工業(yè)涂料創(chuàng)新技術(shù)大會

萬華化學工業(yè)涂料綜合解決方IndustrialcoatingWanhuaChemicalGroup SurfaceMaterialJeffZhangOct23,2014 能能 Netprofitbelongingtotheparentcompanyfrom1999to

歸屬于母公司凈利潤（Netprofitgrowsannuallybyacompoundrate29.5percentoverthepast13yearsfrom2001to2013.

增長率（百分比右軸

Thenetprofitof2013is28.7timesthatof

0

10,07315,433

BusinessStructureofWanhuaWanhuaWanhuaChemical

PetrochemicalsandAcrylicAcid(AA)ButylAcrylate(BA)EthylAcrylate(EA)…

SpecialtyADIADI(HMDI,HDI,IPDI,SpecialAmines(IPDA,HMDA,MDA,MDBA,SpecialAmines(IPDA,HMDA,MDA,MDBA,（waterbornePUandPAdispersions,表面材料事業(yè) Basic 依托上游聚氨酯和丙烯酸酯原料優(yōu)勢，延伸產(chǎn)業(yè)R&D

（Industrial

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（Textile&Artificial

al））（Interiorpaints

AutoOEM

（Waterbornefootwear（Textilepigmentcoatings

（Hair（Exteriorpaints（Primer

（Wood（Plastic（Floor（Glass（Printing（Electronic

otiveinterior

（Textile

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反應型樹脂

WB

表面材料事業(yè)部國內(nèi)布ChengduplantinJune2017-工廠ZhuhaiplantInJuly倉庫Commercialandtechnicalservicecenter

研發(fā)中心R&DYantai寧波工廠NingboplantinJuneinJuly2013)CommercialandtechnicalserviceNingboAqueousDispersionPlantof50,000TonsProducts金屬涂料產(chǎn)品 -- - -- -- Lightdutyanticorrosionsystem輕防腐體

LightLightdutyanticorrosionpaint,Wantipro?Wantipro?HighperformancelightdutyanticorrosionWantipro?HigherHardness硬ExcellentadhesiononmetalHigherExcellentsalt HigherWantipro?Outstanding Goodsalt Goodstability ,30dSalt , Water

1水/21水/213464786952Black12345Tego67水/8VesmodyTMThicknessofdryfilm,40um,on

pHafterRT40

干膜厚度40umdrying:T=25CRH=55%

Visco,stomer,25°C,RT40dWantipro?Execllentadhesion馬口鐵

碳鋼

鋁Testmethod:GB/T9286-1998,RT7days測試方法：GB/T9286-1998,制膜后，室溫養(yǎng)護7天。PVC=16%Excellent 5saltwater,7d5%鹽水,7d

5%H2SO4,

Water,Testmethod:GB/T9274,RT7daysthicknessofdryfilmis40um,ontinplate.PVC=16%測試方法：GB/T9274將室溫放置7d的漆膜(干膜厚40um馬口鐵)Wantipro? Goodsaltfog 7D

ExcellentorientationofAlWanriproWanripro? Thicknessoffilm干膜厚:80umAluminumphosphate三聚磷酸鋁5%Zincphosphate磷酸鋅:5%Titaniumdioxide鈦白粉物水BYK-AMP-CF-HEUCOPHOS?拜物水BYK-AMP-CF-HEUCOPHOS?拜爾樂滑石粉(1250目Black%1556供應去離子分散劑/畢克化pH調(diào)節(jié)填膨潤土/美洋時炭黑/德固攪拌狀態(tài)下依次加入,研磨至細度20um以Wantipro? 樹脂/萬華化二乙二醇丁 成膜助TegoFoamex 消泡劑/迪NALZIN?FA VesmodyTM 增稠劑/萬華化VesmodyTM 增稠劑/萬華化 指 Smoothsurface,nosaggingGoodstabilitySalt 工藝：浸涂后掛起表干10-20min,然后80-100C施工粘度：17-25s(可根據(jù)所需膜厚及現(xiàn)場施工環(huán)境調(diào)節(jié)55 Excellentstability Diluteto20s,50°C3weeks,nosettling,nosegmentationnopigskinnoviscochange開稀至20s，熱儲ExcellentcompatibilityMixedwithacommercial paint,RT7days,themixisstable,noviscochange,andtheglosskeepsthe光澤/粘度光澤/粘度Wantipro?0612For 用于浸Salt 24h耐鹽霧性WantiproWantipro? Thickness膜厚Wantipro?

