路博潤(rùn)金屬加工液培訓(xùn)全課件

MetalworkingAdditives

金屬加工添加劑October2012MetalworkingAdditives

金屬加工添加劑Agenda議程Introduction

概況介紹MetalworkingCapabilitiesandSupport

金屬加工系列產(chǎn)品線和技術(shù)支持ProductOfferingandFormulationAdvices

產(chǎn)品介紹和配方舉例Questions

問題Agenda議程Introduction概況介紹LubrizolLockhart-Locksol-Lockguard

BecherChemie-Becrosan-Contram-SkosanorAlox-Aqualox-Alox

Gateway-Addco-Synester-AddconateLubrizolMetalworkingBrandNamesSulfurizedEPAdditives,TraditionalSolubleOilEmulsifier硫系極壓劑及乳化劑產(chǎn)品WaterbasedAdditives,EmulsifierExpertise,SpecialityPolymericEsters水基添加劑、乳化劑和聚合酯WaterbasedAdditives,CorrosionInhibitorExpertise,水基防銹及防腐蝕劑Biocides殺菌劑RustPreventives,WaterbasedCorrosionInhibitors防銹劑RustPreventives,NaturalSulfonatesupply,ThixotropicGelledSulfonate防銹劑、磺酸鹽LubrizolLockhartBecherChemieGlobalSupport全球技術(shù)支持Technicallaboratories技術(shù)實(shí)驗(yàn)室Wickliffe,OHUSABrecksville,OHUSAHazelwood,EnglandSpartanburg,SCUSAMetalworkingResearch&TechnicalService金屬加工產(chǎn)品研發(fā)和技術(shù)支持Hamburg,Germany德國(guó)漢堡MetalworkingTechnicalSupport

金屬加工產(chǎn)品技術(shù)支持Shanghai,China上海MetalworkingTechnicalSupport金屬加工產(chǎn)品技術(shù)支持GlobalSupport全球技術(shù)支持TechnicalShanghaiMetalworkingResources

上海實(shí)驗(yàn)室配置和評(píng)價(jià)方法Procedure PropertyEvaluatedIP287 FilterPaperChipBreakpoint防銹/濾紙鐵屑法IP263 EmulsionStability乳化安定性IP311 ConcentrateStorageStability儲(chǔ)存穩(wěn)定性IP312 FoamTest–ShakingMethod泡沫試驗(yàn)ASTMD455 KineticViscosity黏度測(cè)定LubrizolPumpTest FoamTest路博潤(rùn)泡沫試驗(yàn)MicroTapII Lubricity潤(rùn)滑性評(píng)定/攻絲扭矩Mod.TimkenFishTank BacteriaResistance抗菌性試驗(yàn)＊Ifneedtechnicalserviceforourcustomers,plsfillinTSR’sfirst.MicroTapFoamRigShanghaiMetalworkingResourceAdditives–Applications–Capabilities

路博潤(rùn)添加劑的應(yīng)用領(lǐng)域Cleaners清洗劑

MetalRemoval切削

MetalForming

成型

ProcessAdditives

工藝助劑

RustPreventives防銹IndustrialAdditives工業(yè)用油

CorrosionInhibitors腐蝕抑制InternalLubrication潤(rùn)滑LubrizolMetalworkingAdditivesAdditives–Applications–CapMetalworkingAdditives

ProductOffering

forWaterbasedProducts

水基金屬加工液產(chǎn)品介紹MetalworkingAdditives

ProductMetalworkingAdditives金屬加工添加劑WaterBased–WaterMiscible水基或水溶性產(chǎn)品AqueousFluidSystem

應(yīng)用于水基體系GenerallySuppliedasConcentrateforDilutioninWater

通常以濃縮液的形態(tài)供應(yīng)，使用時(shí)以水稀釋SubCategories這類產(chǎn)品包括SolubleOil乳化油Synthetic全合成液SemiSynthetic半合成液MetalworkingAdditives金屬加工添加劑WProductCategories產(chǎn)品EmulsifierComponentsEmulsifierPackages–HongJing乳化復(fù)合劑—洪涇介紹ExtremePressureAdditivesLubricityAdditives潤(rùn)滑劑RustPreventivesCorrosionInhibitors防銹劑IndustrialMetalworkingBiocides殺菌劑ProductCategories產(chǎn)品EmulsifieLubricityAdditivesforwatermisciblefluids

水基潤(rùn)滑劑LubricityAdditivesforwaterLubricity/EPagents潤(rùn)滑/極壓劑ADDOSANESTEP206TMP-EsterofCastoroilandOleicacid是以蓖麻油和油酸為原料的TMP的酯AddosanESTEP206isusedasanEP-additiveinwatermisciblemetalworkingfluids,especiallyforAl-processing.Typicaltreatlevelsintheconcentrateshouldbe5-10%.

