小蘇打計(jì)算(最最新5)

1、60攝氏度Na2CO3-NaHCO3-Na2SO4-H2O體系溶解度數(shù)據(jù)液相組成（質(zhì)量分?jǐn)?shù)）液相干鹽組成（質(zhì)量分?jǐn)?shù)）Na2co3NaHC03Na2SO4H20Na2co3NaHC03Na2SO4H20/干鹽131.868.2100214.5214.185.9100609.2331.368.7100219.5430.71.36895.944.060.00212.5516.97.475.769.5530.450.00311.5629.75.564.884.380.0015.63184.179.2023.567.328.130.0071.87205.885.0527.3867.570.0015.57

2、84.43208.4910.233.5719.8266.3830.4310.6258.95197.41010.163.6119.4766.7630.5710.8658.57200.81128.10.744.9766.1983.112.1914.70195.81226.81.9871.2293.126.880.00247.51322.13.2974.6187.0412.960.00293.9148.510.181.445.7054.300.00437.6154.3111.1384.5627.9172.090.00547.7162.3511.785.9516.7383.270.00611.7171

3、.412.985.79.7990.210.00599.3一清堿液12.991.196.6979.1262.245.7232.03379.0二清堿液10.075.838.3175.7941.6024.0734.32313.1三清堿液9.456.8110.0073.7436.0025.9338.08280.8四清堿液9.566.6411.8171.9934.1323.7142.16257.0五清堿液9.916.0813.6270.3933.4820.5345.99237.7C12x+3=9.9999Hx-6.9999SyC1+TT+HC1+BB+S3x+y+z=9 x+y+z=5x+2y=7H+S

4、x2000H+S+Ty2.5T+B+Hz0.5C1+T+BTTHHHH設(shè)計(jì)任務(wù) 總堿Na2CO3NaHCO3NaSO425.66%24.25%2.23%10.96%25.66%化堿、澄清、洗泥物料衡算(以1000kg天然堿為例)Gt+Gs=GQ+Gpn天然堿渾堿液清堿液GtGhGQ10001841.431818step16G(zc)tGhG(zc)Q256.6253.196875step45天然堿流量及組成總堿Na2CO3NaHCO3質(zhì)量256.6242.522.3分?jǐn)?shù)25.66%24.25%2.23%256.57洗泥液組成Gxs總堿Na2CO3NaHCO3質(zhì)量2.6606252.514425

5、4190.231223451分?jǐn)?shù)3.00%2.84%0.26%總堿2.66清堿液組成GQ總堿Na2CO3NaHCO3質(zhì)量253.196875239.283874522.00424907分?jǐn)?shù)13.75%12.99%1.19%總堿253.167512.991.19碳化工段計(jì)算 以100g清堿液為例 碳化率取90Na2co3NaHC03Na2SO4清堿液12.991.196.69碳化后：1.3719.616.69J點(diǎn)坐標(biāo)6.55%由圖查的O3數(shù)據(jù)Na2co3NaHC03Na2SO4干鹽4.5871.0224.4液相1.21%18.75%6.44%由計(jì)算所得O3數(shù)據(jù)碳化反應(yīng)消耗水量1.97碳化后系統(tǒng)O

6、3水量77.15碳化后O3干鹽總量27.67碳化后系統(tǒng)O3水值278.7893699計(jì)算的O3數(shù)據(jù)Na2co3NaHC03Na2SO4干鹽1.3719.616.69液相1.31%18.71%6.38%由圖查的Q數(shù)據(jù)Q水值434.5Q7.657.534.91.42%10.76%6.53%固相( NaHCO3) 析出量10.11碳化母液中干鹽總量17.57其中1.379.506.69母液干鹽組成7.83%54.11%38.07%總堿7.3719碳化后母液O3水量77.15計(jì)算的Q數(shù)據(jù)碳化母液的水值439.173988碳化母液總量94.72其中1.45%10.03%7.06%清堿液組成Gxs組分Na

7、2CO3NaHCO3質(zhì)量239.283874522.00424907析出NaHCO3量kg Gc理186.0979182Gc實(shí)200.9857516Gm理1744.150442Gm實(shí)1729.262608Gmf1296.946956總堿第二輪計(jì)算Gt+Gs+Gmf1+Gxs1=GQ+GpnG(zc)t+G(zc)mf1+G(zc)xs1=G(zc)Q+G(zc)pn+G(zc)xs2天然堿渾堿液清堿液GtGhGQ10002594.908282step16G(zc)tGhG(zc)Q256.6356.7998887step45天然堿流量及組成Gt總堿Na2CO3NaHCO3質(zhì)量256.6242.

