorobutadieneHexachloroethaneHexanelsophoroneMaleicanhydrideMethanol

甲醛六氯丁二烯六氯乙烷正己烷異佛爾酮馬來酸酐甲醇

-19.5231185.6121.24215.2119.364.6

440037.9919.6161.9416214.8840.8833.6412758.04

√√√√√√√

√√√√√√√78-93-3

Methylethylketone

甲乙酮(丁酮)202

9970.24

√

√(2-Butanone)108-10-1Methylisobutylketone(Hexone)

甲基異丁基酮94.21966.95√√624-83-9

Methylisocyanate

基異氰酸鹽3549747.50

√

√80-62-61634-04-4

MethylmethacrylateMethyltert-butyl

甲基丙烯酸甲酯100.3甲基叔丁基醚55.2

3915.4426768.56

√√

√√ether74-83-9Methylbromide(Bromomethane)74-87-3Methylchloride(Chloromethane)

溴甲烷3.5183474.29√√氯甲烷-24.3492691.51√√/

75-09-2Methylenechloride(Dichloromethane)

二氯甲烷39.846735.69√√121-69-7

N,N-dimethylaniline

N,N-二甲基苯胺193.5

66.20

√

√68-12-2

N,N-dimethylformamid

N,N-二甲基甲酰

153

372.03

√

√e

胺98-95-395-48-7

Nitrobenzeneo-Cresoland

硝基苯鄰甲酚

210.6191

22.1725.87

√√

√√cresylicacid95-47-6106-46-7127-18-4

o-xylenep-DichlorobenzenePerchloroethylene

鄰二甲苯對-氯苯四氯乙烯

144.411174.1121.1

647.14166.401870.84

√√√

√√√108-95-275-44-5106-50-3

PhenolPhosgenep-Phenylenediamine

苯酚氯代甲酰氯對苯二胺

181.88.2267.4

47.45158376.420.34

√√√

√√√57-57-8

Propiolactone(beta-)丙酯

162

158.43

√

√123-38-6

Propionaldehyde

丙醛

47.93

34003.01

√

√78-87-5

Propylenedichloride1,2-二氯丙烷

96.3

16723.19

√

√75-56-9106-42-3100-42-579-34-5

Propyleneoxidep-xylenesStyreneTetrachloroethanes

環(huán)氧丙烷對二甲苯苯乙烯1,1,2,2-四氯乙

34.3138.351145.14146.20

58030.90874.56592.25436.03

√√√√

√√√√烷108-88-379-01-6121-44-8108-05-475-01-476-13-1

TolueneTrichloroethyleneTriethylamineVinylacetateVinylchloride1,1,2-Trichlorotrifl

甲苯三氯乙烯三乙胺醋酸乙烯酯氯乙烯氟利昂-113

110.62587.289.573-13.447.5

2887.937688.747125.3111932.88339701.7635856.15

√√√√√√

√√√√√uoroethane96-18-41,2,3-trichloropropane120-82-11,2,4-Trichlorobenzene108-70-31,3,5-Trichlorobenzene

1,2,3-三氯丙烷156.8355.31√1,2,4-三氯苯211.440.43√1,3,5-三氯苯211.349.92√107-88-0106-98-9109-67-1104-76-7

1,3-butyleneglycol1-butene1-pentene2-ethylhexanol

1,3-丁二醇正丁烯1-戊烯2-乙基己醇

207-6.2629.968184.6

1.53255858.4870783.2910.54

√√√√/

2807-30-92-propoxy-ethano105-57-7Acetal

乙二醇單丙醚1,1-二乙氧基乙

258.2103.6

294.592732.41

√√烷64-19-7108-24-767-64-175-86-575-36-574-86-2107-18-698-83-9111-41-1

AceticacidAceticanhydrideAcetoneAcetonecyanohydrinAcetylchlorideAcetyleneAllylalcohola-methylstyreneAminoethylethanolami