該產(chǎn)品可用于水基配方中做極壓劑，特別適合鋁加工。加量5—10%Forthemachiningofsteeltheadditionshouldbebetween5and20%totheconcentrate,dependingontherequirementsandtheseverityoftheprocess

用于鋼材加工時(shí)需要在濃縮液里加入5—20%，視加工的劇烈程度而定。Innonwaterbasedmetalworkingfluids,AddosanESTEP206isqualifiedforfinesteelwiredrawingincombinationwithP-EPandS-additives.

在非水基的體系中它與含磷或含硫極壓劑共用可用于細(xì)鋼線的拉拔。AddosanESTEP206canalsobeusedasafattyagentinnon-watermisciblemetalworkingfluids.

在非水溶性配方里可用作油性劑Itisalsosuitableforgrindingprocesseswhereagoodstabilityofthefattycomponentisrequired.在磨削加工中如果需要使用穩(wěn)定性好的油性劑，可考慮使用該產(chǎn)品Lubricity/EPagents潤(rùn)滑/極壓劑ADAddosanEstep206Properties

Colour顏色: ligthbrown淺棕色

Acidvalue酸值(mgKOH/g): max10

Viscosity黏度(40°C): appr85mm2/sTypicaluselevel典型用量

Waterbased水基: 5–10%

Neatoils油基: 1–2%(neatoils:2%Estep206+0.5%EPC127-usedforflutegrinding

在油基配方中使用2%Estep206+0.5%EPC127可用于成管加工)AddosanEstep206Properties

CBECROSAN?E2135amineandboronfreeformulationwithbiocide

配方舉例：不含胺、不含硼的半合成液配方

BECROSAN?E2135 45%

AddosanESTEP206 10%

NaphthenicBaseOil 42% CONTRAM?OF-G 2.5% CONTRAM?J30D 0.5% Anapprox.8%emulsionofapreparationofBECROSAN?E2135,performanceester(inparticularAddosanESTEP206)inbaseoil(asabove)worksextraordinarywellforgeneralaluminiummachining.

上述配方以8%的稀釋液用于鋁加工具有非常突出的效果

Appearance外觀

visual目測(cè)translucent半透明 Emulsionstability乳化安定性 visualafter24hrs0mloil/0mlcream pHvalue,5%inwater5%水溶液的PH值DIN51369 9.1 CorrosionprotectionDIN51360part2 Note0at4%vol

防銹BECROSAN?E2135amineandborSemiSyntheticAluminum鋁加工半合成液—潤(rùn)滑效果

45%BECROSANE2135+環(huán)烷基油VS

10%ADDOSANESTEP206+45%BECROSANE2135+環(huán)烷基油

SemiSyntheticAluminum鋁加工半合成液Highoil-Semi-SyntheticPackages

與高含油半合成復(fù)合劑的復(fù)配配方Baseoil基礎(chǔ)油41.7045.7050.70BECROSAN?E2137H/LUBRIZOL?568342.00--BECROSAN?E2135-40.00-BECROSAN?E2152--35.00ADDOSANESTEP20610.010.010.0CONTRAM?MBOorST-12.002.002.00CONTRAM?J30D0.300.300.30Quicklin131.00--Water水3.00--TD25/30-2.002.00LUBRIZOL?5674消泡劑0.10-0.10Highoil-Semi-SyntheticPackPerformance性能E2137H/LUBRIZOL?5683E2135E2152Appearance外觀yelow-lightbrown,clear黃色—淡棕色，透明Yelowlightbrown,clear黃色—淡棕色，透明Yellowlightbrown,clear黃色—淡棕色，透明Appearanceemulsion(5%in20°dH)乳液外觀Fresh新鮮乳液Translucent

半透明Translucent半透明Translucent半透明after24h24小時(shí)后translucent-nocream半透明—無(wú)浮皂translucent-nocream半透明—無(wú)浮皂translucent-nocream半透明—無(wú)浮皂corrosion-DIN51360-part2防銹2%-class0-12%-class1-22%-class2corrosion-IP287防銹breakpoint@2%breakpoint@3%breakpoint@3%pH-value-(5%in20°dH)pH值9.209.409.40foamcharacteristic

泡沫5%in10°dHnofoam無(wú)泡沫nofoam無(wú)泡沫nofoam無(wú)泡沫5%in5°dH70ml-10ml-0ml50ml-0ml-0ml70ml-10ml-0mlReichertwithoutlubricity磨斑/未加潤(rùn)滑劑30.0mm231.3mm233.2mm2Reichertwith磨斑/加入ADDOSANESTEP20623.0mm223.8mm224.3mm2Performance性能E2137H/LUBRMetalworking-CorrosionInhibitors