8、522.3分?jǐn)?shù)25.66%24.25%2.23%256.57第一輪洗泥液組成Gxs1總堿Na2CO3NaHCO3質(zhì)量2.66062.51440.2312分?jǐn)?shù)3.00%2.84%0.26%2.66返回化堿流量及組成Gmf1總堿Na2CO3NaHCO3質(zhì)量100.942418.8255130.1475分?jǐn)?shù)7.78%1.45%10.03%混堿液流量及組成Gmf1總堿Na2CO3NaHCO3質(zhì)量360.2030263.8399152.6788分?jǐn)?shù)13.50%9.88%5.72%360.172910.07%5.83%清堿液組成GQ總堿Na2CO3NaHCO3質(zhì)量356.7999261.3472151.2

9、363分?jǐn)?shù)13.75%10.07%5.83%356.770110.075.83澄清泥組成Gcn總堿Na2CO3NaHCO3質(zhì)量3.402.49271.4425分?jǐn)?shù)13.75%10.07%5.83%溶液質(zhì)量24.75洗泥液組成Gxs2總堿Na2CO3NaHCO3質(zhì)量2.6606251.94881.1277分?jǐn)?shù)3.00%2.20%1.27%2.66排泥組成Gpn總堿Na2CO3NaHCO3質(zhì)量0.74250.5439085290.314748747分?jǐn)?shù)3.00%2.20%1.27%0.7425溶液質(zhì)量24.75第二輪碳化工段計(jì)算 以100g清堿液為例 碳化率取90Na2co3NaHC03Na2SO

10、4清堿液10.075.838.31碳化后：1.3719.618.31J點(diǎn)坐標(biāo)6.55%碳化反應(yīng)消耗水量1.48碳化后系統(tǒng)O3水量74.31碳化后O3干鹽總量29.30碳化后系統(tǒng)O3水值253.67Q水值414Q8.650.141.31.67%9.75%8.04%固相( NaHCO3) 析出量10.71夾帶母液量碳化母液中干鹽總量18.59其中1.378.918.316.99397.40%47.91%44.70%7.53%1.48%9.59%8.94%碳化后母液O3水量74.31碳化母液的水值399.7700091碳化母液總量92.90其中1.48%9.59%8.94%清堿液組成Gxs組分總堿N

11、a2CO3NaHCO3質(zhì)量356.7998887261.3472072151.236286513.75%10.07%5.83%析出NaHCO3量kg Gc理277.8108738 2612.53夾帶母液量Gc實(shí)300.0357437Gm母液總量2410.771829Gm實(shí)2388.546959去化堿母液Gmf1791.410219第三輪計(jì)算Gt+Gs+Gmf1+Gxs1=GQ+GpnG(zc)t+G(zc)mf1+G(zc)xs1=G(zc)Q+G(zc)pn+G(zc)xs2天然堿渾堿液清堿液GtGhGQ10002841.572176step16G(zc)tGhG(zc)Q256.6390.

12、7161741step45天然堿流量及組成Gt總堿Na2CO3NaHCO3質(zhì)量256.6242.522.3分?jǐn)?shù)25.66%24.25%2.23%256.57第一輪洗泥液組成Gxs1總堿Na2CO3NaHCO3質(zhì)量2.6606251.9487974471.127729246分?jǐn)?shù)3.00%2.20%1.27%2.66返回母液流量及組成Gmf1總堿Na2CO3NaHCO3質(zhì)量134.858726.5110783171.7207179分?jǐn)?shù)7.53%1.48%9.59%混堿液流量及組成Gmf1總堿Na2CO3NaHCO3質(zhì)量394.1193270.9599195.1484分?jǐn)?shù)13.52%9.29%6.6

13、9%394.08939.45%6.81%清堿液組成GQ總堿Na2CO3NaHCO3質(zhì)量390.7161741268.6202026193.4633875分?jǐn)?shù)13.75%9.45%6.81%390.6864113.438781.69999.456.81第三輪碳化工段計(jì)算 以100g清堿液為例 碳化率取90Na2co3NaHC03Na2SO4清堿液9.456.8110.00碳化后：1.3719.6110.00J點(diǎn)坐標(biāo)6.55%碳化反應(yīng)消耗水量1.37碳化后系統(tǒng)O3水量72.37碳化后O3干鹽總量30.99碳化后系統(tǒng)O3水值233.55Q水值386.5Q9.0144.4946.51.85%9.14%

14、9.56%固相( NaHCO3) 析出量11.73夾帶母液量碳化母液中干鹽總量19.26其中1.377.8810.006.34737.14%40.93%51.93%6.93%1.50%8.60%10.91%碳化后母液O3水量72.37碳化母液的水值375.8282054碳化母液總量91.62其中1.48%8.48%10.76%清堿液組成Gxs組分總堿Na2CO3NaHCO3質(zhì)量390.7161741268.6202026193.463387513.75%9.45%6.81%析出NaHCO3量kg Gc理333.3432361 夾帶母液量Gc實(shí)360.010695Gm母液總量2603.51449

15、4Gm實(shí)2576.847035去化堿母液Gmf1932.635277半成品計(jì)算濕產(chǎn)品Gc洗液總堿含量ZGY洗水Gx洗液Gy360.0106951.98%66.6766.67濕產(chǎn)品質(zhì)量流量及組成總堿Na2CO3NaHCO3質(zhì)量212.17110.40335.64組成58.93%0.11%93.23%窯氣計(jì)算入塔窯氣壓力P Mpa入塔窯氣組成質(zhì)量體積0.35Na2CO3反應(yīng)量229.5515639CO2消耗量95.28555482窯氣CO2的量105.872838753.89889969窯氣體積145.6727019水汽計(jì)算前提條件TPH20 Pa304241.61V水1.36905066GH20