Postselfcrosslink性硬 Water柔韌 耐SaltwaterGoodbalanceofflexibilityandWantipro??Bettersaltfog andPerformanceofanticorrosionpaint附著力（碳鋼/馬口鐵 0- 附著力（碳鋼/馬口鐵 P/B=1顏基比=1Thicknessofdryfilm干膜厚度40umDryingconditions干燥條件:7d,T=25CWantipro? Excellentsaltfog 240h

物 供應 1212BYK-顏料分散劑344滑石粉125065Ti-Pure鈦白粉6三聚磷酸鋁AWP-6758Tego消泡劑121345Tego消泡劑6NALZIN?FA防閃銹助劑/7VesmodyTMU604:水增稠劑/P/B=1顏基比=1Thicknessofdryfilm干膜厚度40um.Dryingconditions干燥條件:7d,T=25C,RH=60%

指 1 Wantipro?0618+Wantipro?Evenbettersalt 優(yōu)優(yōu)異的防腐底漆：Wantipro?Excellent優(yōu)的度面漆：Wantipro?Higher優(yōu)的度面漆：Wantipro?Higher較高的硬WBindustrybakingpaint水性工業(yè)烤W(wǎng)antiproWantipro?OutstandingOutstanding卓越的化學抗ExcellentFlexibility,0.5mm >50/>50kg·cm項目項目結(jié)果g 95%,1kg耐醇擦g

≥2000times, H2SO45 NaOH5Saltwater 5%NaCl耐鹽水Salt

24h,no12h無變化,24h輕微起泡,可恢復48h,no48h,no to1kg耐MEK≥200slightgloss to1kg耐MEK≥200slightglossloss噴涂，室溫干燥30分噴涂，室溫干燥30分鐘，140C烘烤30分鐘，隔天測試性能Spraying,RT30min,140oC30min,testTestmethod:ASTMD5402-2006,load500g100次，漆膜無變2000次，漆膜無100times,nochange2000times,no200次，漆膜有失200times,slightglossMEKAlcohol物%供應123ButylCellosolveTM456CYMEL71防腐助劑 指標1Wantipro?0676+Antkote?2033:wheelhubForwheelhubGoodappearanceandbuildingupproperty Goodflexibility&recoatabilityAntkote?BuildingupAntkote?BuildinguppropertyAppearanceWantipro?FlexibilityRecoatability重涂項目項目 結(jié)果Salt

240h,nobubbleand NaOH,0.1mol/L

24h,no,H,H2SO40.1mol/L48hslightglossNo.9348h,no40°C40°C144h,no

2h,noWantipro?0676+Antkote?2033:wheelhubGoodstabilityforaluminum RT30days,apply.Thesameappearanceand國產(chǎn)鋁銀漿配漆，室溫放置一個月，噴涂，漆膜外觀及性能無變化Good WBindustrybakingpaint水性工業(yè)烤Recipeforaluminumpaint銀粉漆參考配 Recipeforwhitepaint白漆參考配物物%供應123445678993水12水/345JNW 物 供應 1分散劑2水/3Ti-Pure鈦白粉456CYMEL8748292潤濕劑消泡劑Machineryandtransport工程機械及交抗性硬度外觀OH羥基丙烯酸（組分 聚異酸酯（組分OH

