汽車修補(bǔ)漆樹脂管理知識分析

1、汽車修補(bǔ)漆樹脂管理知識分析Vehicle Refinish Paint Layers機(jī)車修補(bǔ)涂層示意機(jī)車修補(bǔ)涂層示意Metal body Clearcoat (60 m)面漆Basecoat (20 m)底漆Primer / Filler中涂 (60 -150 m)Wash primer磷化蝕洗底漆 (10 m)Polyester putty聚酯灰or Monocoat(60 m) Basic functions 基本功能基本功能 protection of surface 表面保護(hù) leveling, smoothing of rough surface 流平，修整粗糙表面 adhesive

2、 layer for topcoat 與面漆層間附著Resin Requirements 樹脂要求樹脂要求hardness / flexibility : stone chip resistance 硬度/柔韌性：耐石擊性pigment wetting : leveling and appearance 顏料濕潤性：流平和外觀adhesion : corrosion resistance, no peeling-off of topcoats 附著力：耐腐蝕，防止面漆剝離。drying speed: earlier sanding 干燥速度：盡早打磨low price : economics

3、低價(jià)：實(shí)惠Vehicle Refinish Primer 汽車修補(bǔ)中涂汽車修補(bǔ)中涂Vehicle Refinish Primer Resins Overview機(jī)車修補(bǔ)中涂樹脂概況機(jī)車修補(bǔ)中涂樹脂概況 Solventborne溶劑型Standard標(biāo)準(zhǔn): Setalux 1184 (結(jié)合Setalux 1187)fast drying快干: Setalux 1200 good adhesion附著力好: Setalux 1196chemical resistance耐化學(xué)性好: Setalux 1152non-isocyanate 2K: Setalux 7202 + 7002Vehicle

4、Refinish Primer Resins Products (1)汽車修補(bǔ)中涂產(chǎn)品汽車修補(bǔ)中涂產(chǎn)品Setalux 1184 SS-51acrylic polyol with 2.0% OH (on non-volatiles)2.0%羥基丙烯酸very fast drying 非?？旄蒰ood hardness 硬度好good sandability 打磨性好Setalux 1187 XX-60acrylic polyol with 3.6% OH (on non-volatiles) 3.6%羥基丙烯酸very flexible 柔韌性好medium solids 中等固體份Vehicl

5、e Refinish Primer Resins Products (2)汽車修補(bǔ)中涂產(chǎn)品汽車修補(bǔ)中涂產(chǎn)品Setalux 1196 XX-60acrylic polyol with 2.6% OH (on non-volatiles) 2.6%羥基丙烯酸good adhesion on various substrates 在不同的底材上有好的附著fast drying 快干good chemical resistance 耐化學(xué)性好Setalux 1200 XX-55acrylic polyol with 1.8% OH (on non-volatiles) 1.8%羥基丙烯酸very fa

6、st drying 非?？旄蒰ood adhesion on various substrates 在不同的底材上有好的附著good hardnessVehicle Refinish Primer Resins Products (3)汽車修補(bǔ)中涂產(chǎn)品汽車修補(bǔ)中涂產(chǎn)品Setalux 7202aceto-acetate functional acrylic resin 帶乙酰乙酸功能丙烯酸樹脂Setalux 7002ketimine functional a酮亞胺功能樹脂cPrinciple原理原理: The ketimine groups in the crosslinker are debl

7、ocked by traces of water (humidity). The resulting primary amines react very fast with the aceto-acetate groups to form enamine bonds. 酮亞胺官能團(tuán)由水 (濕度)的作用交聯(lián)解塊。結(jié)果伯胺和酮亞胺官能團(tuán)反應(yīng)非?？飚a(chǎn)生烯胺鍵。rFeatures: very fast drying and curing resulting in good sanding properties even under severe humidity conditions and low

8、temperatures 在低溫和濕氣環(huán)境下很快干易打磨。 good adhesion 附著好 low toxicity 低毒性:total system 整個(gè)體系: LC50 4,84 g/m3 rat individual resins單獨(dú)樹脂: LD50 10 ml/kg ratesin (cross-lir)Vehicle Refinish Primer Resins Formulation 汽車修補(bǔ)中涂樹脂配方汽車修補(bǔ)中涂樹脂配方 Formulation for a primer with PVC = 43% and 100%crosslinking 中涂體積顏基比43%和100%交