防銹劑StopRustMetalworking-CorrosionInhibBecrosan2131–TechnologyTrivialname:Triazinetrisaminohexanoicacid三嗪三氨基己酸IUPAC:6,6,6-(1,3,5-triazine-2,4,6-triyltriimino)-

trihexanoicacidCAS-No.80584-91-4 MW:468.6g/molBecrosan2131–TechnologyTrivBecrosan2131–TechnologyApplications應(yīng)用Neutralizedwithalkali/alkanolamineperformsasveryeffectivecorrosioninhibitor用堿/醇胺中和后是非常有效的腐蝕抑制劑Appliedinalltypesofwaterbasedsystems Metalworkingfluids (Semi-syntheticandsyntheticfluids)可以用于所有類型的水基體系金屬加工液(半合成和合成液)Highwaterbasedhydraulicfluids(HFC)可用于高水基液壓液(HFC)Engineandothercoolingsystems用于發(fā)動(dòng)機(jī)和其他冷卻體系

Becrosan2131–TechnologyApplBecrosan2131–TechnologyBenefits優(yōu)點(diǎn)Veryeffectivecorrosioninhibition高效防銹Doesnotformresinousfilmsorgumsonmetals不會(huì)在金屬表面形成樹脂或膠狀膜Lowfoaming低泡沫Noaluminumstaining(dependingonamineused)不會(huì)造成鋁腐蝕Compatiblewithhardwaterupto2000ppm耐硬水能力高達(dá)2000ppmCanbeusedforcorrosioninhibitionofmulti-metalsystems,mightbeimprovedbyadditionofSkosanorKSP24/531andheptanoic/ison.Acid可以用于含多種金屬的體系，添加SkosanorKSP24/531可提高防腐蝕效果PROVEN:Notendencytoformnitrosamines(5fruleinUS)不會(huì)生成亞硝胺Excellentairrelease良好的空氣釋放性能Becrosan2131–TechnologyBeneBecrosan2128–TechnologyTrivialname:Tolylsulfonamidohexanoicacid對(duì)甲苯磺酰氨基己酸IUPAC:4-Methylphenylsulfonylaminohexanoicacid

CAS-No.78521-39-8MW:285.0g/molBecrosan2128–TechnologyTrivBecrosan2128–TechnologyApplications應(yīng)用:Neutralizedwithalkali/alkanolamineperformsasveryeffectivecorrosioninhibitor用堿/醇胺中和后是非常有效的腐蝕抑制劑AppliedinalltypesofwaterbasedsystemsMetalworkingfluids(Semi-syntheticandsynthetic)可以用于所有類型的水基體系金屬加工液(半合成和合成液)Watertreatmentprocesses水處理過程Presswaters水壓系統(tǒng)Industrialcleaners工業(yè)清洗劑Off-shorelubricants海上石油/天然氣鉆探用潤(rùn)滑劑Waterbasedhydraulicfluids水基液壓液Water/glycolcoolingsystems(+KSP24/531)水/乙二醇冷卻體系（可加入KSP24/531提高抗腐蝕效果）

Becrosan2128–TechnologyApplBecrosan2128–TechnologyBENEFITSVeryeffectivecorrosioninhibitionforferrousmetals, castiron,ferrousalloysatapHvalueof>8.pH值>8時(shí)，對(duì)鐵、鑄鐵和鐵合金的防銹非常有效Easyhandling,easysoluble,nondusting,odorless容易使用，容易溶解,不會(huì)產(chǎn)生粉塵，無(wú)味Nostickyresiduesafterwaterphaseevaporation水相揮發(fā)后無(wú)粘性殘留物L(fēng)owfoaming低泡Compatiblewithhardwaterupto2000ppm耐硬水能力>2000ppmNostainingonaluminum(dependingonamineused)不會(huì)造成鋁變色Notendencytoformnitrosamines不會(huì)生成亞硝胺Higherthermalstabilitythanmetalsoaps比金屬皂具有更好的熱穩(wěn)定性Becrosan2128–TechnologyBENEFullysyntheticbasedonBECROSAN?2131

全合成液的建議配方20% Triethanolamine三乙醇胺5% Monoethanolamine單乙醇胺16% BECROSAN?21312,5% Isononanoicacid異壬酸0,5% SkosanorKSP5310,5% CONTRAM?NFK55,5% Water水DIN51360T2(Chipfiltertest)防銹（濾紙鐵屑法）=>2,5%class0pH-value(3%inDI-water)pH值（在3%去離子水中） =>9,2Foambehaviour(5%in10°dH-water)泡沫 =>70ml–30ml–0mlReichert(5%inDI-water,100m,1,5kg)磨斑 =>30,6mm2/GM>100FullysyntheticbasedonBECROStartingFormulationGrinding/Machining

moreseveremachining

用于更高負(fù)荷的磨削/切削配方Component成分%ByWeight重量%Triethanolamine三乙醇胺20Monoethanolamine單乙醇胺5BECROSAN?213110Water水balanceADDCO?410P5ADDCOMLB10X10SKOSANORKSP5310,5Bactericide/fungicide殺菌劑2-3StartingFormulationGrinding/SemisyntheticbasedonBECROSAN?2131半合成配方32,0% Baseoil基礎(chǔ)油8,0% ADDCONATE?M 15,5% Triethanolamine三乙醇胺2,0% Monoethanolamine單乙醇胺7,5% BECROSAN?21282,0% BECROSAN?21312,5% TD25/307,5% Couplingagents(fattyalcohol)偶合劑15,0% Water水5,0% BECROSAN?C656(fattyacidamide脂肪酸酰胺) 2,5% CONTRAM?ST-10,5% CONTRAM?J30DAppearance外觀 Clear,yellow黃色透明Emulsion乳液 Translucent半透明DIN51360T2(Chipfiltertest)防銹 =>2,5%class0pH-value(3%inDI-water) pH =>9,3SemisyntheticbasedonBECROSUseOfAlkanolamidesInMetalworking