HH

OH交聯(lián)反OH羥基反應 異酸酯反應

化學交聯(lián)–NH-C-與水性體系互溶性Aquolin?self-emulsion與水性體系互溶性Aquolin?self-emulsion能度，100%>100/100andGood優(yōu)異的機械穩(wěn)定性OutstandingGoodappearanceandbuildingup優(yōu)異的外觀豐Highgloss>90%,清漆光澤and 優(yōu)異的耐紫外和耐候Antkote?2KPUsystem雙組分聚氨酯卓卓越的化學抗2KPUindustrypaint雙組分聚氨酯體系工業(yè)Goodappearanceandbuildingupproperty Excellent andweatherability物%供應 物%供應 BYK Ti-PureR- BYK BYK BYK BYK Aquolin?萬華 根據(jù)實際需求，添加適當粉料。23℃條件下，活2KPUindustrypaint雙組分聚氨酯體系工業(yè)NCO/OH=1.5，表干30min+80℃/30min，膜厚=40-測試項目 值potlife涂膜干燥條件drytouchGB/T1728實干hard7GB/T1728鉛筆硬度pencilHGBglossGB附著力（adhesiveGB/TGB/Timpactkg.cm,GBGB（23℃）耐堿（5%NaOH耐酸（5%H2SO4化NopulverizationGB/T耐UV2KPUindustrypaint雙組分聚氨酯體系工業(yè)不同產(chǎn)品耐UV測試對321

X-X-7X-76X-50 其中，X-5、X-6、X-7、X-76為市面競

2KPUindustrypaint雙組分聚氨酯體系工業(yè)物物%供應12BYK34Ti-PureR-234TegoWet5BYK6BYK75891Aquolin?2Formulationofmotor 各類水性木器漆與溶劑型體系的

0

/ WB WB2K SB2KPU WBProductsforWoodCoatings木器漆產(chǎn)Lacper?Lacper?Highhardness.FastLacper?家andbuildingupLacper?Excellentbuildingup.GoodLacper?Excellentstackability.LowVOCHighhardnessand Lacper?GoodadhesiononMetal/Glass/SBpaint/Plastic.Exellentchemical.木器戶Lacper?Flexibility.GoodearlywaterwhiteningDurabilityagainstweather..Lacper?VerylowVOCneeded.Flexibility.GoodwaterDurabilityagainstweather.Good.WBUrosin?Goodadhesionon地Compatiblewithpigment/dye.Re-WBUrosin?Highhardness.DustfreebeforeUVWBUrosin?Forhighglosscoating.GoodchemicalHighhardness..插VeryfineparticleHydrophilicPolyisocyanate親 PolymerbasedonHDIAquolin?Polyethermodified.GoodchemicalHydrophilicallymodifiedpolyisocyanatebasedonHDIAquolin?Sulfonatemodified.GoodwaterHydrophilicallymodifiedpolyisocyanatebasedonMDIAquolin?TDIfree.Gooddrying.CouldbeusedwithLacper?4316asisolationsealer.WanhuaWB1K萬萬華水性2KWanhuaWB2K萬萬華水性UVWanhuaWBUVWanhuaWB1K: Solids,%MFFT, Lacper?

PUD

Outstandingbuildingupproperty,handfeeling,flexibility.ForLacper?Lacper? Excellentstackability,hardness,fastdrying,lowodour.ForLacper?

Aqueousacrylic

Flexibility,Goodearlywater ,Durabilityagainstweather.CouldbeinhighPVCsystem.Forfurniture,DIY,exteriorLacper?Lacper?4316Styrene-acrylatecopolymer Fastdrying,hard,goodsandability.Forfurniture,Lacper?

Acrylicemulsion,self-

,flexible,durabilityagainstweather,goodadhesionondifficultsub.furniture,windowLacper?Lacper?4501Acrylicemulsion,self- LowVOCpossible, .Forfurniture,Lacper?

Acrylicemulsion,self-

Stackability,lowVOCpossible, .ForLeasys?Leasys?5530PUD Fineparticlesize,goodcompatiblitywithcosolvent/dye/pigment.ForWanhuaWBLacper?4221:HighhardnessandLacper?4221:HighhardnessandlowcosolventFastdrying,outstandingCouldbeusedas2KwithAquolin?APEO,NMPandOrganotinTypicalViscosity(25°C),MFFT,PencilImpact,OutstandinghandfeelingandbuildingupGoodadhesiononPU,PVC,Couldbeusedas2KwithAquolin?APEO,NMPandOrganotinTypicalViscosityViscosity(25°C),Non-volatilecontent,MFFT,Pendulumhardness,PencilBImpact,Flexibility,WanhuaWB