9、聯(lián)。solid binder 100.0 acrylic polyol + isocyanate 羥基丙烯酸+異氰酸酯Bentone 38 2.5 rheology control 流變助劑Kronos 2190 40.0 hiding power 鈦白粉Micro Talc AT Extra 40.0 extender 滑石粉China Clay 90.0 extender 高嶺土Heucophos ZP10 30.0 anti-corrosion 磷酸鋅Bayferrox 3910 6.0 hiding power 氧化鐵黃Dibutyl tin dilaurate 2.5 catalys

10、t 催化劑BYK-141 1.0 defoamer 消泡劑solvents .溶劑Vehicle Refinish Primer Resins Comparison (2) 汽車中涂樹脂對比汽車中涂樹脂對比Tackfree : time in h:mm with cotton wool methodHardness : Knig hardness in seconds after 7 days 23CVehicle Refinish Primer Resins Comparison (3) 汽車中涂樹脂對比汽車中涂樹脂對比Adhesion : overall relative score of

11、 adhesion on several substrates, wet adhesion and high pressure cleaningSaltspray : blistering rate after 1000 hours exposure on phosphated steel (f=few, m=medium, d=dense)Vehicle Refinish Primer ResinsStarting Point Formulations汽車修補(bǔ)中涂起始配方汽車修補(bǔ)中涂起始配方Solventborne溶劑型 Setalux 1184 REC 97021 Setalux 1184

12、 + 1187REC 99051 Setalux 1196REC 03009 Setalux 1200 REC 99026 Setalux 7202 + 7002REC 99015Vehicle Refinish Basecoat 汽車修補(bǔ)底漆汽車修補(bǔ)底漆Basic functionsic 基本功能Aesthetics 美觀Resin Requirements 樹脂要求pigment wetting / stability : colour matching and in-can stability顏料濕潤性/穩(wěn)定性：色差儀和涂料儲存穩(wěn)定adhesion : intercoat adhesio

13、n, no peeling-off between layers附著力：層間附著，層間不分層。film inertness : prevent strike-in of solvents from clearcoatrheology control : metallic particles orientation, optimum flip-flop 防止清漆溶劑咬底，外觀控制金屬粉定向。thixotropy : no setting of pigment with good spray properties觸變性：防止顏料沉降和好的噴涂性能。Vehicle Refinish Basecoat

14、 Resins Overview汽車修補(bǔ)底漆概括汽車修補(bǔ)底漆概括Solventborne溶劑型Polyester聚酯: Setal 173Polyester聚酯: Setal 189polyester SCA mod.: Setal 90173Acrylic丙烯酸: Setalux 1184Acrylic丙烯酸: Setalux 1385Vehicle Refinish Basecoat Resins Products (1)汽車修補(bǔ)底漆樹脂產(chǎn)品汽車修補(bǔ)底漆樹脂產(chǎn)品Setal 173 VS-60saturated polyester 飽和聚酯good adhesion 附著力好good fle

15、xibility 柔韌性好good chemical and water resistance 耐化學(xué)和耐水性好Setal 189 XX-65saturated polyester飽和聚酯good pigment wetting 顏料濕潤性好good hardness 高的硬度good compatibility with CAB 與CAB相溶性好Ve hicle Refinish Basecoat Resins Products (2)汽車修補(bǔ)底漆樹脂產(chǎn)品汽車修補(bǔ)底漆樹脂產(chǎn)品Setal 90173 SS-50-SCA modified saturated polyesters 飽和聚酯改進(jìn)流

16、變控制劑-prevents settling and sagging 防止沉降和流掛-excellent metallic orientation 優(yōu)異的金屬定向性-less CAB required (higher solids, cost effective) 對CAB需求少-less wax required 對蠟的需求少-good adhesion 附著好-good pigment wetting 顏料濕潤性好Vehicle Refinish Basecoat Resins Products (3)汽車修補(bǔ)底漆樹脂產(chǎn)品汽車修補(bǔ)底漆樹脂產(chǎn)品Setalux 1385 BX-51thermo