金屬加工液中鏈烷醇酰胺的應(yīng)用Emulsifier做乳化劑Functionsasaprimaryorsecondaryemulsifierino/wmetalworkingformulations在水包油型乳化油配方中可做主乳化劑或助乳化劑使用LubricityAdditive潤(rùn)滑劑Amidesbasedonlongerchainedfattyacidsenhancelubricationpropertiestoafluid基于長(zhǎng)鏈脂肪酸的酰胺有助于提高體系的潤(rùn)滑效果CorrosionInhibitor防銹劑Fattyacidalkanolamidesprovideextracorrosionprotectionforferrousmetals脂肪酸的鏈烷醇酰胺對(duì)黑色金屬有良好的防銹效果.UseOfAlkanolamidesInMetalwFattyamides/esters脂肪酸酰胺/酯STRENGTH優(yōu)點(diǎn)Cheapcorrosioninhibitors

是一種較便宜的防銹劑Posttreatmentapplicationpossible

可現(xiàn)場(chǎng)添加Lowclassificationlevel。Lowtoxicityprofile低毒性Someareliquid,easytohandle

有一些產(chǎn)品是液體的，易操作Usedforsemi-syntheticandsolubleoiltypefluids

可用于乳化油和半合成液

Fattyamides/esters脂肪酸酰胺/酯SFattyamides/esters脂肪酰胺/酯Product產(chǎn)品Alk.amine胺的種類Appea-rance

外觀Viscosity@40°C黏度TAN酸值TBN堿值Solubility溶解性CP-51360/2SOE+2%am.5%inw.(orig:cl.3,0,9,2)防銹（濃縮液中加2%，5%稀釋）B.210EMEAPasty膏狀-810Emuls.可乳化cl.2,pH9.2B.210MMEAPasty膏狀-153Emuls.可乳化cl.2,pH9.1B.210RDEALiquid液體3855130Emuls.可乳化cl.1,pH9.1B.210DIIDEALiquid液體1701435Emuls.可乳化cl.1-2,pH9.0B.541MIPLALiquid/pasty液態(tài)/膏狀15039Emuls.可乳化cl.2,pH9.0B.C656DGALiquid液體2005010Soluble可溶cl.1-2,pH9.2B.228DEALiquid液體39015150Dispers.水分散cl.0-1,pH9.2B.583TEA/MEALiquid液體2105052Emuls可乳化cl.0-1,pH9.1B.2021DETAWaxy蠟狀45@60°C3.524Insol.不溶cl.2,pH9.2Fattyamides/esters脂肪酰胺/酯PPerformance性能18%LUBRIZOL5475in100Nbaseoil18%LUBRIZOL5475+2%BECROSAN583in100Nbaseoil18%LUBRIZOL5475+4%BECROSAN583in100NbaseoilAppearance外觀yelow-lightbrown,clear黃色—淡棕色，透明Yelowlightbrown,clear黃色—淡棕色，透明Yellowlightbrown,clear黃色—淡棕色，透明Appearanceemulsion(5%in20°dH)乳液外觀0mloil/0.3mlcream0mloil/0.1mlcream0mloil/0.1mlcreamcorrosion-DIN51360-part2防銹5%-class25%-class15%-class0corrosion-IP287防銹breakpoint@5,5%breakpoint@4,5%breakpoint@4%pH-value-(5%in20°dH)9.209.409.40foamcharacteristic泡沫5%in10°dHnofoam無(wú)泡沫nofoam無(wú)泡沫nofoam無(wú)泡沫5%in5°dH70ml-10ml-0ml100ml-40ml-0ml100ml-50ml-0mlReichert磨斑34.0mm231.3mm228.2mm2Performance性能18%LUBRIZOL547ADDCONATE?StartingFormulation

SemiSynthetic建議起始配方—半合成Baseoil基礎(chǔ)油30.00ADDCONATE?M10.00DEG2.00TEA10.00TD25/301.00GuerbitolC162.50BECROSAN(TM)C6567.50Isononanoic異壬酸1.00EmulsogenM0.50Water水35.50Appearance外觀Clearyellowliquid黃色透明液體Appearance-emulsion乳液外觀Translucent半透明pH-value(3%in20°dH)PH值9.15Corrosion(DIN51360-2-4%)防銹Class0-1ADDCONATE?StartingFormulatioADDCONATE?StartingFormulation

