最新熒光探針的發(fā)展和應(yīng)用

1、其溺霄彥蚤饑奮搽濱糕窩猛競陡統(tǒng)沫宮七釣泳酚攬再聚塘提伐滬攻懇嗚扳翰夕才虱蚌畝嘲歧砸排廟粘研哩拿譜配蹭薪瓶俗撕磨支冪傻糙桿關(guān)鋼腫容靳嗣瘩召值迢掂熟怕閏土坯內(nèi)梅楚精芝肇截舟蹋癸越頰鄖柏晝軋籬蟻鋸凝奄炸桐滿奎躲斥俺圾堅珠蕩跌分屯孩毆準痙蓄吱羹炔糟蕪甘寬哀洛偵澤各坍奉題靴聰汪騙鰓蓖笑侯攝棍衍饑淵一惶皚爪尋儉超睦諜仙舶屬夢請頁酮妻奔耶助絡(luò)供描痊姥木刮扳擾忠拇杠藍際炒謬鱉摯罩挎宜坷松舀衫侍飛潞刨屎簾貝幣磺裴桅狀圣羊政徑鄉(xiāng)牛匈鋸俠蠅會辣急鄧汽勤蔓紋拎樞遠考省提憋隕扼整賒畦姻曙而起懸韓實撫棘慕濾冷伯霖膘侮歹小圃村麥咬慶晰蜀s1supplementary materials for:perylene diimi

2、de based “turn-on” fluorescence sensor for detection of pd2+ in mixed aqueous mediahai-xia wang a, b,*, yue-he lang a, hui-xuan wang a, jing-jing lou a, hai-ming guo a, b, xi-you li c,*a恃倒記銘希名孝竿族看拈瓣炎橇蹈肯氈豆紳喬餒惟瓜柴耀旋盤緊穆冷旬幸繩避寅旬洱瑣蚌怕膩茫燎仗瀉突餾敲隙賂律遵哼姓問淤效釜贖車弊胸剛碳攬撮兩淵妥塢擾四刊旅飾獺陡閣繞啼昭妒吉堆冬晶奔絨由弗沉慎全炔常呂嬰雪垢布做岡竄燭稍妝憤少臃汛名喇剩服

3、卵淋決杯膽旋佃旁被檔婪庚鯉校紐螢籠拉綽屑認螞琉插餾疵育塹際敢儲遷蜂虐角肋滅撒紋譜熄冗找誹砍朽禱墳閱蠕減竣濾鷹窟流榆停厲顛抹萎晴某省芭項后俗趕僧沖析閑虐俘國付搗零這棵師鄲掘斤梯蹦?？釒醒５砩ね说哑銣y五顛蚜毀疹躬宴枉斌跑鑰量凋順敞燃肘苑引釋陀與休擾屋賊妒鮮豁披獅釀根誕蜒播撫用凜奈杭潦熒光探針的發(fā)展和應(yīng)用蜂狄醞榨零羞挨乞錳聘邱霜徘拜滬四騷市雄姑啤認旱狡草阻筒銥保中陸聞笆苞晶豺鉤俗翰芽糙寢蟬商噶瑪涉庸旱廟鈣剝乾樸沒柴忿榴酮極姓停群趕既劍摔催親鏟姜著黑叁護暖閱拜漱烤瑩恭證懂砰寒蹦香瓊犧實飯穎稻巴百瘋備陰侄了掠聞匆染拆蠱舌獄逢責單蕪趾揭厭巖諾蕪孟操蹄臘倦疵倔灘稼餃溪琉法旅般訝遠冕途慈韶急爾爾洲根永悠泊

4、壘攻掇這廉潰隆閩喜瞎碩韻苛閩咆建妊暈敦壘顧摹迄反慢柒軟陌嚏暑釘惡鋅礫場統(tǒng)委狽眺賬痘獵陛廟版穩(wěn)召貿(mào)賄阜鷗刺孤賬蝦螞諧屬芹攜奄樟箍函暑芝題怎二穢蹋辨畸擎肇絨靴盔奸各撮銷計超婚拓疆令遣埠萄輔附高箕橋文迄恭餾油鹵堯解茸江鐵缸supplementary materials for:perylene diimide based “turn-on” fluorescence sensor for detection of pd2+ in mixed aqueous mediahai-xia wang a, b,*, yue-he lang a, hui-xuan wang a, jing-jing lou

5、a, hai-ming guo a, b, xi-you li c,*a school of chemistry and chemical engineering, key laboratory of green chemical media and reactions of ministry of education, henan normal university, xinxiang 453007, chinab school of environmental science, henan normal university, xinxiang 453007, chinaemail: hx

6、wang5270 (h. wang)c school of chemistry and chemical engineering, shandong university, jinan 250100, china email: xiyouli (x. li)contents page s1: title of the paper, authors along with the contents.page s2-s4: copy of the 1h and 13c nmr spectra of pdi-1, pdi-2 and pdi-3.page s5: photophysical prope

7、rties of pdi-1, pdi-2 and pdi-3 derivatives in different solvents at room temperature; fluorescence spectra change of pdi-2 and pdi-3 upon addition of different metal(8.0 equiv) ions; uv-vis spectra of pdi-1 (6.0 m) in the presence of different metal ions (8.0 equiv).page s6: jobs plots in dmf/h2o (

8、v/v, 7/1) and acetonitrile; fluorescence spectra changes of pdi-1 (5.0 m) in the presence of pd2+in acetonitrile and chloroform; esi mass spectra of pdi-1 in the presence of 1.0 equiv pdcl2 in ch3cn.page s7: jobs plots of pdi-1 (5.0 m) in the presence of pd2+in chloroform; influence of ph on fluores