16、1.100129994VN290.40475152GN2113.0059394G窯219.9789081入塔窯氣壓力P Mpa尾氣計(jì)算0.15質(zhì)量體積N2113.005939490.40475152C0210.587283875.3898899690.050663636H2O8.51072901610.59112944尾氣132.1039523106.3857709任務(wù)書所給數(shù)據(jù)生產(chǎn)規(guī)模kt/a百分含量%年工作日/d日工作小時(shí)1000.98530024333.3333333X1X2小蘇打G2kg/h干硝Gkg/h0.0621424220.00200400813888.888913861.111

17、11濕硝G1kg/h14722.47412I0I1I2Cm49.78610709173.6268041152.14123471.050390782干燥熱量衡算蒸發(fā)水分消耗熱量 物料升溫所需熱量熱損失干燥所需熱量583.2920067141.551504672.48435114797.3278625預(yù)熱器熱量衡算所需熱量Qp預(yù)熱器損失Qm預(yù)熱器所需熱量加熱蒸汽消耗量Gs1222.04997861.102498911283.1524772248.729395熱效率計(jì)算干燥熱效率1總效率預(yù)熱器所需熱量73.16%47.73%95.24%化堿階段物料總平衡表輸入物質(zhì)天然堿返回母液質(zhì)量質(zhì)量分?jǐn)?shù)質(zhì)量總堿2

18、56.625.66%134.8587Na2CO3242.524.25%26.5111NaHCO322.32.23%171.7207NaSO4109.610.96%140.7017NaCl15.21.52%19.51338082水不溶物49.54.95%0.0000水560.956.09%1432.963296總和1000100.00%1791.4102192915.822176澄清階段的物料總平衡表輸入輸出渾堿液清堿液物質(zhì)質(zhì)量質(zhì)量分?jǐn)?shù)質(zhì)量總堿394.119299113.52%390.7161741Na2CO3270.95987579.29%268.6202026NaHCO3195.148447

19、26.69%193.4633875NaSO4251.71366368.63%249.5401769NaCl34.909194221.20%34.60776176水不溶物49.51.70%0水2113.59099572.49%2095.340647總和2915.822176100.00%2841.5721762915.822176碳化過濾階段的物料總平衡表輸入輸出清堿液母液物質(zhì)質(zhì)量質(zhì)量分?jǐn)?shù)質(zhì)量總堿390.716174113.75%179.8115655Na2CO3268.62020269.45%35.3481044NaHCO3193.46338756.81%228.9609572NaSO4249

20、.54017698.78%187.6023278NaCl34.607761761.22%26.01784109水不溶物00.00%0水2095.34064773.74%1910.617729總和2841.572176100.00%2388.5469592748.557654洗泥階段的物料總平衡表輸入澄清泥洗水物質(zhì)質(zhì)量質(zhì)量分?jǐn)?shù)質(zhì)量總堿3.40312513.75%Na2CO32.3396731129.45%NaHCO31.6850597296.81%NaSO42.1734867178.78%NaCl0.3014324641.22%水不溶物49.50.00%水18.2503479873.74%總和7

21、4.25100.00%88.6875計(jì)算結(jié)果匯總以h為基準(zhǔn)年產(chǎn)100kt所需的濕產(chǎn)品G114722.474121000kg天然堿生產(chǎn)的濕產(chǎn)品Gc360.010695一小時(shí)所需的量是天然堿生產(chǎn)濕產(chǎn)品的倍數(shù)40.89454655一小時(shí)所需的天然堿的量Gt40894.54655第二輪的母液Gmf273258.90861第二輪的洗泥水Gxs23626.835097補(bǔ)充水Gs1460.935435渾堿液Gh119241.2257清堿液Gq116204.805696.83733801澄清泥Gc3036.420081洗泥液Gxs33626.835097排泥Gpn3036.420081尾氣G尾5402.331

22、226離心洗水Gx2726.384097離心洗液Gy2726.384097母液Gm105378.991以噸產(chǎn)品為基準(zhǔn)G11060.018137 W60.01813698L2557.764628 Lo2587.703819Vo2647.721956 L2502.585742V2544.821079 Gs2.572160842Gt40894.54655 Gxs23626.835097Gmf273258.90861 Gq116204.8056Gc3036.420081 Gxs33626.835097Gpn3036.420081 Gh119241.2257Gs1460.935435 G窯9387.40

23、7115G尾5402.331226 Glx2726.384097Gly2726.384097 Gm119241.2257第四輪計(jì)算Gt+Gs+Gmf1+Gxs1=GQ+GpnG(zc)t+G(zc)mf1+G(zc)xs1=G(zc)Q+G(zc)pn+G(zc)xs2天然堿渾堿液清堿液GtGhGQ10002834.501351step16G(zc)tGhG(zc)Q256.6389.7439358step45天然堿流量及組成Gt總堿Na2CO3NaHCO3質(zhì)量256.6242.522.3分?jǐn)?shù)25.66%24.25%2.23%256.57第一輪洗泥液組成Gxs1總堿Na2CO3NaHCO3質(zhì)量