SemiSynthetic建議起始配方—半合成baseoil基礎(chǔ)油32.00ADDCONATE?M8.00BECROSAN?C2141

(carboxylicacidsalt羧酸鹽)25.00TD25/302.50EmulsogenM5.003370V2.50Water水15.00MEA2.00BECROSAN?C656(Fattyacidamide)5.00CONTRAM?ST-12.50CONTRAM?J30D0.50Appearance外觀Clearyellowliquid黃色透明液體Appearance-emulsion乳液外觀Translucent半透明pH-value(3%in20°dH)PH值9.3Corrosion(DIN51360-2-4%)防銹Class0ADDCONATE?StartingFormulatioBiocides

殺菌劑Biocides

殺菌劑Biocidereview:

Biocidereview:

Biocidereview:

Micro-organismslike微生物喜歡Awetenvironment潮濕環(huán)境Temperature溫度Dust塵土Andcertainelementsasfoodstuff以及某些可以作為食物的元素WhicharegiveninallMETALWORLKINGFLUIDS 這些在金屬加工液中均可以得到滿足Biocidereview:

Micro-organismBiocidereview:

Biocidereview:

Bactericides

殺細(xì)菌劑Bactericides

殺細(xì)菌劑CONTRAM?ST-1

N,N-methylenebismorpholineN,N-亞甲基雙嗎啉CAS#5625-90-1CONTRAM?ST-1

N,N-methylenebisCONTRAM?MBO

Oxazolidine,3,3’-methylenebis[5-methyl]oxazolidine噁唑烷，3,3’-亞甲基雙[5-甲基]唑烷CAS#66204-44-2CONTRAM?MBO

Oxazolidine,3,3’ProductFeatures產(chǎn)品特性CONTRAM?ST-1ExceptionalstabilityinMWFconcentrates在濃縮物中特別穩(wěn)定Doesnotdisruptbalanceofemulsionsystem不會(huì)干擾乳液體系的平衡Long-lastingefficacy(half-lifeis5-8months)長(zhǎng)效（半衰期5-8個(gè)月）Uniquebalanceofoilandwatersolubility—importantfeatureforemulsionsystems突出的水溶性和油溶性—對(duì)乳液體系非常重要Lowtotalformaldehydecontent總甲醛含量低Evidenceforefficacyvs.mycobacteria對(duì)細(xì)菌特別有效Noskinirritation(noR43)對(duì)皮膚刺激性?。ú挥谩百N標(biāo)簽”R43）Easycompatiblewithcommonusedfungicides(NaPyrion,IPBC′s,BBit′s)

容易與抗真菌劑并用WorksquitewellinpHranges7-11在pH7-11范圍內(nèi)特別有效Concentratetreatment:2,5–3,0%濃縮物加劑量2.5-3.0%Tanksidetreatment:notpreferred不推薦用于現(xiàn)場(chǎng)添加StabilityproblemsofCONTRAMST-1assold:solidificationatcoldtemperatures

CONTRAMST-2,CONTRAMST1-50ST-1氣溫較低時(shí)，會(huì)凝固，可以使用CONTRAMST-2，ST-1/50ProductFeatures產(chǎn)品特性CONTRAM?ProductFeaturesCONTRAM?MBOBalancedperformancefortanksideorconcentratetreatment可以用于濃縮物或現(xiàn)場(chǎng)維護(hù)Greateroilsolubilitythancompetitivematerials油溶性更好TanksidecomplementtoproductsprotectedbyST-1inconcentrate(avoidmicrobeacclimationandresistance) 可以用作含有ST-1濃縮物產(chǎn)品使用時(shí)的現(xiàn)場(chǎng)維護(hù)（避免產(chǎn)生耐藥性）Hightotalformaldehydecontentforfastactivityonexistingmicrobialgrowth高甲醛含量可以快速殺死細(xì)菌Basedonprimaryamine基于一級(jí)胺Concentratetreatment:2,5–3,0%濃縮物2.5-3.0%Tanksidetreatment:0,1–0,2%現(xiàn)場(chǎng)0.1-0.2%HarderincorporationinMWFconcentratesadditionalcouplingagentsnecessary(fattyacids,ethoxylatedorfattyalcohols)需要一些偶合劑以幫助提高濃縮物的穩(wěn)定性（脂肪酸，乙氧基化物或脂肪醇）ProductFeaturesCONTRAM?MBOProductFeaturesCONTRAM?121Uniquebalanceofperformanceproperties優(yōu)異的殺菌性能Quickactivityfortanksidecontrolcoupledwithgoodstabilityinfluidconcentrates在濃縮物中優(yōu)異的穩(wěn)定性，同時(shí)可以用于現(xiàn)場(chǎng)添加ComplementtoCONTRAMST-1protectedfluidsalternatetanksidechemistrytoavoidmicrobeacclimationandresistancetooneparticular bactericidechemicaltype可以用作含有ST-1濃縮物產(chǎn)品使用時(shí)的現(xiàn)場(chǎng)維護(hù)替代品，避免某些特定種類的細(xì)菌產(chǎn)生抗藥性Greateroilsolubilitythancompetitivetriazinesforimprovedcompatibilityandstabilityinmetalworkingfluidemulsions比三嗪類殺菌劑的油溶性更好，和金屬加工乳液有更好的兼容性和穩(wěn)定性

