高分子材料化學(xué)3

1、XCH2=CHA+R- +XRCH2CH-A+Na-Na+-+Na+CH2=CHX+CH2-CHX-CH2-CHX-CHCH2XCH2CH-X2+nCH2=CHXCH3CHXCH2-CH-A+XnCH3CXHCH2CH-A+XCH3CH-A+XCH2=CHXCH2-CH-A+XCH3CHXCH2CHXCH2CH-XH-+XCHCH+H2OROHCO2XCH2-CHXCH2-CH-A+XCH2-CH2XCH2-CH2CH2-CH-A+XXCH2-CHCOO-ARCOOH+AOHROARCOOA+XCH2-CH-A+X高活性鏈CHCHX+HA+CH2-CH-A+X高活性鏈CH2CHX+X-X低活性

2、鏈穩(wěn)定鏈CH2CH2XCHCHXCH2CHCH2CCHCHCH2CH-Na+Na+-CHCH2CH2CH-Na+CH2CH-Li+CO2XXCH2CHCOO-Li+CH2CH-Li+CH2CCH3COOCH3CH2CHCH2CCH3COCH2CHCH2CCH3CO ClCH2CH2ClCH2ClClCH2CH2CH-Li+S-SSB-SBSSBRBSCH2=CHXH+B- +CH3CH+B-X+nCH2=CHXCH3CHXCH2-CH+B-XnCH2-CH+B-XCH3CH+B-XCH2=CHXCH2-CH+B-XCH3CHXCH2CHXCH3CHXCH2-C+HB-X+H2OXCH2-C-O

3、H + H+B-HCH2-C+HB-X+CH2=CCH3CH3CH=CHX+CH3CCH3CH3+B-BF3 + H2OBF3OH- + H+SnCl4+RO- + R+SnCl4RORCH2CHXBCH2CH-CH2CH-CH2CH-XXXB+B+B+共價(jià)鍵緊密離子對(duì)松散離子對(duì)自由離子對(duì)Cat*CH2CH3CH2=CH2+CH2CH2CH2CH3Cat*+CH2=CH2CH2CH2CH2CH3Cat*Cat*(CH2CH2)CH2CH3n+Cat*(CH2CH2)CH2CH3nCat*(CH2CH2)CH2CH3nH2ORCOOHCat*Cat*OHOCORH(CH2CH2)CH2CH3+(

4、CH2CH2)CH2CH3H+nCO2+Cat*OCO(CH2CH2)CH2CH3Cat*(CH2CH2)CH2CH3nCH2CH3CH2=CH2+Cat*(CH2CH2)CH2CH3+(CH2CH2)CH2CH3+Cat*(CH2CH2)CH2CH3nCat*(CH2CH2)CH2CH3nnCH2=CHAlR3Cat*CH2CH3nR2AlRRRAlTiClClTiClRRR(CH2-CH)RAlTiClClCH3nRRCH2-CHRAlTiClClCH3RRCH2=CHCH3RAlTiClClRRCH2=CHCH3RAlTiClClRRCH2=CHRAlTiClClCH3配位移位重復(fù)配位移

5、位重復(fù)CH3CH2=CHCH3TiClRCH2-CHTiClRCH2=CHCH3TiClCH2CHCH3RRCHCH3CH2ClTiCH2=CHCH3n=CH-CH2CH2CH=n催化劑OnCHCH2CH2OCHCF3CF3CH-CH=CH-CHnCF3CF3CF3CF3CHCHCH=CH-CH=CHnCCMeOMeMeOSiMe3OCCMeCH2OMeMeOMeMeOSiMe3MeCH2OCCCCMeOMMAMMAMMAMeOMeOSiMe3MeCH2OCCCCMeO()CH2nH()Y-CH2Y-C=C-Z+Y-CH-C-C-ZYHOOC(CH2)3SiO-SiO-(CH2)3COOH + D4CH3CH3CH3CH3CH3CH