24、2.6606251.8291989791.317410333分?jǐn)?shù)3.00%2.06%1.49%2.66返回母液流量及組成Gmf1總堿Na2CO3NaHCO3質(zhì)量133.886429.00134785166.2329696分?jǐn)?shù)10.32%1.50%8.60%混堿液流量及組成Gmf1總堿Na2CO3NaHCO3質(zhì)量393.1471273.3305189.8504分?jǐn)?shù)13.52%9.40%6.53%393.11719.56%6.64%清堿液組成GQ總堿Na2CO3NaHCO3質(zhì)量383.11270.96188.21分?jǐn)?shù)13.52%9.56%6.64%389.71429.566.64第四輪碳化工段計(jì)算

25、 以100g清堿液為例 碳化率取90Na2co3NaHC03Na2SO4清堿液9.566.6411.81碳化后：1.3719.6111.81J點(diǎn)坐標(biāo)6.55%碳化反應(yīng)消耗水量1.39碳化后系統(tǒng)O3水量70.60碳化后O3干鹽總量32.80碳化后系統(tǒng)O3水值215.27Q水值352.3Q6.8734.1758.961.52%7.55%13.04%固相( NaHCO3) 析出量12.76夾帶母液量碳化母液中干鹽總量20.03其中1.376.8511.815.69536.86%34.18%58.95%6.28%1.52%7.56%13.03%碳化后母液O3水量70.60碳化母液的水值352.4448

26、02碳化母液總量90.63其中1.48%7.37%12.71%清堿液組成Gxs組分總堿Na2CO3NaHCO3質(zhì)量383.11270.96188.2113.48%9.56%6.64%析出NaHCO3量kg Gc理361.802612.53夾帶母液量Gc實(shí)390.75Gm母液總量2569.00Gm實(shí)2540.05去化堿母液Gmf1905.04半成品計(jì)算濕產(chǎn)品Gc洗液總堿含量ZGY洗水Gx洗液Gy390.74635881.80%72.3672.36半成品質(zhì)量流量及組成總堿Na2CO3NaHCO3質(zhì)量230.09880.44363.99組成58.89%0.11%93.15%窯氣計(jì)算入塔窯氣壓力P M

27、pa入塔窯氣組成質(zhì)量體積0.35Na2CO3反應(yīng)量231.9931439CO2消耗量96.29904088窯氣CO2的量106.998934354.47218474窯氣體積147.2221209水汽計(jì)算前提條件TPH20 Pa304241.61V水1.383612298GH201.111831311VN291.36632389GN2114.2079049G窯222.3186705入塔窯氣壓力P Mpa尾氣計(jì)算0.15質(zhì)量體積N2114.207904991.36632389C029.6299040884.902496627H2O8.55285672810.64355504尾氣132.390665

28、7106.9123756任務(wù)書所給數(shù)據(jù)生產(chǎn)規(guī)模kt/a百分含量%年工作日/d日工作小時(shí)800.98530024X1X2小蘇打G2kg/h干硝Gkg/h0.0612355360.00200400811111.111110944.44444濕硝G1kg/h11614.63336I0I1Cm49.81167.51.042蒸發(fā)水分消耗熱量物料升溫所需熱量熱損失1632.996176423.5856788從產(chǎn)品到倒往回各個(gè)工段流量干燥總組分水分蒸發(fā)量總計(jì)輸出11111.1111648.256211759.3673輸入11614.6333611614.6334其中56NaCl水不溶物水1.52%4.95%

29、56.09%100.00%第一輪計(jì)算G(zc)t=G(zc)Q+G(zc)pn+G(zc)xs1濕產(chǎn)品母液澄清泥洗水GcGmGcnGxn74.2588.687527GcGmG(zc)cnGxn3.4031253NaSO4NaCl水不溶物水109.615.249.5560.910.96%1.52%4.95%56.09%NaSO4NaCl水不溶物水1.1364166020.157605222084.647829311.28%0.18%0.00%95.45%NaSO4NaCl水不溶物水108.146443914.9984119301456.9988395.87%0.81%0.00%79.12%6.6

30、979.12H20Na2co3NaHC03Na2SO479.1262.245.7232.03水值12278.83473.60%75設(shè)計(jì)任務(wù) 化堿、澄清、洗泥物料衡算(以1000kg天然堿為例)天然堿流量及組成洗泥液組成Gxs清堿液組成GQ碳化工段計(jì)算 以100g清堿液為例 碳化率取90由圖查的O3數(shù)據(jù)水值77.1573.60%O3QAQ水值14.940.881.29%合計(jì)77.1594.7281.45%100.00%NaSO4NaCl水不溶物水108.146443914.9984119301456.998839濕產(chǎn)品3/4母液澄清泥洗水GcGmfGcnGxn1296.94695674.2588

