吡蟲啉、啶蟲脒生產(chǎn)工藝論述

山東農(nóng)業(yè)大學(xué)學(xué)士論文目錄TOC\o"1-5"\h\z摘要 1英文摘要 2第一章序言 31我國(guó)農(nóng)藥發(fā)展概況 32毗蟲咻、啶蟲脒性質(zhì)介紹 52.1毗蟲咻性質(zhì)介紹 52.2啶蟲脒性質(zhì)介紹 6第二章實(shí)習(xí)部分 71企業(yè)介紹 72生產(chǎn)原理 92.12-氯-5-氯甲基毗啶合成原理 92.2毗蟲咻的合成原理 112.3啶蟲脒的合成原理 113生產(chǎn)工藝流程簡(jiǎn)述 113.1 二氯生產(chǎn)車間 113. 1.1雙環(huán)戊二烯裂解單元 113. 1.25-降冰片烯-2-醛合成單元 133. 1.32-氟乙基-5-降冰片烯-2-醛合成單元 143. 1.42-亞甲基-4-氟基丁醛合成單元 153. 1.52-氯-2-氯甲基-4-氟基丁醛合成單元 173. 1.62-氯-5-氯甲基毗啶環(huán)合單元 183.2 DMF法合成毗蟲咻車間 203. 2.1流程示意圖 203. 2.2各單元工藝規(guī)程 203.3 啶蟲脒的合成 223. 3.1流程示意圖 22吡蟲麻、啶蟲瞇生產(chǎn)工藝流程論述TOC\o"1-5"\h\z3.3.2各單元工藝規(guī)程 22第三章實(shí)習(xí)心得及建議 241實(shí)習(xí)心得 242個(gè)人建議 25參考文獻(xiàn) 26致謝 28II山東農(nóng)業(yè)大學(xué)學(xué)士論文ContentTOC\o"1-5"\h\zAbstract 1Abstractin English 2Preamble 3Theoverviewofpesticidesinourcountry 3TheintroductionofthefeaturesofIdaclopridandAtamiprid 5TheintroductionofthefeaturesofIdacloprid 5TheintroductionofthefeaturesofAtamiprid 6Part of Internship 7Introduction of company 7Principle of the production 9Principleofthetheproductionof2-chloro-5-chloromethylpyridine 9Principleofthesythesisofimidacloprid 11Principleofthesythesisofacetamiprid 11Briefintroductionontheprocesses 11Productionworkshopof2- chloro-5-chloromethylpyridine 11Part of the cracking ofdicyclopentadiene 11Part of the synthesis of5-norbornene-2-aldehyde 13Part of the synthesis of2-cyanoethyl-5-norbornene-2-aldehyde 14Partofthesynthesisof2-methyl-4-cyanidehyborxybutyricaldehyde 15Partofthesynthesisof2-chloro-2-chloromethyl-4-Cyanidehybroxybutyric aldehyde 17Partofthesynthesisof2-chloro-5-chloromethylpyridine…18Productionworkshop ofDMFsynthesis ofimidacloprid 20iii吡蟲麻、啶蟲瞇生產(chǎn)工藝流程論述TOC\o"1-5"\h\zTheflowchart 20Theoperationrulesofeveryparts 20Productionworkshopofacetamiprid 22Theflowchart 22Theoperationrulesofeveryparts 22Internshipexperienceandpersonalrecommendations 24Internshipexperience 24Personalrecommendations 25Reference 26Thanks 28IV山東農(nóng)業(yè)大學(xué)學(xué)士論文吡蟲咻、啶蟲脒生產(chǎn)工藝論述摘要：農(nóng)藥工業(yè)在國(guó)民經(jīng)濟(jì)中占有重要地位，其發(fā)展與農(nóng)業(yè)生產(chǎn)和人民生活的提高密切相關(guān)。隨著人們環(huán)保意識(shí)及害蟲抗藥性的提高，農(nóng)藥品種需要不斷更新。吡蟲啉、啶蟲瞇作為新型煙堿類超高效殺蟲劑，在農(nóng)業(yè)生產(chǎn)中的應(yīng)用越來越廣泛。本文根據(jù)自己在山東海利爾藥業(yè)集團(tuán)原藥生產(chǎn)基地實(shí)習(xí)學(xué)到的一些工藝及取得的一些經(jīng)驗(yàn)，綜述農(nóng)藥工業(yè)中2-氯-5-氯甲基吡啶、DMF法合成吡蟲啉以及啶蟲瞇的生產(chǎn)技術(shù)與實(shí)際生產(chǎn)中工藝參數(shù)要求，并對(duì)現(xiàn)有的生產(chǎn)工藝提出改革建議。關(guān)鍵詞：2-氯-5-氯甲基吡啶（二氯）；吡蟲啉；啶蟲瞇；生產(chǎn)工藝ResearchontheProductionofIdaclopridandAtamipridAbstract：Pesticideindustryplaysanimportantroleinthenationaleconomy.Itsdevelopmentiscloselyrelatedwithagriculturalproductionandpeople'slives.Withenvironmentalprotectionandimprovementofpestresistance,pesticidevarietiesneedtobeco