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6.2FormationandcharacteristicsofadhesivejointFormationandcharacteristicsofadhesivejoint1CompositionItiscomposedofadhesivelayer,interfaceareaandsurfacelayerofadherent.AdhesionCohesionAdhesion+cohesion=adhesionforceFormationandcharacteristicsofadhesivejoint1Composition

Twotypesofdamage1“Cohesivefailure”Cohesion<adhesionDamageofadhesivelayeroradhesivelayer2“Adhesionfailure”Cohesion>adhesionInterfacelayerfailure

destructionSlimecohesionMixedfailurInterface

(a)被黏物破壞(b)內(nèi)聚破壞(c)界面破壞(d)混合破壞圖3—54膠接接頭破壞形式Adhesionandadhesionmechanism1Adhesionisaphysical,chemicalandmechanicalaction.The

Adhesion

TheoryMechanicalcombinationtheoryAdsorptiontheoryElectrostatictheoryDiffusiontheory1AdsorptiontheoryTwostages1.Thepolymerintheadhesiveisclosetothesurfaceduetothermalmovement.2.Thedistancebetweentheadhesiveandtheadherentissmallenoughtoproduceadsorption.Theoreticalexplanation:Theadsorptionforceistheattractionbetweenpolarmolecules.2ElectrostatictheoryTheoreticalexplanation:Theadhesiveforcecomesfromtheelectrostaticattractionoftheelectricdoublelayer.FlawsElectrostaticinteractiononlyexistsinthebondingsystemofelectricdoublelayer,whichisnotuniversal.3DiffusiontheoryTheoreticalexplanation:Moleculesformastrongadhesivejointbydiffusion.4MechanicalcombinationtheoryTheadhesivepenetratesintothesurfaceoftheobjecttobeadhered,aftercuring,toproduceadentateormosaicconnection.

Relationshipbetweenwettingandbonding1Wetting2WettabilityNecessaryconditionsforimprovingadhesion:Goodcontactofthewholesurfaceoftheadhesive,fullywet.Thesmallerthecontactangle,thebetterthewettabilityandadhesion.Relationshipbetweenwettingandbonding

contactangleCohesionandcuringofadhesive1CuringofadhesiveTheprocessinwhichanadhesivebecomesasolidafterwettingthesurfaceoftheobjecttobeadhered.2NecessityofcuringTheadhesiveitselfproducesenoughcohesion.Loadbearing.Cohesionandcuringofadhesive3Curingmethodofadhesive(1)Condensationorsolventvolatilization(2)HeatingandpressurizingStressformofadhesivejoint1FourstressformsofadhesivejointStressforms(1)Tearing(stretch)evenly(2)Shear(3)Uneventearing(splitting)(4)StrippedStressformofadhesivejoint1FourstressformsofadhesivejointStressmodeShearPullforceUniformpullingforce(tension)Unevenpullingforce(splitoff)Strippingforce1Uniformpullingforce(tension)Theactionlineofexternalforceisverticaltothegluejoint.Features:

stretching2ShearTheexternalforceactinglineisparalleltotheglueseam.Features:

ShearShearisthebeststressformofadhesivejoint,andtheadhesivestrengthisthehighest.3Uneventearing(splitting)Thesplittingforceisformedattheedge,andthestressconcentrationislarge.Features:

UneventearingForexample,theconnectionofwing,wingribandlongtruss.Thebondingstrengthislow.4

strippingExternaltensionisformedattheedge,andthestressisveryconcentrated.Features:Thebondingstrengthisthelowest.

Therelationshipbetweenlapleng

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