31、.687527GcG(zc)mfG(zc)cnGxn100.94238873.4031253NaSO4NaCl水不溶物水由計(jì)算所得O3數(shù)據(jù)計(jì)算的O3數(shù)據(jù)由圖查的Q數(shù)據(jù)計(jì)算的Q數(shù)據(jù)清堿液組成Gxs第二輪計(jì)算G(zc)t+G(zc)mf1+G(zc)xs1=G(zc)Q+G(zc)pn+G(zc)xs2天然堿流量及組成Gt109.615.249.5560.910.96%1.52%4.95%56.09%NaSO4NaCl水不溶物水1.13640.15760.000084.64781.28%0.18%0.00%95.45%NaSO4NaCl水不溶物水80.417511.15280.00001056.4

32、0366.20%0.86%0.00%81.45%NaSO4NaCl水不溶物水191.153926.510449.50001985.47537.16%0.99%1.85%74.39%7.30%1.01%75.79%NaSO4NaCl水不溶物水189.347926.259901966.7169337.30%1.01%0.00%75.79%8.3175.79NaSO4NaCl水不溶物水1.80600.250549.500018.75847.30%1.01%75.79%NaSO4NaCl水不溶物水1.41190.1958084.00321.59%0.22%0.00%94.72%NaSO4NaCl水不溶

33、物水0.3940656250.05465143749.523.442625661.59%0.22%94.72%第一輪洗泥液組成Gxs1返回化堿流量及組成Gmf1混堿液流量及組成Gmf1清堿液組成GQ澄清泥組成Gcn洗泥液組成Gxs2排泥組成GpnH20Na2co3NaHC03Na2SO475.7941.6024.0734.32由圖查的O3數(shù)據(jù)Na2co3NaHC03Na2SO4干鹽4.6265.7829.6液相1.30%18.57%8.36%1.33%18.93%8.02%1.48%9.59%8.94%水值80.54%O3QAQ0.85647997917.0346.6合計(jì)74.3192.907

34、9.99%100.00%79.99%100.00%NaSO4NaCl水不溶物水189.347923626.25993101966.7169337.30%1.01%75.79%22.22486991濕產(chǎn)品3/4母液澄清泥洗水GcGmfGcnGxn1791.41021974.2588.687527GcG(zc)mfG(zc)cnGxn134.85867413.4031253第二輪碳化工段計(jì)算 以100g清堿液為例 碳化率取90清堿液組成Gxs第三輪計(jì)算G(zc)t+G(zc)mf1+G(zc)xs1=G(zc)Q+G(zc)pn+G(zc)xs2NaSO4NaCl水不溶物水109.615.249.

35、5560.910.96%1.52%4.95%56.09%NaSO4NaCl水不溶物水1.4119177090.195813405084.003242191.59%0.22%0.00%94.72%NaSO4NaCl水不溶物水140.701745919.5133808201432.9632967.85%1.09%0.00%79.99%NaSO4NaCl水不溶物水251.713734.909249.50002113.59108.63%1.20%1.70%72.49%8.78%1.22%73.74%NaSO4NaCl水不溶物水249.540176934.6077617602095.3406478.78

36、%1.22%0.00%73.74%105.381214.614910.0073.74H20Na2co3NaHC03Na2SO473.7436.0025.9338.08由圖查的O3數(shù)據(jù)Na2co3NaHC03Na2SO4干鹽4.4563.2732.28液相1.33%18.97%9.68%1.33%18.98%9.68%1.50%8.60%10.91%水值79.45%O3QAQ天然堿流量及組成Gt第一輪洗泥液組成Gxs1返回母液流量及組成Gmf1混堿液流量及組成Gmf1清堿液組成GQ第三輪碳化工段計(jì)算 以100g清堿液為例 碳化率取900.93847550719.852.3合計(jì)72.3791.62

37、78.98%100.00%77.89%98.62%NaSO4NaCl水不溶物水249.540176934.6077617602095.3406478.78%1.22%0.00%73.74%26.66745889361.110825NaSO4NaCl水總計(jì)GQ2.5560074360.35448278321.06302885360.010.71%0.10%5.85%100.00%體積百分比CO2吸收率0.370.9體積百分比TPH20 Pa0.126525020.41清堿液組成Gxs半成品計(jì)算濕產(chǎn)品質(zhì)量流量及組成 干燥w1w2空氣t0廢氣t20.05850.0022060水分蒸發(fā)量W空氣消耗L新

38、鮮空氣質(zhì)量流量L0r0冷空氣比容833.585235935524.5087335940.330820.844153184冷空氣相關(guān)物料計(jì)算冷空氣流量29988.12715尾氣流量尾氣質(zhì)量流量r0冷空氣比容尾氣體積流量36773.916050.99493950735344.73724075896.615CsCm1.0421.050390782I1I226.043806457.77149299732.5033345I2153.49H20.035687667L34758.1353輸出洗泥液渾堿液質(zhì)量分?jǐn)?shù)質(zhì)量質(zhì)量分?jǐn)?shù)質(zhì)量7.53%2.66063.00%394.11929911.48%1.94882.2