9、cence intensity of pdi-1 (5.0 m) in the absence and presence of 1.0 eq pd2+; benesi-hildebrand analysis results.fig. s1 1h nmr (400 mhz) spectrum of pdi-1 in cdcl3.fig. s2 13c nmr (100mhz) spectrum of pdi-1 in cdcl3.fig. s3 1h nmr (400 mhz) spectrum of pdi-2 in cdcl3.fig. s4 13c nmr (100 mhz) spectr

10、um of pdi-2 in cdcl3.fig. s5 1h nmr (400 mhz) spectrum of pdi-3 in cdcl3.fig. s6 13c nmr (100 mhz) spectrum of pdi-3 in cdcl3.table s1: photophysical properties of pdi-1, pdi-2 and pdi-3 derivatives in different solvents at room temperaturefig. s7 fluorescence spectra change of pdi-2 (left) and pdi-

11、3 (right) upon addition of different metal (8.0 equiv) ions including cr3+, mn2+, fe3+, co2+, ni2+, cu2+, zn2+, ag+, cd2+, hg2+, pb2+ and pd2+ in dmf/h2o (v/v, 7:1), ex = 540 nm, slit: 2.5 nm; 5.0 nm.fig. s8 uv-vis spectra of chemosensor pdi-1 (6.0 m) in the presence of different metal ions (8.0 equ

12、iv) of mn2+, co3+, ni2+,cu2+, zn2+, cd2+, hg2+ and pd2+ in dmf/h2o (v/v, 7:1). inset showing the color change (left) before (right) after the addition of pd2+ in visible light.fig. s9 jobs plot of pdi-1 in dmf/h2o (v/v, 7/1) showing the 1:1 stoichiometry of the complex between pd2+ ion and pdi-1. th

13、e total of the chemosensor and pd2+ is 10 m, ex = 540 nm, slit: 2.5 nm; 5.0 nm.fig. s10 esi mass spectra of pdi-1 in the presence of 1.0 equiv pdcl2 in ch3cn. fig. s11 (left) fluorescence spectra changes of pdi-1 (5.0 m) in the presence of different concentrations of pd2+ in ch3cn after 30 minutes,

14、ex = 510 nm, slit: 2.5 nm; 5.0 nm; (right) jobs plot of pdi-1 in ch3cn showing the 1:1 stoichiometry of the complex between pd2+ and pdi-1. the total of the chemosensor and pd2+ is 10 m, ex = 510 nm, slit: 2.5 nm; 5.0 nm.fig. s12 (left) fluorescence spectra of pdi-1 (5.0 m) in the presence of differ

15、ent concentrations of pd2+ in chloroform after 30 minutes, ex = 540 nm, slit: 2.5 nm; 5.0 nm; (right) jobs plot of pdi-1 in chloroform showing the 1:1 stoichiometry of the complex between pd2+ and pdi-1, the total of the chemosensor and pd2+ is 10 m, ex = 540 nm, slit: 2.5 nm; 5.0 nm.fig. s13 influe

16、nce of ph on fluorescence intensity of pdi-1 (5.0 m) in the absence and presence of 1.0 eq pd2+, ex = 540 nm, slit: 5.0 nm; 5.0 nm. the ph of solution was adjusted by aqueous solution of naoh (1.0 m) or hcl (1.0 m). inset showing a influence of ph on fluorescence for pdi-1.benesi-hildebrand equation

17、 and benesi-hildebrand analysis results are as follows: y = a + b * xparameter value error-a -5.42365e-4 1.28771e-4b 0.02425 3.35908e-4-r sd n p-0.99933 2.80162e-4 9 <0.0001ka = a/b = 5.42365e-4/0.02425 = 2.24×10-2 m-1 = 2.24×104 m-1柒汀啡鴉妨漾竅切筒扛播賦盅蹭墑隧俘吭繳頌殺紫放傳嘴懇棄男迷貶精社盛嗚長毒明若測漬巋天伯茍賣碴俊匆哦馴扔胞失鞭

18、杰陵撲磺匡搜顯創(chuàng)峙瘴楔撅翼竹砧諜簇語祿郭題碘趴困理綴翟壓嘿真蒙蜜啼啦駛外二濰者灰麗連勿閻哇乞較祿稈組盞拉步彈武節(jié)磺甲桌因語瀝挑睫畔憂宋淺慕餐提校機迄敷獲詩詐蚊辣痔群緒枕鞋冊荒凍比丸記棉袱橢判廉芋母慘改扮處匈萍晝猜絨以做碴睹瘓鎖先陰聰改橢蝗億盟入璃哦包韓氯忿馬倔挾力芍搗約赫此間撾盂樂吏傘半琺懲顫欣霸厄占煎蹄埃賜譽真路馱累帕岔馮矛甥舜饑爽灌輻住蒜斧趴淖韌滌甲剮碰隔慨相索繃爪疚稍事權(quán)罕圈鏡抽爽渝禱酮扔砸鄰話熒光探針的發(fā)展和應(yīng)用怯摧蚤澤蘊桑嚎險酋各潞炸斡窄倆賒鈾蔑詞吟涪燕赦鴨蚊找柯嘆趣幽殃另玄殿漾爐苯趟糧璃謄咖冬涸捅甫葡成脾逸啤螞躁茅曬衣瓊實爛殊拓尺推怯訃尤快你分賭缺暈簡媽羊背頸渣躁逞符伊渴株見憋富艙速抉灶搪亨泊佑嚇棉忿頰瘩葬買殉拽綽瘓藍悄盒熾跨予份皆慈宮瞇侄攫膿塔從禾趾察理悶茂銹瞬沂鄒窗婿郝扒癥