17、setting hydroxylated acrylic 熱固性羥基丙烯酸樹脂very good compatibility with CAB 和醋酸丁酸纖維素有好的相容性fast drying 快干Setalux 1184 SS-51acrylic polyol 羥基丙烯酸good compatibility with CAB 和醋酸丁酸纖維素有好的相容性fast drying 快干Vehicle Refinish Basecoat Resins System examples (1) 汽車修補(bǔ)底漆樹脂例汽車修補(bǔ)底漆樹脂例Polyester 聚酯49 parts Setal 189 XX-6

18、538 parts CAB 381-0.510 parts CAB 551-0.23-5 parts Cerafak 106 or Ceratix 8461( 5 parts Setamine US-138 )SCA modified polyester聚酯改進(jìn)流變控制劑67 parts Setal 9017330 parts CAB 381-0.5 3 parts Cerafak 106Vehicle Refinish Basecoat Resins System examples (2）汽）汽車修補(bǔ)底漆樹脂例車修補(bǔ)底漆樹脂例Thermosetting acrylic 熱固性丙烯酸樹脂51

19、parts Setalux 1385 BX-5138 parts CAB 381-0.5 5 parts Ceratix 8461 6 parts Setamine US-138Acrylic polyol 羥基丙烯酸58 parts Setalux 118438 parts CAB 381-0.5 4 parts Cerafak 106Vehicle Refinish Basecoat Preparation (1)汽車修補(bǔ)底漆制備汽車修補(bǔ)底漆制備Solventborne metallic basecoat 溶劑型金屬底漆1. dissolve the metallic pigments u

20、nder slow stirring;add dispersant and rheology control additive低速分散金屬顏料和添加分散劑和觸變劑2. make a premix of basecoat resins; add the CAB-resin under high shear forces ; add the other additives 高速攪拌底漆樹脂與CAB的混合基料，添加助劑。3. add the pigment-paste (component 1) under slow stirring bit by bit to component 2 低速攪拌將顏

21、料漿緩慢加入基料，然后高速分散。4. add the solvents till the right delivery form.添加溶劑調(diào)整Vehicle Refinish Basecoat Metallic control汽車修補(bǔ)底漆金屬效果控制汽車修補(bǔ)底漆金屬效果控制Wet basecoatRandom orientation of Al-platesNo “Flop”鋁粉在濕膜中無規(guī)則排列Dry basecoatParallel alignment of Al-platesExcellent “Flop”干燥后鋁粉有序排列DryingShrinkage of the wet basec

22、oat during drying results in good particle orientation底漆干燥收縮過程中有好的顆粒定向Vehicle Refinish Basecoat ResinsStarting Point Formulations 汽車修補(bǔ)底漆樹脂起始配方汽車修補(bǔ)底漆樹脂起始配方Solventborne溶劑型溶劑型 Setal 173REC 01008 Setal 189REC 01010, 02032 till 02038 Setal 90173REC 03044, 04008 Setalux 1184REC 00031 Setalux 1385REC 04036

23、Vehicle Refinish Clearcoat汽車修補(bǔ)清漆汽車修補(bǔ)清漆Basic function 基本功能基本功能-Protection of basecoat layer against environment 對底層的保護(hù) -Aesthetics 美觀 Resin Requirements 樹脂要求樹脂要求-good gloss, levelling, clarity : overall appearance 光澤，流平：綜合外觀-chemical resistance : no acid attack 耐化學(xué)性：酸侵蝕-weathering resistance : outdoo

24、r durability 耐候性：戶外耐久性-fast drying / hardness development : earlier handling / polishability快干/硬度：盡早的操作/打磨性-low colour : no problems in colour matching 低的顏色：不影響色差-good adhesion : intercoat adhesion 好的層間附著力Vehicle Refinish Clearcoat Resins Overview汽車修補(bǔ)清漆樹脂概括汽車修補(bǔ)清漆樹脂概括Solventborne溶劑型Standard標(biāo)準(zhǔn) : Setal

25、ux 1152 SS-51economy grade實(shí)惠 : Setalux 1186 SS-60 fast drying快干 : Setalux 1192 SS-60，good appearance外觀好 : Setalux 1190 SS-61, Setalux XSZ1107medium solids中等固體 : Setalux 1198 SS-70 , Setalux 1215 BA-68high gloss, wetlook高光 : Setalux 1211, Setalux 1753high solids acrylic高固丙烯酸 : Setalux 1901 , Setalux