39、0%270.9598757任務(wù)書所給數(shù)據(jù)化堿階段物料總平衡表輸入返回母液9.59%1.12771.27%195.14844727.85%1.41191.59%251.71366361.09%0.19580.22%34.909194220.00%0.00000.00%49.579.99%84.0032421994.72%2113.590995100.00%88.6875100.00%2915.8221762915.822176澄清泥質(zhì)量分?jǐn)?shù)質(zhì)量質(zhì)量分?jǐn)?shù)13.75%3.40312513.75%9.45%2.3396731129.45%6.81%1.6850597296.81%8.78%2.1734

40、867178.78%1.22%0.3014324641.22%0.00%49.50.00%73.74%18.2503479873.74%100.00%74.25100.00%濕產(chǎn)品質(zhì)量分?jǐn)?shù)質(zhì)量質(zhì)量分?jǐn)?shù)7.53%212.171139958.93%1.48%0.4001749640.11%9.59%335.63700193.23%7.85%2.5560074360.71%1.09%0.3544827830.10%0.00%00.00%79.99%21.063028855.85%100.00%360.010695100.00%輸出排泥洗泥液質(zhì)量分?jǐn)?shù)質(zhì)量質(zhì)量分?jǐn)?shù)質(zhì)量0.74253.00%2.66062

41、50.5104741342.06%1.8291989790.3676493951.49%1.3174103330.4742152841.92%1.6992714330.0657670830.27%0.235665381澄清階段的物料總平衡表輸出清堿液碳化過濾階段的物料總平衡表輸出母液洗泥階段的物料總平衡表輸入洗水49.50.00%023.331894194.27%83.6059538774.25100.00%88.6875以噸天然堿為基準(zhǔn)年產(chǎn)100kt所需的濕產(chǎn)品G11000kg天然堿生產(chǎn)的濕產(chǎn)品Gc1h天然堿生成的濕產(chǎn)品是所需濕產(chǎn)品的倍數(shù)Gc8.803391292G2339.62692G33

42、8.9476661W20.38377501L868.6857227L0878.8538778L849.9454875Vo899.2376528V864.2897448Gs0.873575065計(jì)算結(jié)果匯總以h為基準(zhǔn)濕產(chǎn)品3/4母液澄清泥洗水GcGmfGcnGxn1932.63527774.2588.687527GcG(zc)mfG(zc)cnGxn133.88643583.4031253NaSO4NaCl水不溶物水109.615.249.5560.910.96%1.52%4.95%56.09%第四輪計(jì)算G(zc)t+G(zc)mf1+G(zc)xs1=G(zc)Q+G(zc)pn+G(zc)x

43、s2天然堿流量及組成GtNaSO4NaCl水不溶物水1.6992714330.235665381083.605953871.92%0.27%0.00%94.27%NaSO4NaCl水不溶物水185.238127125.6899592301526.4728739.58%1.33%0.00%78.98%NaSO4NaCl水不溶物水296.537441.125649.50002058.4110.19%1.41%1.70%70.77%10.37%1.44%71.99%NaSO4NaCl水不溶物水293.9740.7702040.5910.37%1.44%0.00%71.99%11.8171.99H20

44、Na2co3NaHC03Na2SO471.9934.1323.7142.16由圖查的O3數(shù)據(jù)Na2co3NaHC03Na2SO4干鹽4.1959.7536.06液相1.33%18.95%11.44%1.33%18.97%11.42%1.52%7.56%13.03%水值77.89%O3QAQ1.02113815224.3662.59合計(jì)70.6090.631.0077.90%100.00%第一輪洗泥液組成Gxs1返回母液流量及組成Gmf1混堿液流量及組成Gmf1清堿液組成GQ第四輪碳化工段計(jì)算 以100g清堿液為例 碳化率取9075.99%97.56%NaSO4NaCl水不溶物水293.9740

45、.7702040.5910.37%1.44%0.00%71.99%28.94NaSO4NaCl水總計(jì)GQ3.3120827320.45933994122.54689165390.750.85%0.12%5.77%100.00%體積百分比CO2吸收率0.370.9體積百分比TPH20 Pa0.126525020.41清堿液組成Gxs半成品計(jì)算半成品質(zhì)量流量及組成任務(wù)書所給數(shù)據(jù)干燥w1w2空氣t0廢氣t20.05770.0022060水分蒸發(fā)量W空氣消耗LL0r0冷空氣比容648.25616536198.6406386271.197073相對誤差絕對誤差144.73391.25%產(chǎn)量kt/a總堿大

46、于等于NaHCO3大于等于1000.990.985排泥洗泥液水GpnGxsGs74.2588.6875915.6818182278G(zc)pnG(zc)xsGs0.74252.66062533澄清泥組成Gcn總堿Na2CO3質(zhì)量3.4031253.216125536分?jǐn)?shù)13.75%12.99%總堿3.40溶液質(zhì)量排泥組成Gpn總計(jì)總堿Na2CO388.6875 質(zhì)量0.74250.701700117100.00% 分?jǐn)?shù)3.00%2.84%總堿0.7424總計(jì)溶液質(zhì)量1841.4318181H20/干鹽379.00所求變量一34532153936#NUM!化堿、澄清、洗泥物料衡算(以1000k