乙酸乙酸酐丙酮丙酮氰醇乙酰氯乙炔丙烯醇α-甲基苯乙烯羥乙基乙二胺

117.913956.2167.351-84.054.3165-169215.98

1559.41330.4224390.56104.7730793.484328141.932537.19252.440.11

√√√√√√√√√ne628-63-7110-58-7543-59-9100-66-3100-52-765-85-0100-47-0100-51-698-87-3100-46-9108-99-6107-92-6106-31-0109-74-0105-60-2558-13-475-45-675-72-9

amylacetateAmylamineAmylchlorideAnisoleBenzaldehydeBenzoicacidBenzonitrileBenzylalcoholBenzyldichlorideBenzylamineb-picolineButyricacidButyricanhydrideButyronitrileCaprolactamCarbontetrabromideChlorodifluoroethaneChlorotrifluorometha

乙酸戊酯1-氨基戊烷1-氯戊烷苯甲醚苯甲醛苯甲酸苯甲腈苯甲醇二氯芐芐胺3-甲基吡啶丁酸丁酸酐丁腈己酰胺四溴化碳一氯二氟甲烷氯三氟甲烷

149.2105.5107-108153.6178.7250191204.699214185143.5163.27198.3118180181.2-40.826.8

330.723018.553356.58344.88110.263.58E-0171.426.6648.2259.32587.6784.9824.271959.200.5085.65893928.813178608.49

√√√√√√√√√√√√√√√√√√ne80-15-9Cumenehydroperoxide

過氧化羥基異丙苯

253.73.49E-01√506-77-4110-82-7108-93-0108-94-1110-83-8108-91-8

CyanogenchlorideCyclohexaneCyclohexanolCyclohexanoneCyclohexeneCyclohexylamine

氯化氰環(huán)己烷環(huán)己醇環(huán)己酮環(huán)己烯環(huán)己胺

13.880.738159.6155.682.979134.5

134561.5510367.1965.46345.049295.60990.80

√√√√√√/

111-78-4112-30-1123-42-275-71-8

CyclooctadieneDecanolDiacetonealcoholDichlorodifluorometh

1,5-環(huán)辛二烯1-癸醇甲基戊酮醇氟里昂-

125230168.1-29.8

479.236.22E-01162.33560905.07

√√√√ane101-83-7111-46-6

DicyclohexylamineDiethyleneglycol

二環(huán)己胺二甘醇

256.1246

2.824.39E-01

√√112-36-7

Diethyleneglycol

二乙二醇二乙醚190.2

47.30

√diethylether111-96-6

Diethyleneglycol

二乙二醇二甲醚159.8

281.95

√dimethylether112-15-2

Diethyleneglycol

乙二醇一甲醚221.8

13.14

√monoethylether112-15-2Diethyleneglycolmonoethylether

乙二醇一甲醚162.713.14√111-77-3

Diethyleneglycol

二乙二醇單甲醚226.927

14.84

√monomethyl75-37-6674-82-875-18-367-68-5101-84-825265-71-

DifluoroethaneDiketeneDimethylsulfideDimethylsulfoxideDiphenyloxideDipropyleneglycol

1,1-二氟乙烷二乙烯酮二甲基硫二甲基亞砜二苯醚一縮二丙二醇

-25106.638189.0258230.5

563101.621055.4653488.0956.543.752.72

√√√√√√864-17-560-29-7141-78-6141-97-974-96-475-04-7105-56-674-85-1

EthanolEtherEthylacetateEthylacetoacetateEthylbromideEthylamineEthylcyanoacetateEthylene

乙醇乙醚乙酸乙酯乙酰乙酸乙酯溴乙烷乙胺氰乙酸乙酯乙烯

78.334.4873.9236.338.316.5206.0-103.71

5830.290.589632.1771.8751046.70114501.225.056261415.60

√√√√√√√√107-07-3

Ethylenechlorohydrin2-氯乙醇

128.6

692.93

√111-55-7

Ethyleneglycol

乙二醇二乙酸酯168

5.68

√diacetate110-71-4Ethyleneglycoldimethylether

乙二醇二甲醚637916.43√111-15-9Ethyleneglycolmonethylether111-76-2Ethyleneglycolmonobutylether

