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1、氨基酸表面活性劑的市場現(xiàn)狀及應(yīng)用突破Market analysis and application breakthrough of amino acid surfactants廣州天賜高新材料股份有限公司Guangzhou Tinci Materials Technology Co. Ltd.毛華麗 Lily Mao 2014.01.11,WWW,個(gè)人簡介 Introduction,毛華麗 Lily Mao 2009年畢業(yè)于浙江工業(yè)大學(xué),專業(yè)為微生物與生化藥學(xué),獲得碩士學(xué)位。 Graduated from Zhejiang University of Technology with Maste
2、rs degree for Microbiology it is easy to get facial cleanser; low soap content leads to narrow changing temperature range and rough appearance. 1.5%,氨基酸表面活性劑在不同pH條件下的起泡性能 Foamability of amino acid surfactants at different pH,1、月桂酰肌氨酸鈉pH在5-9.5區(qū)間內(nèi)均有良好的起泡性能,酸性條件下更佳. Sodium Lauroyl Sarcosinate shows exc
3、ellent foamability at pH 5-9.5, and in acid condition is better. 2、椰油酰甘氨酸鉀在pH7時(shí)具有良好的起泡效果,pH中性條件下有較好的耐硬水性能. Potassium Cocoyl Glycinate shows excellent foamability when pH7, and shows excellent hard water resistance in neutral condition.,測試方法:SITA 泡沫儀,900rpm,30s,樣品濃度:0.3% Test method: SITA Foam Tester
4、,900rpm,30s,sample concentration: 0.3%,氨基酸表面活性劑在不同pH條件下的起泡性能 Foamability of amino acid surfactants at different pH,月桂酰谷氨酸鈉在酸性條件下起泡性能優(yōu)異,當(dāng)pH7時(shí),其在硬水中形成月桂酰谷氨酸鈣反而有較優(yōu)異的表面活性。 Sodium Lauroyl Glutamate shows excellent foamability in acid condition, when pH7, it shows excellent surface activity for the genera
5、tion of Calcium Lauroyl Glutamate.,月桂酰谷氨酸鈉與脂肪酸復(fù)配泡沫性能Foamability of Sodium Lauroyl Glutamate combined with fatty acid,泡沫質(zhì)量評(píng)價(jià)方法:配制10%的AMIN LGNa溶液,加熱至35,取此溶液4ml用雙手搓15秒,拍照,觀察泡沫的質(zhì)與量。 Test method: Prepare 10% Sodium Lauroyl Glutamate solution, heat to 35, take 4mL into hand and rub for 15s, photo it and c
6、ompare the quality and quantity of the foam.,AMIN LGNa溶液 AMIN LGNa solution,AMIN LGNa添加1%十四酸 Add 1% myristicacid into AMIN LGNa solution,AMIN LGNa添加1%十二酸 Add 1%lauricacid into AMIN LGNa solution,AMIN LGNa添加1%混合酸十四酸/十二酸=7:3 Add 1% myristic acid and lauricacid at the ratio 7:3 into AMIN LGNa solution,
7、AMIN LGNa的泡沫舒適,細(xì)密、柔滑,呈乳脂狀。與脂肪酸結(jié)合可改變泡沫的狀態(tài),添加混合脂肪酸可改變增加泡沫的質(zhì)與量 The foam of AMIN LGNa is small, fine, smooth and creamy. When combined with fatty acid, the condition of the foam will change: the quality and quantity of the foam will be improved.,氨基酸表面活性劑乳化力性能測定及膚感Emulsifying ability tests and skin feeli
8、ng,滋潤感 Emollient,堿性 Alkalinity,酸性 Acidity,清爽感 Refreshing,AMIN,AMIN LG95F,AMIN GCK30,皂基 Soap,AMIN LS30,測試方法:量筒法測試乳化力,30ml0.3%表面活性劑溶液與30ml白油混合震蕩乳化,記錄分層時(shí)間。 Test method: Test with measuring cylinder, mix 30mL 0.3% surfactant solution with 30mL white oil, record the time of phase separating.,氨基酸表面活性劑增稠解決