47、g天然堿為例)洗泥液組成Gxs清堿液組成GQ碳化工段計(jì)算 以100g清堿液為例 碳化率取90第一輪計(jì)算G(zc)t=G(zc)Q+G(zc)pn+G(zc)xs1由相圖查總計(jì)GQ1841.431818排泥洗泥液水GpnGxsGs74.2588.6875283.5238252278G(zc)pnG(zc)xsGs0.74252.66062533總計(jì)清堿液組成Gxs第二輪計(jì)算G(zc)t+G(zc)mf1+G(zc)xs1=G(zc)Q+G(zc)pn+G(zc)xs2天然堿流量及組成Gt1000100.00%總計(jì)88.6875100.00%總計(jì)1296.9470100.00%總計(jì)2669.158

48、3100.00%100.00%總計(jì)2594.9083100.00%總計(jì)74.25100.00%總計(jì)88.6875100.00%總計(jì)74.25100.00%第一輪洗泥液組成Gxs1返回化堿流量及組成Gmf1混堿液流量及組成Gmf1清堿液組成GQ澄清泥組成Gcn洗泥液組成Gxs2排泥組成GpnH20/干鹽313.08所求變量二水值254.271.77%71.73%79.99%由相圖查總計(jì)GQ2594.908282100.00%排泥洗泥液水GpnGxsGs74.2588.687535.72445614278G(zc)pnG(zc)xsGs0.74252.66062533第二輪碳化工段計(jì)算 以100g

49、清堿液為例 碳化率取90清堿液組成Gxs第三輪計(jì)算G(zc)t+G(zc)mf1+G(zc)xs1=G(zc)Q+G(zc)pn+G(zc)xs2由圖查的O3數(shù)據(jù)總計(jì)1000100.00%澄清泥組成Gcn總堿總計(jì)質(zhì)量3.403188.6875分?jǐn)?shù)13.75%100.00%洗泥液組成Gxs2總堿總計(jì)質(zhì)量2.6606251791.410219分?jǐn)?shù)3.00%100.00%2.66排泥組成Gpn總堿總計(jì)質(zhì)量0.74252915.822176分?jǐn)?shù)3.00%100.00%0.7424100.00%總計(jì)2841.572176746.23152872798.368233100.00%315.1346H20/干

50、鹽280.79所求變量三水值233.5570.02%70.02%78.98%由相圖查天然堿流量及組成Gt第一輪洗泥液組成Gxs1返回母液流量及組成Gmf1混堿液流量及組成Gmf1清堿液組成GQ第三輪碳化工段計(jì)算 以100g清堿液為例 碳化率取90由圖查的O3數(shù)據(jù)0.8434090911.040178571總計(jì)GQ2841.572176100.00%356.69清堿液組成Gxs相對濕度濕度H2進(jìn)干燥濕度H1飽和壓力0.80.0351702920.0117052172.3389濕硝T1干硝T2112055從產(chǎn)品到倒往回各個(gè)工段流量干燥總組分水分蒸發(fā)量總計(jì)輸出13888.8889833.585214

51、722.4741輸入14722.4741214722.4741其中質(zhì)量分?jǐn)?shù)13.52%9.29%任務(wù)書所給數(shù)據(jù)化堿階段物料總平衡表干燥輸出6.69%8.63%1.20%1.70%72.49%100.00%質(zhì)量分?jǐn)?shù)3.00%2.06%1.49%1.92%0.27%輸出洗泥液0.00%94.27%100.00%14722.47412360.0106950.024453138以噸天然堿為基準(zhǔn)年產(chǎn)100kt所需的濕產(chǎn)品G11000kg天然堿生產(chǎn)的濕產(chǎn)品Gc1h天然堿生成的濕產(chǎn)品是所需濕產(chǎn)品的倍數(shù)排泥洗泥液水GpnGxsGs74.2588.6875-112.5714253278G(zc)pnG(zc)x

52、sGs0.74252.66062533總計(jì)1000100.00%第四輪計(jì)算G(zc)t+G(zc)mf1+G(zc)xs1=G(zc)Q+G(zc)pn+G(zc)xs2天然堿流量及組成Gt澄清泥組成Gcn總堿總計(jì)質(zhì)量3.345288.6875分?jǐn)?shù)13.52%100.00%洗泥液組成Gxs2總堿總計(jì)質(zhì)量2.6606251932.635277分?jǐn)?shù)3.00%100.00%2.65排泥組成Gpn總堿總計(jì)質(zhì)量0.74252908.75分?jǐn)?shù)3.00%100.00%0.7553100.00%總計(jì)2834.50100.00%H20/干鹽257.03所求變量四水值215.2768.28%68.28%77.90

