化工設(shè)計競賽附錄3-物料衡算表

2019“東華科技-恒逸石化杯”第十三屆全國大學(xué)生化工設(shè)計競賽中國石化中科煉化

年產(chǎn)10萬噸醋酸乙烯酯和4.5萬噸的碳酸乙烯酯項目物料衡算表丹東路1號團(tuán)隊隊伍成員：崔榮凱、趙越、崔梓銘、王金林、陳子璇指導(dǎo)老師：封瑞江、王吉林、龍文宇、鞠佳、梁飛雪目錄TOC\o"1-5"\h\z\o"CurrentDocument"第一章概述 1\o"CurrentDocument"第二章物料衡算原理 2\o"CurrentDocument"第三章物料衡算任務(wù) 4\o"CurrentDocument"第四章物料衡算表 5\o"CurrentDocument"醋酸乙烯合成工段 5\o"CurrentDocument"氣體分離車間 12\o"CurrentDocument"醋酸乙烯精制車間 25\o"CurrentDocument"碳酸乙烯合成精制工段 41第一章概述本項目以總廠在廣東省湛江市中國石化中科煉化化工業(yè)園區(qū)的中國石化中科煉化責(zé)任有限公司的醋酸為主要工業(yè)原料進(jìn)行生產(chǎn)醋酸乙烯烯酯。以醋酸為原料經(jīng)醋酸乙烯酯合成工段、氣體分離工段、醋酸乙烯精制工段、碳酸乙烯合成精制工段。設(shè)計過程中利用AspenPlus對全流程進(jìn)行模擬，并在此基礎(chǔ)上完成物料衡算、能量衡算，Aspenplus全模擬流程如圖1-1所示。原料氧氣醋酸蒸發(fā)器品酸乙烯合成反應(yīng)器圖1-1第二章物料衡算原理系統(tǒng)累計的質(zhì)量=輸入系統(tǒng)的質(zhì)量一輸出系統(tǒng)的質(zhì)量+反應(yīng)生成的質(zhì)量一反應(yīng)消耗的質(zhì)量假設(shè)系統(tǒng)無泄漏，有：dF/dt=FIN-FouT+GR-CR當(dāng)系統(tǒng)無化學(xué)反應(yīng)發(fā)生時，有：dF/dt=FIN-FouT在穩(wěn)定狀態(tài)下，有：dF/dt=FIN-FOUT=0，F(xiàn)IN=FOUT注：FIN一進(jìn)入系統(tǒng)的物料流率；fout一流出系統(tǒng)的物料流率；GR—反應(yīng)產(chǎn)生物料速率；CR—反應(yīng)消耗物料速率。第三章物料衡算任務(wù)通過對系統(tǒng)整體以及部分主要單元的詳細(xì)物料衡算，得到主、副產(chǎn)品的產(chǎn)量，原料的消耗量，“三廢”的排放量以及最后產(chǎn)品的質(zhì)量指標(biāo)等關(guān)鍵經(jīng)濟(jì)技術(shù)指標(biāo)，對所選工藝路線、設(shè)計流程進(jìn)行定量評述，為后階段的設(shè)計提供依據(jù)。

第四章物料衡算表醋酸乙烯合成工段換熱器E0101UnitsS0110S0111FromV0101E0101ToE0101R0101TemperatureC115.7568307155.5Pressurebar11MoleFractionsMassFlowskg/hr87279.2417687279.24176MassFractionsVolumeFlowcum/hr82889.452691360.09206MolarVaporFraction11MolarLiquidFraction00MoleFlowskmol/hr2563.4593952563.459395O2kmol/hr161.686741161.686741N2kmol/hr1.0084817951.008481795H2Okmol/hr97.7795293297.77952932CH3COOHkmol/hr222.33194222.33194C2H4kmol/hr1542.4895921542.489592VACkmol/hr0.166288640.16628864CO2kmol/hr537.9968222537.9968222EOkmol/hr00ECkmol/hr00EGkmol/hr00MoleFractionsMassFlowskg/hr87279.2417687279.24176MassFractionsVolumeFlowcum/hr82889.452691360.09206

E0102UnitsS0110S0111FromV0101E0101ToE0101R0101TemperatureC115.7568155.5Pressurebar11MoleFractionsMassFlowskg/hr87279.2487279.24MassFractionsVolumeFlowcum/hr82889.4591360.09MolarVaporFraction11MolarLiquidFraction00MoleFlowskmol/hr2563.4592563.459O2kmol/hr161.6867161.6867N2kmol/hr1.0084821.008482H2Okmol/hr97.7795397.77953CH3COOHkmol/hr222.3319222.3319C2H4kmol/hr1542.491542.49VACkmol/hr0.1662890.166289CO2kmol/hr537.9968537.9968EOkmol/hr00ECkmol/hr00EGkmol/hr00MoleFractionsMassFlowskg/hr87279.2487279.24MassFractionsVolumeFlowcum/hr82889.4591360.09