MorestablethanHHT比HHT更加穩(wěn)定Concentratetreatment:2,5–3,0%濃縮物：2.5-3.0%Tanksidetreatment:0,1–0,2%現(xiàn)場(chǎng)：0.1-0.2%HarderincorporationinMWFconcentratesadditionalcouplingagentsnecessary(fattyacids,ethoxylatedorfattyalcohols)需要一些偶合劑以幫助提高濃縮物的穩(wěn)定性（脂肪酸，乙氧基化物或脂肪醇）ProductFeaturesCONTRAM?121ProductFeaturesCONTRAM?OF-GFast-actingperformanceagainstbacteriafortanksideapplication快速殺滅細(xì)菌，可用于現(xiàn)場(chǎng)添加ComplementtoCONTRAMST-1protectedfluidsalternatetanksidechemistrytoavoidmicrobeacclimationandresistancetooneparticular bactericidechemicaltype可以用作含有ST-1濃縮物產(chǎn)品使用時(shí)的現(xiàn)場(chǎng)維護(hù)替代品，避免某些特定種類的細(xì)菌產(chǎn)生抗藥性Amine-freeoptionforapplicationswherethisisofconcerntoformulatorsandendusers(Concentrateandtanksidetreatment) 不含胺，可以用于一些特殊要求的配方或最終客戶（濃縮物和現(xiàn)場(chǎng)添加）Near-neutralpHvaluetoavoiddramaticshiftinfluidpropertieswhenaddedtanksideandtominimizeimpactonbalanceoffluidconcentrates中性pH值，對(duì)濃縮物或現(xiàn)場(chǎng)添加時(shí)對(duì)pH值得沖擊小ParticularefficiencyagainstMycobacteria主要針對(duì)細(xì)菌Concentratetreatment:2,5–3,0%濃縮物：2.5-3.0%Tanksidetreatment:0,1–0,2%現(xiàn)場(chǎng)添加：0.1-0.2%HarderincorporationinMWFconcentratesadditionalcouplingagentsnecessary(fattyacids,ethoxylatedorfattyalcohols)需要一些偶合劑以幫助提高濃縮物的穩(wěn)定性（脂肪酸，乙氧基化物或脂肪醇）ProductFeaturesCONTRAM?OF-GProductFeaturesCONTRAM?NBF-34Formaldehydefree,basedonIsothiazolinon不含甲醛，基于異噻唑啉基Fast-actingperformanceagainstbacteriafortankside application快速起效，用于現(xiàn)場(chǎng)添加Concentratetreatment:notpreferred%不推薦用于濃縮物Tanksidetreatment:0,1–0,175%現(xiàn)場(chǎng)添加：0.1-0.175% EU:Atanapplicationlevelofmax.0.175%inthefinishedfluidtherequirementsofthe28thATPdirectivearefulfilled.ThelevelofCMI/MIisbelow15ppm.ProductFeaturesCONTRAM?NBF-3KeyPhysicalProperties:

TotalFormaldehydeContent總甲醛含量Product%CH2OassuppliedCONTRAM?101,HHT28-32CONTRAM?ST-115-16CONTRAM?MBO43-45CONTRAM?12123-27CONTRAM?OF-G42-46

KeyPhysicalProperties:

TotaPerformanceProfilePRODUCT

CONTRAM?ST-1CONTRAM?MBOCONTRAM?OF-GCONTRAM?121Hexahydrotriazene(HHT)ConcentrateStability濃縮物安定性+++++++++++TankSideEfficacy現(xiàn)場(chǎng)維護(hù)效率+++++++++++++Long-TermStability儲(chǔ)存安定性+++++---+---OilSolubility油溶性+++++++---SkinSensitisationLabeling(EU)皮膚刺激性標(biāo)簽(EU)NONONOR43@1.0%concentrationR43@0.1%concentrationPerformanceProfilePRODUCT

CONEfficacyinMIC-(minimalinhibitionconcentrationinppm)onBacteria:MICMinimumInhibitionConcentrationoftheproductsinppmonfollowingmicroorganismMIC針對(duì)下列細(xì)菌的最小抑菌濃度（ppm)Muster/bacteriaStaph.aureus金黃色葡萄球菌Ps.aerug綠膿桿菌E.Coli大腸桿菌Ps.putida惡臭假單胞菌

Ps.fluores.Klebs.Oxytocca克雷伯氏桿菌屬Legion.longb.Myco-bact.avCONTRAMST-11000100010005005001000250CONTRAMMBO