53、%由相圖查第一輪洗泥液組成Gxs1返回母液流量及組成Gmf1混堿液流量及組成Gmf1清堿液組成GQ第四輪碳化工段計(jì)算 以100g清堿液為例 碳化率取90由圖查的O3數(shù)據(jù)總計(jì)GQ2834.50100.00%清堿液組成Gxs任務(wù)書所給數(shù)據(jù)相對濕度濕度H2進(jìn)干燥濕度H1飽和壓力0.80.1162855930.0117052172.3389濕硝T1干硝T219.94442055干燥H2O小于等于任務(wù)所給量0.0021915.6818總堿Na2CO3NaHCO3NaSO4NaCl13.39%12.66%1.16%5.72%0.79%12.99%1.19%5.87%0.81%NaHCO3NaSO4NaCl

54、水不溶物水0.295750926 1.45355610.20158807549.519.582979351.19%5.87%0.81%79.12%24.75NaHCO3NaSO4NaCl水不溶物水0.064527475 0.31713950.04398285349.523.622650040.26%1.28%0.18%95.45%24.750.7425化堿、澄清、洗泥物料衡算(以1000kg天然堿為例)澄清泥組成Gcn排泥組成Gpn2669.1583總堿Na2CO3NaHCO3NaSO4NaCl13.50%9.88%5.72%7.16%0.99%13.75%10.07%5.83%7.30%1.

55、01%2915.8222總堿Na2CO3NaHCO3NaSO4NaCl14.77%9.29%6.69%8.63%1.20%13.75%9.45%6.81%8.78%1.22%Na2CO3NaHCO3NaSO4NaCl水不溶物2.33971.68512.17350.301449.50009.45%6.81%8.78%1.22%溶液質(zhì)量24.75Na2CO3NaHCO3NaSO4NaCl水不溶物1.82921.31741.69930.235702.06%1.49%1.92%0.27%0.00%Na2CO3NaHCO3NaSO4NaCl水不溶物0.510474134 0.36764940.47421

56、52840.06576708349.50002.06%1.49%1.92%0.27%溶液質(zhì)量24.75澄清泥組成Gcn洗泥液組成Gxs2排泥組成Gpn熱空氣t1由書查的140碳化塔熱量計(jì)算物料以0為基準(zhǔn)進(jìn)塔溫度t70CO2比熱 Kj/kg/kN2比熱 Kj/kg/k0.8791.0461、進(jìn)塔堿液帶入熱量相對誤差絕對誤差785694.70650.00000.00%2、氣體帶入熱量CO29150.3654522791.8667563、反應(yīng)放出熱237264.985總熱量1032110.0574、母液熱量462774.70145、NaHCO3結(jié)晶放出熱15630.464346、尾氣熱量CO2305

57、35.22393604.90446387、熱損失103211.00578、冷卻水移走熱量419958.6617碳化塔熱量衡算表項(xiàng)目輸入液體785694.7065固體NaHCO3氣體9150.365452干燥反應(yīng)237264.985水箱冷卻總計(jì)1032110.057t1t2tm2908.7514總堿Na2CO3NaHCO3NaSO4NaCl13.52%9.40%6.53%10.19%1.41%13.75%9.56%6.64%10.37%1.44%Na2CO3NaHCO3NaSO4NaCl水不溶物2.36601.64342.56690.356049.50009.56%6.64%10.37%1.44

58、%溶液質(zhì)量24.7500Na2CO3NaHCO3NaSO4NaCl水不溶物1.84081.27861.99710.277002.08%1.44%2.25%0.31%0.00%Na2CO3NaHCO3NaSO4NaCl水不溶物0.525150590.364760.5697379660.07901475449.50002.12%1.47%2.30%0.32%溶液質(zhì)量24.7500澄清泥組成Gcn洗泥液組成Gxs2排泥組成Gpn放空氣140干燥水不溶物水2.58%77.08%100.00%79.12%100.00%總計(jì)74.25100.00%總計(jì)74.25100.00%化堿、澄清、洗泥物料衡算(以1

59、000kg天然堿為例)澄清泥組成Gcn排泥組成Gpn水不溶物水1.85%74.39%100.00%75.79%100.00%水不溶物水編號11.70%72.49%100.00%名稱天然堿73.74%100.00%質(zhì)量 kg/h總堿256.60Na2CO3242.50NaHCO322.30NaSO4109.60NaCl15.20水不溶物49.50水560.90總計(jì)1000水總計(jì)18.250374.2573.74%100.00%水總計(jì)83.606088.687594.27%100.00%水總計(jì)23.331894174.2594.27%100.00%澄清泥組成Gcn洗泥液組成Gxs2排泥組成Gpn0

60、.0326689.42103.953343.9863.940.046出塔溫度t液體比熱反應(yīng)熱Kj/mol453.9559.789水汽在30 Kj/kg/k水汽在65 Kj/kg/k2556.42614N2H2O3546.1263782812.372318N2H2O7683.2738222247.04565輸出損失462774.701415630.4643430535.22393碳化塔熱量計(jì)算碳化塔熱量衡算表419958.6617928899.0513103211.00571032110.057302527.42407474水不溶物水1.70%70.77%100.00%71.99%100.00%