26、1903high solids polyester高固聚酯 : Setal 1715 , Setal 1603Weather resistance 耐候耐黃變: Setalux XSZ 1003 Super fast drying 超快 :Setalux 57-2500Vehicle Refinish Clear coat Resins （1）汽車修補(bǔ)清漆樹脂汽車修補(bǔ)清漆樹脂Setalux 1152 SS-51standard low solids acrylic polyol with 4.2% OH (on NV)標(biāo)準(zhǔn)低固羥值4.2%丙烯酸good hardness 硬度好good glo

27、ss and leveling 光澤和流平好good chemical resistance 耐化學(xué)性好Setalux 1186 SS-60low solids acrylic polyol with 3.0% OH (on non-volatiles)低固羥值3.0%丙烯酸good gloss and leveling 光澤和流平好good hardness / flexibility 硬度和柔韌性平衡Vehicle Refinish Clearcoat Resins （2）汽車修補(bǔ)清漆樹脂汽車修補(bǔ)清漆樹脂Setalux 1204 XS-60low solids acrylic polyol

28、 with 3.0% OH (on non-volatiles)低固體份羥值3.0%丙烯酸good drying properties under severe conditions在苛刻條件下快干good hardness build-up 好的實(shí)干硬度Setalux 1192 SS-60low solids acrylic polyol with 3.8% OH (on non-volatiles)低固體份羥值3.8%丙烯酸fast drying with good overspray take-up 厚涂時(shí)快干good adhesion 附著力好Vehicle Refinish Clea

29、rcoat Resins （3）汽車修補(bǔ)清漆樹脂汽車修補(bǔ)清漆樹脂Setalux 1753 SS-70medium solids acrylic polyol with 4.2% OH (on solid)中固體羥值4.2%丙烯酸fast drying 快干good hardness / flexibility 硬度和柔韌性好的平衡good appearance with high build and gloss好的豐滿度和光澤外觀Vehicle Refinish Clearcoat Resins （4）汽車修補(bǔ)清漆樹脂汽車修補(bǔ)清漆樹脂Setalux 1190 SS-61(XYL/PMA)low

30、 solids acrylic polyol with 4.5% OH (on non-volatiles)低固體份羥值4.5%丙烯酸good leveling and appearance 流平和外觀好good outdoor durability 戶外耐久性好Setalux 1211 BA-65medium solids acrylic polyol with 3.0% OH (on non-volatiles)中固體份羥值3.0%丙烯酸good leveling and appearance 流平和外觀好very high gloss 非常高的光澤Vehicle Refinish Cle

31、arcoat Resins （5）汽車修補(bǔ)清漆樹脂汽車修補(bǔ)清漆樹脂Setalux 1198 SS-70medium solids acrylic polyol with 4.2% OH (on non-volatiles)中固體份羥值4.2%丙烯酸good leveling and appearance 外觀流平好good outdoor durability 戶外耐久性好Setalux 1215 BA-68medium solids acrylic polyol with 4.5% OH (on non-volatiles)中固體份羥值4.5%丙烯酸good leveling and app

32、earance 流平和外觀好good drying properties 好的干燥性能Vehicle Refinish Clearcoat Resins （6）汽車修補(bǔ)清漆樹脂汽車修補(bǔ)清漆樹脂Setalux 1901 SS-75high solids acrylic polyol with 5.4% OH (on non-volatiles)高固體羥值5.4%丙烯酸very good durability 戶外耐久性好good flexibility柔韌性好Setalux 1903 BA-75high solids acrylic polyol with 4.5% OH (on non-vol

33、atiles)高固體羥值4.5%丙烯酸fast drying 快干good gloss 光澤好Vehicle Refinish Clearcoat Resins （7）汽車修補(bǔ)清漆樹脂汽車修補(bǔ)清漆樹脂Setal 1615 SS-75high solids polyester polyol with 4.4% OH (on non-volatiles)高固體聚酯多元醇4.4%羥值very good durability 非常好的耐久性good flexibility 柔韌性好Setal 1603high solids polyester polyol with 5.4% OH (on non-v