9、方案Solution of viscosity increasing of amino acid surfactants,結(jié)論Conclusion: 1、三種增稠方案在pH=4.5-5.5之間可以達(dá)到較好的增稠效果 The thickening ability is the best when pH is among 4.5-5.5 under the 3 condition 2、泡沫性能,pH在5.0以下有更優(yōu)的起泡性能 The foamability is better when pH is under 5.0,不同氨基酸表面活性劑在不同pH條件下的粘度Viscosity of diffe
10、rent amino acid surfactants under different pH,pH,Viscosity/mPa.S,增稠機(jī)理?,氯化鈉對(duì)含氨基酸表面活性劑體系粘度的影響The influence of NaCl for the viscosity of amino acid surfactants system,結(jié)論Conclusion: 氯化鈉對(duì)三種氨基酸表面活性劑的增稠性能:AMIN GCK30AMIN LS30AMIN LG30 The influence of NaCl for the viscosity of 3 kinds of amino acid surfact
11、ants: AMIN GCK30AMIN LS30AMIN LG30,研究洗發(fā)水在適當(dāng)?shù)墓潭╬H條件下,氯化鈉對(duì)含氨基酸表面活性劑體系粘度的影響 Test the influence of NaCl for the viscosity of shampoo at specified pH,3、氨基酸表面活性劑在洗發(fā)香波中的應(yīng)用及選擇 Application and optimal solution for amino acid surfactants,日本無硫酸鹽洗發(fā)水例 Sulfate-free shampoo in Japan,配料表: 水,月桂基甜菜堿,甲基椰油酰基?;撬徕c,椰油酰胺DE
12、A,丁二醇,月桂酰胺丙基羥磺基甜菜堿,椰油酰谷氨酸二鈉,吡羅克酮乙醇胺鹽,甘草酸二鉀,椰油酰胺MEA,椰油酰谷氨酸鈉,提取物,聚季銨鹽-10 Ingredients: Water, Lauryl betaine, Sodium Methyl Cocoyl Taurate, Cocamide DEA, Butanediol, Cocamidopropyl Hydroxysultaine, Disodium cocoyl glutamate, Piroctone Olamine, Dipotassium Glycyrrhizinate, Cocamide MEA, Sodium Cocoyl Gl
13、utamate, Extract, Polyquaternium-10,市售洗發(fā)水泡沫對(duì)比 Foamability comparison for marketed shampoo products,含有氨基酸表面活性劑洗發(fā)水的粘度對(duì)比Viscosity comparison of shampoo with amino acid surfactants,含有氨基酸表面活性劑的洗發(fā)水一般都粘度較低 Normally, shampoo with amino acid surfactants appear low viscosity,洗發(fā)水的配方突破點(diǎn)Shampoo formula breakthro
14、ugh,天然 Natural 無硫酸鹽 Sulfate-free 溫和 Mild 低刺激 Low irritation 洗護(hù)分開 Cleaning, conditioning separation,寶潔體系洗護(hù)二合一 P&G system-2 in 1,新領(lǐng)域 New field: 無硫酸鹽 Sulfate-free 洗護(hù)二合一 Shampoo, conditioner 2 in 1,含有氨基酸表面活性劑洗發(fā)水的單一變數(shù)比較實(shí)驗(yàn) Single variable comparison test of shampoo with amino acid surfactants,在本實(shí)驗(yàn)配方中,肌氨酸鹽
15、比其它在梳理性方面有一定優(yōu)勢 Sarcosinate surfactant shows better combing performance in this test.,Main ingredients: AES 9% or 12%, CAB35 3%, Amino acid surfactants 3% or 0%, PQ-10 0.5%,Sodium Cocoyl Glutamate,Sodium Cocoyl Glycinate,Sodium Lauroyl Sarcosinate,Blank,Untreated(Wet Hair),Before rinse,After rinse,Af
16、ter dry,無硫酸鹽洗發(fā)水 Sulfate-free shampoo 主要成分 Main ingredients: 卡波姆380 Carbomer 380 椰油酰胺丙基羥基磺基甜菜堿 Cocamidopropyl Hydroxysultaine 月桂酰肌氨酸鈉 Sodium Lauroyl Sarcosinate 月桂酰谷氨酸鈉 Sodium Lauroyl Glutamate 聚季銨鹽-10 Polyquaternium-10 乳化硅油 Silicone emulsion 防腐劑 Preservative 香精 Fragrance,粘度 Viscosity:5,000-10,000 成本
17、 Cost:7-8 RMB/kg,無硫酸鹽氨基酸洗發(fā)水的開發(fā)參考配方框架 Reference formula for sulfate-free amino acid surfactants shampoo,無硫酸鹽氨基酸洗發(fā)水與市售某產(chǎn)品對(duì)比Comparison of sulfate-free amino acid surfactants shampoo with marketed product,無硫酸鹽氨基酸洗發(fā)水與市售某產(chǎn)品對(duì)比Comparison of sulfate-free amino acid surfactants shampoo with marketed product,4