6420

Buildingup Early Lacper?Lacper? Lacper?WanhuaWB1K:Lacper?Lacper?4210couldbeusedWithAquolin?268, willbeAdd5%hardenerinLacper?421080%80%Mixby-535355532Gloss20°/60°,--Particlesizein2K,-BFF-Water,555-50%,355-Acetic 30%, ,5%,555-Case:Add5%Aquolin?268/MPA80%inLacper?4210Water atRTisincreasedfrom5daysto7daysonwood-plasticWanhuaWB1K:Lacper?GoodOnonPC/PC+ABS/PVCAquolin?268couldimprovetheadhesiononPVC/PU/plastic-wood.SilaneCouplingAgentZ-6040couldimprovetheadhesiononmelamine. Onpine+PU,Lacper?Aquolin268couldimprovetheearly

OnPVC,whitetopLacper?4210+Aquolin?268(2%to

+Z-6040(4%toWanhuaWB1K:Lacper?Lacper?4210onexcellent

Lacper?4210ontinplateWanhuaWB1K:Lacper?Lacper?4221couldbeusedWithAquolin?268,chemical Andtheglosskeepsthesame.Aging7daysatAcetic Hot Dry50%,30%,Acetic Hot Dry50%,30%,5%,70°C0%268(70%in Withoutmatting 5%268(70%in 5555510%268(70%in 5555550%268(70%in 5555With0.7%CP4- 5%268(70%in 555510%268(70%in 55555*75%Lacper?4221inthe**Thepartoffilmiswhitewhenthediscis***Droptheboilingwateronthefilmandkeepaglassbottlewith250mlboilingwateronit,removethebottleafterWanhuaWB1K:Lacper?Sub:HDF,with2layersofWBUVlacquerbasedfromUrosin?4699,100g/m2foreachlayer.ApplyWBlacquersby150umapplicator.Flashoff3minat25C,then40C40min,cooling3min.StackatRT24hand50C15h,pressure0.12kg/m2.50C 25CLacper?CompetitorCompetitorWanhuaWB1K:Lacper?HardnesscLacper?4221Lacper?4221Lacquer+5%268(70%inLacper?4221Lacquer+10%268(70%in75%Lacper?4221intheApplyonglassby100umspiralapplicator,andagingat25°C,RHWanhuaWB1K:Lacper?ExcellentSolidDipSB2KPUas1stSpray3layers2KWBGoodbuildingupGoodbuildingupGoodhidingGood?Stable,noGoodfilmFastLacper?4055在白色ApplicationofLacper?4055inwhiteRaw% 172Orotan 3BYK 4TegoAirex 5Talc12506Ti-PureR- 7Talc1250Grinding30min,addwaterif8Lacper?429BYK 4LaponiteS048210%water2VesmodyTMU60430%water0.651Freshvisco,2Viscoafter8daysatRT,WanhuaWB1K:Lacper?Lacper?4055在戶外漆中的ApplicationofLacper?4055inExteriorwood優(yōu)異的早期耐水白性Outstandingearlywater清漆，粘度:70-80KU。Clearlacquervisco70-80KU.Brush2layersonpine,includingtheedges.DryingatRTor50°CovernightforeachImmerseinwaterovernight,noWanhuaWB1K:Lacper?Lacper?4055在戶外漆中的ApplicationofLacper?4055inExteriorwood戶外暴281天（至2014-6-10），煙臺，距海1.8km，松木Outdoorexposure281days,Yantai,1.8kmtothecoastonpine啞光白漆

啞光紅漆 WanhuaWB1K:Lacper?快Fast打磨ExcellentCouldbeusedwithAquolin?296asisolationsealer

耐水GoodPencilhardnessHB光澤Highgloss,Lacper?4316,P320onmapleveneer

Lacper?4316,P320onrubberwoodWanhuaWB1K:Lacper?清底 RawRaw rRaw r1Lacper?2Highspeed10min,check

50

Lacper?Highspeed10min,check

267267TegoAirexPremix3-7,addingslowlyathighspeed,10min,

3 45367TegoAirexPremix3-7,addingslowlyathighspeed,10min,checkcraters,thenmiddlespeedcraters,thenmiddle8Lacper?9TegoGlide10