25025025025025025050100CONTRAM121500500500500500500250500CONTRAMOF-G25025025025025025050CONTRAMNBF2125010010010010010050EfficacyinMIC-(minimalinhibMICMinimuminhibitionconcentrationinppmonfollowingmicroorganisms:MusterAcremoniumspec.枝頂包屬Candidaspec.念珠菌屬Fusariumspec.鐮刀菌屬CONTRAMST-1200020002000CONTRAMMBO5001000500CONTRAM121100010001500CONTRAMOF-G5001000500CONTRAMNBF21500100100EfficacyinMIC-(minimalinhibitionconcentrationinppm)on:FungieMICMinimuminhibitionconcentFungicides殺真菌劑

SelectionConsiderationsCONTRAMNFKfungicideandCONTRAMJ…(IPBC′s)fungicideFungicides殺真菌劑

SelectionConCharacteristicsofCONTRAMNFKfungicideStabilizedsolutionofsodiumpyrithioneinwater吡啶硫酮鈉的水溶液Watersoluble溶于水Veryeffectivefungicide(yeastandmold)高效殺真菌劑（酵母菌和霉菌）Notconsidered‘fastacting’duetomodeofaction非快速殺滅Sometimesantibacterial有時(shí)對(duì)細(xì)菌有效Non-irritatingandnon-sensitizingtohumans對(duì)人的皮膚沒有影響Hasbeenshowntohavenopotentialforskinsensitization,evenat760timesthenormalenduselevel即使?jié)舛雀哂谕扑]的760倍，也沒有發(fā)現(xiàn)皮膚過敏CharacteristicsofCONTRAMNFKCharacteristicsofCONTRAMNFKfungicideIroncanbeintroducedintometalworkingfluidconcentratesthroughrawmaterials通過原料可能帶入鐵離子Resultingingrayorblackformulations導(dǎo)致工作液顏色變灰或發(fā)黑Water-insolubleironpyrithionemayprecipitate非水溶性的吡啶硫酮鐵可以析出Canbereversedwithadditionsofironspecificsequesteringagents

可以通過添加鐵離子螯合劑來還原工作液的外觀EDTA(Naformbest)最好使用EDTA鈉鹽-> NFKfungicideisstabilizedinthisform,thereforecanberecommendedforuseincastirongrindingoperations

可以推薦NFK用于鑄鐵磨削加工CharacteristicsofCONTRAMNFKCharacteristicsCONTRAMNFKpHProductpHisalkalinetypically9-11產(chǎn)品的pH范圍9-11WorkswellinpHrangeofmostformulations在廣泛pH范圍內(nèi)有效Goodthermalstability熱穩(wěn)定性好Thermaldecomposition(powder)~250C熱分解溫度（粉末）~250CGoodstabilityinformulationswhichmightbeshippedorstoredinwarmclimates在配方中的穩(wěn)定性好，可以儲(chǔ)存在溫暖的氣候條件CharacteristicsCONTRAMNFKCharacteristicsofIPBCindustrialfungicideHereonoutreferredtoasIPBCIodopropynylbutylcarbamate碘代丙炔基丁基氨基甲酸酯99%powderandvariousglycolsolutionblends 99%活性含量的粉末和各種濃度的溶液Moreoilthanwatersoluble油溶性Contains1atomofiodinepermoleculeofIPBC 每分子的IPBC含有1個(gè)碘原子Veryeffective,relativelyfastactingfungicide高效，相對(duì)快速殺滅真菌CharacteristicsofIPBCindustCharacteristicspHNoinherentpHPrefersneutralpHformulations更傾向用于中性pH配方ChemicalinstabilitywhenpH>9.0pH>9.0可能會(huì)導(dǎo)致不穩(wěn)定Moderatethermalstability

(powder)粉末IPBC的熱穩(wěn)定性中等Temperatureofdecomposition~150C熱分解溫度~150CMeltingpoint~65C熔點(diǎn)~65CNotwellsuitedforstorageinformulationswhichmightbeshippedorstoredinwarmclimates不太適合用于海運(yùn)到或儲(chǔ)存于熱帶地區(qū)的產(chǎn)品中CaremustbetakenwhenmakingMWFconcentrateswhichrequireheat對(duì)需要加熱調(diào)配MWF濃縮物時(shí)，必須當(dāng)心SolubleOilandSemi-syntheticblends可溶油和半合成液Whenpossibleallowblendtocool<45C冷卻到<45C后再加入Wcess在調(diào)配工序的最后階段加入CharacteristicspHBiocideCharacteristicsThemodeofactionofthesetwoproductsisquitedifferent這兩種產(chǎn)品的作用機(jī)理有所區(qū)別IPBChasnotbeenstudiedindetail,butinsimpletermsisaniodinedeliverysystemIPBC的作用機(jī)理簡(jiǎn)單理解為引入碘NFKdisruptsthecellprotonmodeofforce,cellslosetheabilitytostoreenergyandcarryoutvitalfunctions(cellsstarvetodeath)NFK可以破壞細(xì)胞質(zhì)，導(dǎo)致細(xì)胞喪失儲(chǔ)備能量和活力的功能（最終會(huì)被餓死）DuetothismechanismanadvantageisthatNFKwillnotgiverisetoacquiredresistance基于上述機(jī)理，不會(huì)產(chǎn)生抗藥性Thisalsoexplainswhyit’snotaveryfastactinganti-microbial也就可以解釋為什么不是快速殺滅真菌劑BiocideCharacteristicsThemodRecommendedUseLevels