乙二醇乙醚醋酸酯乙二醇單丁醚

156.4217.71√151.57977.60√/

110-80-5Ethyleneglycolmonoethylether109-86-4Ethyleneglycolmonomethylether

乙二醇單乙醚221499.68√乙二醇甲醚124.6853.24√107-15-375-12-764-18-698-01-156-81-5

EthylenediamineFormamideFormicacidFurfuralGlycerol

乙二胺甲酰胺甲酸糠醛甘油

117.2210.5100.6161.898.3

1162.754.954402.66208.581.17E-02

√√√√√629-11-8124-09-4

Hexamethyleneglycol1,6-己二醇Hexamethylenediamine1,6-己二胺

239.7226.4

7.01E-0210.00

√√74-90-8123-92-278-83-1110-19-0115-11-778-84-279-31-225339-17-

HydrogencyanideIsoamylacetateIsobutanolIsobutylacetateIsobutyleneIsobutyraldehydeIsobutyricacidIsodecanol

氰化氫乙酸異戊酯異丁醇乙酸異丁酯異丁烯異丁醛異丁酸異癸醇

25.7142.0107.8116.8-6.967.1154.7213.4

81251.18510.23947.811766.52262095.5818299.20167.341.62

√√√√√√√√778-78-478-79-567-63-0108-21-475-29-675-31-0463-51-4108-42-9108-41-8541-73-1141-79-7

IsopentaneIsopreneIsopropanolIsopropylacetateIsopropylchlorideIsopropylamineKetenem-chloroanilinem-chlorotoluenem-dichlorobenzeneMesityloxide

2-甲基丁烷異戊二烯異丙醇乙酸異丙酯2-氯丙烷異丙胺乙烯酮3-氯苯胺3-氯甲苯1,3-二氯苯4-甲基-烯

303482.288.235-3648.6-56227.8161.6173132.7

76218.3360574.734409.226199.0858495.5762683.391214927.625.58307.50206.041085.48

√√√√√√√√√√√-2-酮79-41-4563-47-3

MethacrylicacidMethallylchloride

甲基丙烯酸3-氯-甲基丙

162~16372.5

87.8111237.64

√√烯79-20-9105-45-3107-31-3108-11-2

MethylacetateMethylacetoacetateMethylformateMethylisobutyl

醋酸甲酯乙酰乙酸甲酯甲酸甲酯4-甲基-戊醇

56.9169.431.7133.5

22648.4680.7363434.35489.07

√√√√carbinol/

74-89-5108-87-213952-84-

MethylamineMethylcyclohexaneMethylpropylamine

甲胺甲基環(huán)己烷仲丁胺

-6.4100.93462.9

294402.284753.2318839.90

√√√6110-91-8115-10-671-41-0123-86-4141-32-271-36-3109-73-9123-72-875-98-979-24-375-52-5100-61-8109-66-071-23-895-51-288-73-395-49-895-50-1123-63-7106-47-8100-00-5106-43-4110-85-0156-43-479-09-4540-54-5107-10-8115-07-157-55-6110-86-169-72-778-92-2110-15-675-65-075-64-9

MorpholineN,N-dimethylethern-Amylalcoholn-butylacetaten-butylacrylaten-butylalcoholn-butylaminen-butyraldehydeNeopentanoicacidNitroethaneNitromethanen-methylanilinen-pentanen-propylalcoholo-chloroanilineo-chloronitrobenzeneo-chlorotolueneo-dichlorobenzeneParaldehydep-chloroanilinep-chloronitrobenzenep-chlorotoluenePiperazinep-phenetidinePropionicacidPropylchloridePropylaminePropylenePropyleneglycolPyridineSalicylicacids-butylalcoholSuccinicacidt-butylalcoholt-butylamine

嗎啡啉甲醚1-戊醇乙酸丁酯丙烯酸丁酯正丁醇正丁胺丁醛特戊酸硝基乙烷硝基甲烷N-甲基苯胺正戊烷正丙醇鄰氯苯胺鄰氯硝基苯鄰氯甲苯1,2-二氯苯三聚乙醛對氯苯胺對硝基氯苯對氯甲苯哌嗪對氨基苯乙醚丙酸1-氯丙烷丙胺丙烯1,2-丙二醇吡啶水酸仲丁醇丁二酸叔丁醇叔丁胺

128.9-24.9137.8126.6221.938117.777.477.6166.209109.2100-102200.430.07497.2208.8245.5159.5180.4233.9208.8242162.2149.324254140.8346.648.6-47.7187.3115-11621199.5236.182.444.4

986.87507144.60218.511022.21530.83648.969456.6311626.2652.742081.653640.1341.0656259.461973.2117.671.81339.36127.321072.526.352.33264.38330.138.49E-01347.9837183.8232792.571015268.1910.592080.711.01E-011719.785.14E-043977.9140154.76