30

Neptune5223NRHighspeedLaponiteS48210%Middle

2.5211VesmodyTMU604

0.75

Lacper? TegoGlide VesmodyTMU604 1viscosity23°C,DIN4

Viscosity23°C,DIN4Gloss,

WanhuaWB1K:Lacper?ExcellentflexibilityandhigherGood Lacper?Lacper?AcrylicAcrylicAcrylicMFFT,Breakingelongation, ,Hardness,k?nig,WanhuaWB1K:Lacper?戶外暴曬128天無開裂，煙臺，距海1.8kmOutdoorexposure,128days,nocracks,1.8kmtothecoast,on附著力優(yōu)異，與 劑搭配附著力更好GoodadhesiononUV/plastic-wood/PVC,BetteradhesionwithAquolin?Lacper?4400+Aquolin?296(7%to

Onbirch+UV,mattop,glossLacper?4400+Aquolin?268(5%toWanhuaWB1K:Lacper?CompetitorCompetitorCompetitor543210均衡的性低成膜助劑需求配方寬容度Excellent GoodcomprehensiveLowVOCEasytobeGloss,Alcohol50%Aceticacid30%5NaHCO35%5Coffe4Water5

2layerslacqueronmapleveener,ageing7days.1%TS-100and2%Neptune5223NRintherecipe.WanhuaWB1K:Lacper? 物 供 物 供應,22 6 指 Gloss, 供應 指 1Visco,overnight, 1Lacper?2333465Surfynol1046CP4-17TegoAirex8Vesmody1Lacper?23334BYK56

啞光Mat66TegoAirex7VesmodyTM,8Lacper?9WanhuaWB1K:Lacper?優(yōu)異的抗粘連GoodSprayonblackwalnutveneer,110g/m2,1layer.Pressure0.33kg/cm2，stack@50°C,4h.136Lacper? Lacper?4500/4210 WanhuaWB1K:Leasys?Leasys?5530非常適合用 Leasys?5530is Veryfineparticlesize,<30nm,goodpermeabilitytoGoodcompatibilitywithWanhuaWB2Ksystem:Hydrophilicallymodifiedpolyisocyanatebasedon

WB2KsolutionofFixedNCO/OH,complexrecipedesignmixingonHighHighlevelofhardenerneeded,highHighpriceSlowSlowdrying,lowproductionFastWanhuaWB2Ksystem:A組份BindersforAMFFT,Lacper?PUDOutstandingstackability,Lacper?Styrene-acrylatecopolymerFastdrying,goodLacper?

Acrylicemulsion,self-

,goodadhesionondifficultLacper?Lacper? Acrylicemulsion,self- LowVOCpossible,B組份 HardenersforB NCO, HydrophilicallyHydrophilicallymodified,polyisocyanatebasedon Excellentwaterdispersion,

Hydrophilicallypolyisocyanatebasedon

Fastdrying,excellentwaterdispersion,economical,TDIfreeWanhuaWB2KALacper? Lacper?ALacper? Lacper?BAquolin?77freshDIN4,Gloss,visco35°C4h,DIN4,Gloss35°C4h,PencilABPencil2K,FFPencil2K,after35°CFFFastImproveImproveImproveSealingVeryeasytomixbyLongpotWanhuaWB2Ksystem:Mapleveneer,spraysealer,80g/m2,drying35°C0.5h,spraytop,80g/m2干燥35°C1h，Drying35°C1h, Drying35°C1h,23°C7day, Lacper? Lacper?43167%Aquolin?WanhuaWB2Ksystem:Hardness&

0Lacper? Lacper?4316+7%Aquolin?100umwetfilmonglass,ageing@23°C可使用時Longpot35°C4h，粘度沒有變化；底部沒有沉淀。ViscokeepsthesameandnosettlingKeepthesealingpropertytotannin-acid35°C4h，對木塑基材保持一定的附著力。Keeptheadhesiontoplastic-可使用時間取決于具體的指標要求 2K體系35°C4h的沉淀比較。左:Lacper?4316,右:Lacper?Thesettlingof2Ksystemafter35°C4h.Left:Lacper?4316,right:Lacper?WanhuaWB2KSealer:IsolationLacper?4316+Aquolin?WithoutLacper?4316Aquolin?296WithoutLacper?4316Aquolin?296Lacper?4316Aquolin?2964hWithoutLacper?4400Aquolin?296Lacper?4400Aquolin?2964h

基材及工藝：SubstrateandMapleveneer,P240sanding,spraytannin-acidwatersolution,封閉清漆，60-70g/m2，40°C30min，噴一道白面漆Spray2Ksealer,60-70g/m2,drying@40°C30min,spraywhitetop.評估70°Covernight,checkbleeding.結(jié)論35°C4h的放置使得2K體系對單寧酸的Thesealingpropertyisdecreasedaafter35°C4h.Lacper?4316asApartisWanhuaWB2KSealer:Isolation柏木Chinese WanhuaWB2KSealer:IsolationLacper?4500+Aquolin?