34、olatiles)高固體聚酯多元醇5.4%羥值very good durability非常好的耐久性good flexibility柔韌性好good hardness build-up 好的實(shí)干硬度Vehicle Refinish Clearcoat Resins （8）汽車修補(bǔ)清漆樹脂汽車修補(bǔ)清漆樹脂Setalux XSZ 1107 SS-70medium solids acrylic polyol with 3.0% OH (on non-volatiles)中固體份羥值3.0%丙烯酸good leveling and appearance 外觀流平好good chemical resis

35、tance 耐化學(xué)性好good fast drying 快干好 Setalux XSZ 1003 BA-68medium solids acrylic polyol with 4.5% OH (on non-volatiles)中固體份羥值4.2%丙烯酸good leveling and appearance 流平和外觀好good UV yellowing and durability 好的黃變耐老化性能Vehicle Refinish Clearcoat Resins （9）汽車修補(bǔ)清漆樹脂汽車修補(bǔ)清漆樹脂Setalux 57-2500medium solids acrylic polyol

36、 with 4.2% OH (on non-volatiles)中固體份丙烯酸羥值4.2%丙烯酸good gloss and DOI appearance 光澤和鮮映性好good chemical resistance “MEK rub” 耐化學(xué)性好“丁酮擦拭”super fast drying and long potlife 超快干和活化期長Very good exterior durability 非常好戶外耐久性Setalux 57-2500 Zero VOC Acrylic Polyol零零VOC羥基丙烯酸羥基丙烯酸 Clearcoat ready to buff in 30 min

37、utes 快速清漆拋光 Ultra-fast hardness development 超快的硬度提升57-2500Conventional Acrylic PolyolVehicle Refinish Clearcoat Resins VOC汽車修補(bǔ)清漆樹脂有機(jī)揮發(fā)排放汽車修補(bǔ)清漆樹脂有機(jī)揮發(fā)排放Vehicle Refinish Clearcoat ResinsDrying time / Hardness汽車修補(bǔ)清漆樹脂汽車修補(bǔ)清漆樹脂 干燥干燥/硬度硬度Vehicle Refinish Clearcoat ResinsCar wash resistance汽車修補(bǔ)清漆樹脂汽車修補(bǔ)清漆樹脂

38、耐擦洗耐擦洗9089918588856653677060730102030405060708090100Slx 1152Slx 1198Slx 1753Slx 1901Slx 1903AutomotiveOEMGloss 20 degree geometry (GU)Initital glossGloss after car wash testcar wash test according PSA RNUR D24 5359 Vehicle Refinish Clearcoat ResinsUVCON: yellowing/cracking 汽車修補(bǔ)清漆樹脂紫外照射汽車修補(bǔ)清漆樹脂紫外照射cl

39、earcoats with UVA/HALSVehicle Refinish Clearcoat ResinsFlorida: 5 year exposition 汽車修補(bǔ)清漆樹脂汽車修補(bǔ)清漆樹脂 福羅里達(dá)暴曬福羅里達(dá)暴曬9292948994927977807581790102030405060708090100Slx 1152Slx 1186Slx 1190Slx 1192Slx 1198Slx 1753Gloss 20 degree geometry (GU)before expositionafter expositionclearcoats with UVA/HALSVehicle R

40、efinish Clearcoat ResinsFlorida: 1 year exposition汽車修補(bǔ)清漆樹脂汽車修補(bǔ)清漆樹脂 福羅里達(dá)暴曬福羅里達(dá)暴曬9192959086866778657470770102030405060708090100Slx 1204Slx 1208Slx 1211Slx 1903Setal 1615Setal 1603Gloss 20 degree geometry (GU)before expositionafter expositionclearcoats with UVA/HALSVehicle Refinish Clearcoat ResinsStar

41、ting Point Formulations 汽車清漆樹脂起始配方汽車清漆樹脂起始配方Solventborne 溶劑型溶劑型 Setalux 1152REC 96083 Setalux 1186REC 99052 Setalux 1192REC 99068 Setalux 1190REC 00051 Setalux 1198REC 02010 Setalux 1204REC 01001 Setalux 1211REC 04023 Setalux 1215REC 04037 Setalux 1753REC 99075 Setalux 1901 + Setal 1615REC 99019, 99

42、023 Setalux 1903REC 03003 Setalux 1903 + Setal 1603REC 03005, 05013Vehicle Refinish Monocoat 汽車修補(bǔ)色漆汽車修補(bǔ)色漆Basic function 基本功能Protection against environment 保護(hù) Aesthetics 美觀Resin Requirements 樹脂要求-good gloss, levelling, clarity : overall appearance 光澤，流平：綜合外觀-chemical resistance : no acid attack 耐化學(xué)性：