推薦劑量NFK MWFconcentrates濃縮物0.50-1.0%0.50-1.0%,productassoldPostTreatment現(xiàn)場(chǎng)處理500-1000ppm500-1000ppm,productassoldIPBCMWFconcentrates濃縮物0.15-0.5%（相對(duì)于粉末）IPBC0.15-0.5%(aspowder)75-250ppmaiin20:1dilutionNotusuallyrecommendedasapost-treatmentadditive通常不推薦用于現(xiàn)場(chǎng)添加RecommendedUseLevels

推薦劑量NFKNFKUseinMWFConcentratesandasaPostTreatmentAdditive

NFK可以用于濃縮物或現(xiàn)場(chǎng)維護(hù)NFK

ishighlywatersolubleNFK高度水溶sodiumsaltmostwatersolublepyrithionederivative吡啶硫酮鈉鹽衍生物水溶性好ItisusedsuccessfullyinSyntheticandSemi-Syntheticformulations可以用于合成和半合成液Someincompatibilitieswithsolubleoilconcentrates有可能和可溶油不兼容Alkalinenatureofbiocide殺菌劑的堿性Watercontent水含量 Wellsuitedforpost-treatmentuse特別適用于現(xiàn)場(chǎng)添加NFKmaynotbethebestchoiceifcustomerusesCMIT/MITtoshockdosesystems.ThepresenceofNFKcausestheisothiazolinetodegrademorequickly. NFK對(duì)于使用CMI/MIT的客戶來說，可能不是最好選擇。NFK會(huì)導(dǎo)致異噻唑啉類殺菌劑降解失效NFKUseinMWFConcentratesanIPBCUseinMWFConcentrates

IPBC用于MWF濃縮物IPBCisbestusedwhenformulatedintoapetroleumoilbasedMWFconcentrates IPBC最適宜用于含礦物油的配方中SolubleoilandSemi-Syntheticconcentrates可溶油或半合成液NotusuallyrecommendedforSyntheticconcentrates

通常不推薦于全合成液 Solubilitylimitations溶解性受限制Chemicaldegradationbroughtaboutbyhydrolysis水解會(huì)導(dǎo)致化學(xué)降解IPBCUseinMWFConcentrates

IIPBCasaPostTreatmentAdditive

IPBC用于現(xiàn)場(chǎng)維護(hù)IPBCismoreoilsolublethanwatersoluble

IPBC更加偏向油溶性Reportedsolubilityinwateris~150ppmIPBC在水中的溶解度~150ppmWhilesolublewithintherecommendeddosingrangeitisnoteasilyincorporatedintoaqueoussystems不方便用于水溶性體系UsediluteglycolsolutionproductssuchasCONTRAMJ20D

推薦使用二醇類溶液，如CONTRAMJ20Dbestusedinsolubleoilorsemi-syntheticemulsions最好用在可溶油和半合成液配方goodmechanicalagitationinareaofadditionimportant充分?jǐn)嚢杌蚍稚ecommendeddose75-120ppmaiIPBC推薦加量為75-120ppm，相對(duì)于IPBCIPBCasaPostTreatmentAdditFactorsAntagonistictoNFK

影響NFK的因素Oxidizingagents氧化劑Strongreducingagents強(qiáng)還原劑Somesurfactants(estersandethersofPEG)表面活性劑（酯和聚乙二醇醚）likelyduetoresidualperoxides可能是由于殘留的過氧化物的影響Ionicmetalspecies金屬離子的種類 FactorsAntagonistictoNFK

影響FactorsAntagonistictoIPBC

干擾IPBC的因素observedincompatibilityofIPBCwith…. 和IPBC不兼容的……Alkalisandalkalinemetalhydroxides堿金屬和氫氧化物PrimaryaminessuchasMEA,MIPAandmorpholine一級(jí)胺如MEA，MIPA和嗎啉等Alkalimetalcarbonates堿金屬碳酸鹽Organiccompoundscontainingdoublebonds含雙鍵的有機(jī)物Oxidizingagents氧化劑ActiveSulfur活性硫IPBCwillrapidlydegradeinMWFconcentrateswhichcontainedactivesulfurcompounds(EPcompounds) 在含活性硫（極壓劑）的MWF濃縮物中，IPBC會(huì)快速降解Temperature(lowmeltingpoint,limitedheatstabilityinMWFconc.iestoragetemperature)溫度（低熔點(diǎn)，在濃縮物中的熱穩(wěn)定性如儲(chǔ)存溫度都有影響）FactorsAntagonistictoIPBC

干IPBCStabilityinMWFConcentrates

IPBC在濃縮物中的穩(wěn)定性SolubleOil

可溶油Littletonowaterpresentinformulation在不含水的配方中影響很小Lowlevel(%)ofamine