(DIN4s)隨時間(h)的變ViscositychangewithLacper?4500Aquolin?Lacper?4500Aquolin?Without基材及工藝：SubstrateandMapleveneer,P240sanding,spray2.Spray2Ksealer,60-70g/m2,drying@30min,spraywhite評估70°Covernight,checkbleeding.A%Lacper?22B%Aquolin?2687642001234567 WanhuaWB2KAquolin?268在2K中的應用ApplicationofAquolin?268in2Ksystem:TypicalAquolin?Solids,Viscosity63#12r,cPViscosity62#50r,cP25°C80%solidinMPAParticlesizeinwater1, DilutethehardenerbyMPAto80%solid,andthenmixbyinwater.Hardenersolutiontowater,1:10by

Lacper?4210+Aquolin?268WetfilmWanhuaWB2K &在Lacper?4210清漆中加入 劑。Add5%hardenerinLacper?4210Aquolin?268具有更優(yōu)異的分散性。BetterdispersionforAquolin? and80%80%Mixby-535355532Gloss20°/60°,--Particlesizein2K,-BFF-Water,555-50%,355-Acetic 30%, ,5%,555-Case:Add5%Aquolin?268/MPA80%inLacper?4210lacquer.Water atRTisincreasedfrom5daysto7daysonwood-plasticWanhuaWB2KTop:TheadhesionofWanhua2KtoponUV/PU/PVCisperfect.OnOnPVC,whiteLacper?4210+Aquolin?268(2%toOnpine+PU,clearLacper?4210+Aquolin?268(5%to

Onbirch+UV,mattop,glossLacper?4400+Aquolin?268(5%toWanhuaWBUV:Solids,Urosin?7.0-Multicoatortopforpanelfurniture,kitchenUrosin?7.0-Highgloss,multicoatortopforpanelfurniture,kitchenUrosin?6-Adhesionandstainsealerforfloorandfurniture.Byrollerandmoose櫥柜Kitchen 地板WanhuaWBUV:Urosin?無APEONMPAPEO,NMP,Organic-tinGoodmattingagentarrangement,highmatting DustfreebeforeUV Urosin? Gloss60°, ,555550%,5533,555550%,5533 4%, 15555PencilH5555Finenessofthemat/5/3FilmbeforeUVdustdust :keepthemetalcupwithboilingwateronthefilmwithandwithoutwater,15min.WanhuaWBUV:Urosin?Highgloss,mirrorRawRaw%r1234BYK5TegoAirex6Iragcure7VesmodyTM8LaponiteS048210%in,9VesmodyTM12Gloss,PC+ABS,Lacper?4210assealer,Urosin?4695astopGlossPC+ABS,Lacper?4210assealer,Urosin?4695aswhitetopGloss60°/20°94%/87%WanhuaWBUV:底面合一施工工藝：Multicoat基材打磨P240。Woodsanding噴涂第一道，80-90g/m2。Spray1stlayer,80- ，50%能量，≥400mJ/cm2。Flashoff,1min,50°C,15min,2*Hgcuring,50%energy,≥400mJ/cm2.底漆打磨P320。Sanding噴涂第二道，80-90g/m2。Spray2ndlayer,80- ，50%能量，≥400mJ/cm2。Flashoff,1min,50°C,15min,2*Hgcuring,50%energy,≥400mJ/cm2.下線。StackandWanhuaWBUV:Urosin?Urosin?Urosin?4632isanaliphaticurethaneacrylatedispersiondesignedforfloorandfurniturewithoutstandingwoodwetting,highflexibilityandhardness.Ithasgoodcompatibilitywithpigmentsanddyes.Forfloor:adhesionForFurniture:stainFloor

MooseWanhuaWBUV:Urosin?StabilityofCompetitorUros