E0103UnitsS0110S0111FromV0101E0101ToE0101R0101TemperatureC115.7568155.5Pressurebar11MoleFractionsMassFlowskg/hr87279.2487279.24MassFractionsVolumeFlowcum/hr82889.4591360.09MolarVaporFraction11MolarLiquidFraction00MoleFlowskmol/hr2563.4592563.459O2kmol/hr161.6867161.6867N2kmol/hr1.0084821.008482H2Okmol/hr97.7795397.77953CH3COOHkmol/hr222.3319222.3319C2H4kmol/hr1542.491542.49VACkmol/hr0.1662890.166289CO2kmol/hr537.9968537.9968EOkmol/hr00ECkmol/hr00EGkmol/hr00MoleFractionsMassFlowskg/hr87279.2487279.24MassFractionsVolumeFlowcum/hr82889.4591360.09

混合器V0101UnitsS0102S0109S0110FromT0101V0101ToV0101V0101E0101TemperatureC25119.289115.7568Pressurebar18.9451MoleFractionsMassFlowskg/hr5191.96682087.27687279.24MassFractionsVolumeFlowcum/hr4020.5488759.110982889.45MolarVaporFraction111MolarLiquidFraction000MoleFlowskmol/hr162.18972401.26972563.459O2kmol/hr161.68670161.6867N2kmol/hr0.0026351.00584681.008482H2Okmol/hr0.15027997.6292597.77953CH3COOHkmol/hr0222.33194222.3319C2H4kmol/hr01542.48961542.49VACkmol/hr00.16628860.166289CO2kmol/hr0.35537.64682537.9968EOkmol/hr000ECkmol/hr000EGkmol/hr000MoleFractionsMassFlowskg/hr5191.96682087.27687279.24MassFractionsVolumeFlowcum/hr4020.5488759.110982889.45

壓縮機(jī)C0101UnitsS0102S0109S0110FromT0101V0101ToV0101V0101E0101TemperatureC25119.289115.7568Pressurebar18.9451MoleFractionsMassFlowskg/hr5191.96682087.2887279.24MassFractionsVolumeFlowcum/hr4020.5488759.11182889.45MolarVaporFraction111MolarLiquidFraction000MoleFlowskmol/hr162.18972401.272563.459O2kmol/hr161.68670161.6867N2kmol/hr0.0026351.0058471.008482H2Okmol/hr0.15027997.6292597.77953CH3COOHkmol/hr0222.3319222.3319C2H4kmol/hr01542.491542.49VACkmol/hr00.1662890.166289CO2kmol/hr0.35537.6468537.9968EOkmol/hr000ECkmol/hr000EGkmol/hr000MoleFractionsMassFlowskg/hr5191.96682087.2887279.24MassFractionsVolumeFlowcum/hr4020.5488759.11182889.45

反應(yīng)器R0101UnitsS0102S0109S0110FromT0101V0101ToV0101V0101E0101TemperatureC25119.289115.7568Pressurebar18.9451MoleFractionsMassFlowskg/hr5191.96682087.2887279.24MassFractionsVolumeFlowcum/hr4020.5488759.11182889.45MolarVaporFraction111MolarLiquidFraction000MoleFlowskmol/hr162.18972401.272563.459O2kmol/hr161.68670161.6867N2kmol/hr0.0026351.0058471.008482H2Okmol/hr0.15027997.6292597.77953CH3COOHkmol/hr0222.3319222.3319C2H4kmol/hr01542.491542.49VACkmol/hr00.1662890.166289CO2kmol/hr0.35537.6468537.9968EOkmol/hr000ECkmol/hr000EGkmol/hr000MoleFractionsMassFlowskg/hr5191.96682087.2887279.24MassFractionsVolumeFlowcum/hr4020.5488759.11182889.45

T0101UnitsS0102S0109S0110FromT0101V0101ToV0101V0101E0101TemperatureC25119.289115.7568Pressurebar18.9451MoleFractionsMassFlowskg/hr5191.96682087.2887279.24MassFractionsVolumeFlowcum/hr4020.5488759.11182889.45MolarVaporFraction111MolarLiquidFraction000MoleFlowskmol/hr162.18972401.272563.459O2kmol/hr161.68670161.6867N2kmol/hr0.0026351.0058471.008482H2Okmol/hr0.15027997.6292597.77953CH3COOHkmol/hr0222.3319222.3319C2H4kmol/hr01542.491542.49VACkmol/hr00.1662890.166289CO2kmol/hr0.35537.6468537.9968EOkmol/hr000ECkmol/hr000EGkmol/hr000MoleFractionsMassFlowskg/hr5191.96682087.2887279.24MassFractionsVolumeFlowcum/hr4020.5488759.11182889.45氣體分離車間換熱器E201UnitsS0112S0201FromR0101E0202ToE0202T0201TemperatureC155.5118Pressurebar88MolarVaporFraction11MassFlowskg/hr87280.4887280.48MassFractionsVolumeFlowcum/hr11110.6410138.63MolarLiquidFraction00EnthalpyFlowGcal/hr-71.5622-72.7616MoleFlowskmol/hr2494.0142494.014O2kmol/hr00N2kmol/hr1.0084821.008482H2Okmol/hr298,242298,242CH3COOHkmol/hr83.3635983.36359C2H4kmol/hr1372.7741372.774VACkmol/hr139.1346139.1346CO2kmol/hr599.491599.491EOkmol/hr00ECkmol/hr00EGkmol/hr00