43、酸侵蝕-weathering resistance : outdoor durability 耐候性：戶外耐久性-fast drying / hardness development : earlier handling / polishability快干/硬度：盡早的操作/打磨性-low colour : no problems in colour matching 低的顏色：不影響色差-good adhesion : intercoat adhesion 好的層間附著力Vehicle Refinish Monocoat 1K Resins Overview汽車修補(bǔ)色漆單組份樹脂概括汽車修補(bǔ)

44、色漆單組份樹脂概括Solvent borne溶劑型nitrocellulose lacquers 硝基漆 : Setal 84oxidatively drying 氧化干燥 : Setal 196fast drying acrylic 快干丙烯酸 : Setalux 2117 with Setyrene 78Vehicle Refinish Monocoat 2K Resins Overview汽車修補(bǔ)色漆雙組份樹脂概括汽車修補(bǔ)色漆雙組份樹脂概括Solventborne 溶劑型Standard 標(biāo)準(zhǔn): Setalux 1152fast drying 快干: Setalux 1204good a

45、ppearance 外觀: Setalux 1190，Setalux XSZ1107economy grade 實(shí)惠: Setalux 1199 , Setalux 1186medium solids 中固體份: Setalux 1753 , Setalux 1211 high solids acrylic高固體: Setalux 1901 , Setalux 1903high solids polyester高固體: Setal 1615 , Setal 1603 good pigment wetting 顏料濕潤性: Setal 161Super fast drying 超快干 ：Seta

46、lux 57-2500Good outside durability ：Setalux XSZ 1003Vehicle Refinish Monocoat Resins Products (1)汽車修補(bǔ)色漆樹脂概括汽車修補(bǔ)色漆樹脂概括Setal 84short oil alkyd based on non-drying fatty acid不干脂肪酸短油醇酸good pigment wetting 顏料濕潤性好good appearance 外觀好good weathering resistance 耐候性好Setal 196medium oil alkyd based on air dryi

47、ng fatty acids氣干型中油醇酸fast drying with good hardness build-up快干好的實(shí)干硬度good appearance 外觀好good weathering resistance 耐候性好Vehicle Refinish Monocoat Resins Products (2)汽車修補(bǔ)色漆樹脂產(chǎn)品汽車修補(bǔ)色漆樹脂產(chǎn)品Setal 161medium solids polyester polyol with 3.1% OH (on NV)中固體份聚酯羥值3.1%（固體）good hardness 硬度好good flexibility 柔韌性好goo

48、d outdoor durability 戶外耐久性好Setalux 57-2500medium solids acrylic polyol with 4.2% OH (on NV)中固體份丙烯酸羥值4.2%丙烯酸good gloss and DOI appearance 光澤和鮮映性好good chemical resistance “MEK rub” 耐化學(xué)性好“丁酮擦拭”super fast drying and long potlife 超快干和活化期長Very good exterior durability 非常好戶外耐久性Vehicle Refinish Monocoat Res

49、ins Products (3)汽車修補(bǔ)色漆樹脂產(chǎn)品汽車修補(bǔ)色漆樹脂產(chǎn)品Setalux 1199low solids acrylic polyol with 3.5% OH (on NV) fast drying with good hardness 快干和好的硬度good appearance with high gloss 外觀好和光澤度高good chemical resistance 好的耐化學(xué)性Setalux 1753medium solids acrylic polyol with 4.2% OH (on non-volatiles)fast drying 快干good hardn

50、ess / flexibility 好的硬度/柔韌性good appearance with high build and gloss 高豐滿度光澤外觀好Vehicle Refinish Monocoat Resins Products (4)汽車修補(bǔ)色漆樹脂產(chǎn)品汽車修補(bǔ)色漆樹脂產(chǎn)品Setalux XSZ 1107 SS-70medium solids acrylic polyol with 3.0% OH (on non-volatiles)中固體份羥值3.0%丙烯酸good leveling and appearance 外觀流平好good chemical resistance 耐化學(xué)性好good fast drying 快干好 Setalux XSZ 1003 BA-68medium solids acrylic polyo