√√√√√√√√√√√√√√√√√√√√√√√√√√√√√√√√√√√/

119-64-2Tetrahydronaphthalene

1,2,3,4-四氫萘210.333.25√584-84-9Toluene-2,4-diisocyanate75-69-4Trichlorofluoromethane

甲苯-，4-二異氰酸酯三氯氟甲烷

115-1201.08√26.888844.64√112-49-2Triethyleneglycoldimethylether

三乙二醇二乙醚197.23.28√75-50-375-35-4

TrimethylamineVinylidenechloride

三甲胺過氯乙烯

2.931.6

182229.2165938.58

√√86-57-7

1-Nitronaphthalene

1-硝基萘

—

—

√95-95-4

2,4.5-Trichloropheno

2,4,5-三氯苯酚—

—

√l95-80-781-16-3

2,4-Toluenediamine2,l-Naphthylamine

2,4-甲二胺2-萘胺-磺酸

——

——

√√sulfonicacid532-27-4

2-Chloroacetophenone2-氯苯乙酮

—

—

√101-77-9

4.4'-Methylenedianil

4,4'-亞基二

—

—

√ine

苯胺100-02-7

4-Nitrophenol

4-硝基苯酚

——

√72-48-0

Alizarin

1,2-二羥基蒽醌—

—

√120-12-784-65-127497-51-

AnthraceneAnthraquinoneBromonaphthalene

蒽蒽醌溴萘

———

———

√√√4218-01-9

Chrysene

1,2-苯并菲——

√91-94-1

Dichlorobenzidine

3,3-對二氯聯(lián)苯—

—

√(33-)111-44-4

Dichloroethylether

氯甲醚((2-—

—

√(Bis(2chloroethyl)ether)

氯乙基))26952-23-

Dichloropropene

二氯丙烯

—

—

√8111-42-2

Diethanolamine

乙醇胺

—

—

√(2,2)64-67-5

Diethylsulfate

硫酸二乙酯

—

—

√131-11-3

Dimethylphthalate

苯二甲酸二甲酯—

—

√119-93-7

Dimethylbenzidine

3,3'-二基聯(lián)

—

—

√(3.3-)

苯胺57-14-7

Dimethylhydrazine

1,1-二甲基肼

—

—

√51-28-5

Dinitrophenol

2,4-二硝基苯酚—

—

√/

25321-14-6

Dinitrotoluene

二硝基甲苯混)——√206-44-0118-74-1123-31-960-34-4101-68-8

FluorantheneGlycolethersHexachlorobenzeneHydroquinoneMethylhydrazineMethylenediphenyl

熒蒽乙二醇醚系列六氯苯對苯二酚甲基聯(lián)胺苯基甲烷二異氰

——————

——————

√√√√√√diisocyanate(4,4'-)(MDI)

酸酯120-18-3

Naphthalenesulfonic

β-萘磺酸

—

—

√acid(p)85-47-2

Naphthalenesulfonic

α-萘磺酸

—

—

√acid(a)90-15-3135-19-3

Naphthol(a)Naphthol(p)

α-萘酚β-萘酚

——

——

√√567-18-0

Naphtholsulfonicacid1-萘酚磺酸

—

—

√(1-)134-32-791-59-884-86-6

Naphthylamine(1-)1-萘胺Naphthylamine(2-)2-萘胺Naphthylamine4-萘胺磺酸

———

———

√√√sulfonicacid(1,4-)90-04-0

O-Anisidine

鄰-氧苯胺

—

—

√31055.00Phenanthrene

菲

—

—

√85-44-9129-00-0106-51-4

PhthalicanhydridePyreneQuinone

苯酐芘對苯醌

———

———

√√√或CAS錄B：1施定了編/

（1M01；（2（301F（4；V；S；OEL；C-（5(質(zhì)液質(zhì)液)；（6(0：否)。/

：實(shí)施LDAR揮、層

pmv數(shù)量v數(shù)量

（kg/hr/source）

（d/

、層設(shè)備元件

流體種類

排放因子（kg/hr/source）石化(化工)類篩選值圍ppmv）0-10001001-9999≥10000

煉油類篩選值圍(ppmv)0-10001001-9999≥10000液體0.00014

0.001650.0451

0.00010.0048