18、、結(jié)晶型氨基酸潔面膏介紹 Introduction of crystallized amino acid facial cleanser,結(jié)晶型氨基酸潔面膏 Crystallized amino acid facial cleanser,固體(結(jié)晶)與液體混合 Mixture of solid(crystal) and liquid,v,結(jié)晶 Crystal,表面活性劑飽和溶液 Saturated surfactants solution,室溫Room temperature 80-50 45,Mix solid & liquid,Uniform liquid,Crystallize soli
19、d,結(jié)晶型潔面膏中主次表活的選擇 Choice of primary / secondary surfactants in crystallized amino acid facial cleanser,典型的結(jié)晶型潔面膏配方 Typical formula of crystallized amino acid facial cleanser : 表面活性劑 Surfactants: 15-30% 多元醇 Polyol: 20-40%- 甘油 、山梨醇 、1,3-丁二醇、丙二醇、PEG-6等 Glycinate, sorbitol, butanediol, propyleneglycol, e
20、tc. 水 Water: 30-40% 表面活性劑的選擇 Choice of surfactants : 1、用液體的氨基酸表面活性劑比較難做膏狀的潔面產(chǎn)品 Liquid amino acid surfactants are hard to make paste facial cleanser 2、粉末、片狀、顆粒狀、糊狀 Powder, flake, granular, paste 3、溶解性:偏低 Solubility: low,結(jié)晶型氨基酸潔面膏應(yīng)用例Sample of crystallized amino acid facial cleanser,配料表: 水,月桂酰谷氨酸鈉,丙二醇,
21、PEG-150硬脂酸酯,半乳糖酵母樣菌發(fā)酵產(chǎn)物濾液,PCA鈉,乙二醇硬脂酸酯,椰油酰胺MEA,丁二醇,提取物等 Ingredients: Water, Sodium Lauroyl Glutamate, Propylene Glycol, PEG-150 Stearate, Galactomyces Ferment Filtrate, Sodium PCA, Glycol Stearate, Cocamide MEA, Butanediol, Extract, etc.,SK-II柔膚潔面乳 SK-II Facial treatment cleanser,上市時(shí)間 Time-to-market
22、:2010.12 120.0g 82.71,天賜純氨基酸潔面膏參考框架Reference formula for Tinci amino acid facial cleanser,純氨基酸潔面膏 Amino acid facial cleanser 主要成分 Main ingredients: 月桂酰谷氨酸鈉 Sodium Lauroyl Glutamate 月桂酰肌氨酸鈉 Sodium Lauroyl Sarcosinate 多元醇 Polyol 脂肪酸 Fatty acid 珠光劑 Pearling agent 丙烯酸(酯)類共聚物 Acrylates Copolymer 氯化鈉 Sodi
23、um Chloride 防腐劑 Preservative 香精 Fragrance,成本 Cost:22-25 RMB/kg 結(jié)膏點(diǎn) Crystallized temperature:45,純氨基酸潔面膏參考工藝 Reference manufacture process of amino acid facial cleanser,40水浴浸泡30分鐘后,緩慢攪拌 40 water bath for 30min, mix slowly,80-85,通冷凝水降溫至55-60 Cool to 55-60 with condensatewater,丙烯酸(酯)類共聚物 Acrylates Copol
24、ymer,結(jié)晶溫度46-48 Crystallize temperature 46-48,香精、防腐劑 Preservative, fragrance,去離子水/AMIN LG95F/其他表活/多元醇 D.I. water/AMIN LG95F/other surfactants/polyol,持續(xù)攪拌至室溫,熟化至第二天,擠壓灌裝 Constantly mix to room temperature, cure to the next day, packing,氨基酸潔面膏對(duì)比Comparison of amino acid facial cleansers,v,結(jié)晶 Crystal,表面活
25、性劑飽和溶液 Saturated surfactants solution,v,結(jié)晶 Crystal,表面活性劑飽和溶液 Saturated surfactants solution,聚合物增稠劑 Polymer thickner,純氨基酸潔面膏(SKII) SK-II amino acid facial cleanser,天賜氨基酸潔面膏 Tinci amino acid facial cleanser,潔面膏泡沫性能對(duì)比Foamability of amino acid facial cleansers,測試方法:SITA泡沫儀,900轉(zhuǎn)/min,10s/次,12次,稱取樣品2g至400g150ppm
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