E0202UnitsS0112S0201FromR0101E0202ToE0202T0201TemperatureC155.5118Pressurebar88MolarVaporFraction11MassFlowskg/hr87280.4887280.48MassFractionsVolumeFlowcum/hr11110.6410138.63MolarLiquidFraction00EnthalpyFlowGcal/hr-71.5622-72.7616MoleFlowskmol/hr2494.0142494.014O2kmol/hr00N2kmol/hr1.0084821.008482H2Okmol/hr298,242298,242CH3COOHkmol/hr83.3635983.36359C2H4kmol/hr1372.7741372.774VACkmol/hr139.1346139.1346CO2kmol/hr599.491599.491EOkmol/hr00ECkmol/hr00EGkmol/hr00E0203UnitsS0112S0201FromR0101E0202ToE0202T0201TemperatureC155.5118Pressurebar88MolarVaporFraction11MassFlowskg/hr87280.4887280.48MassFractionsVolumeFlowcum/hr11110.6410138.63MolarLiquidFraction00EnthalpyFlowGcal/hr-71.5622-72.7616MoleFlowskmol/hr2494.0142494.014O2kmol/hr00N2kmol/hr1.0084821.008482H2Okmol/hr298,242298,242CH3COOHkmol/hr83.3635983.36359C2H4kmol/hr1372.7741372.774VACkmol/hr139.1346139.1346CO2kmol/hr599.491599.491EOkmol/hr00ECkmol/hr00EGkmol/hr00

E0204UnitsS0112S0201FromR0101E0202ToE0202T0201TemperatureC155.5118Pressurebar88MolarVaporFraction11MassFlowskg/hr87280.4887280.48MassFractionsVolumeFlowcum/hr11110.6410138.63MolarLiquidFraction00EnthalpyFlowGcal/hr-71.5622-72.7616MoleFlowskmol/hr2494.0142494.014O2kmol/hr00N2kmol/hr1.0084821.008482H2Okmol/hr298,242298,242CH3COOHkmol/hr83.3635983.36359C2H4kmol/hr1372.7741372.774VACkmol/hr139.1346139.1346CO2kmol/hr599.491599.491EOkmol/hr00ECkmol/hr00EGkmol/hr00

混合器V0202UnitsS0210S0306S0211FromV0303V0202ToV0202V0202E0204TemperatureC30186.6343159.7596Pressurebar8.58.58.5MolarVaporFraction000MassFlowskg/hr489.04611964.2092453.248MassFractionsVolumeFlowcum/hr0.4877512.4802622.943034MolarLiquidFraction111EnthalpyFlowGcal/hr-1.088-4.18278-5.27077MoleFlowskmol/hr12.0863547.9136560O2kmol/hr000N2kmol/hr01.83E-481.83E-48H2Okmol/hr5.63238721.7218827.35442CH3COOHkmol/hr6.45396526.1917732.64558C2H4kmol/hr02.88E-312.88E-31VACkmol/hr04.11E-134.11E-13CO2kmol/hr02.29E-342.29E-34EOkmol/hr000ECkmol/hr000EGkmol/hr000

P0201UnitsS0210S0306S0211FromV0303V0202ToV0202V0202E0204TemperatureC30186.6343159.7596Pressurebar8.58.58.5MolarVaporFraction000MassFlowskg/hr489.04611964.2092453.248MassFractionsVolumeFlowcum/hr0.4877512.4802622.943034MolarLiquidFraction111EnthalpyFlowGcal/hr-1.088-4.18278-5.27077MoleFlowskmol/hr12.0863547.9136560O2kmol/hr000N2kmol/hr01.83E-481.83E-48H2Okmol/hr5.63238721.7218827.35442CH3COOHkmol/hr6.45396526.1917732.64558C2H4kmol/hr02.88E-312.88E-31VACkmol/hr04.11E-134.11E-13CO2kmol/hr02.29E-342.29E-34EOkmol/hr000ECkmol/hr000EGkmol/hr000

P0202UnitsS0204S0205FromT0201P0202ToP0202T0202TemperatureC104.2798104.3666Pressurebar7.8199MolarVaporFraction00MassFlowskg/hr95190.3895190.38MassFractionsVolumeFlowcum/hr107.8605107.8752MolarLiquidFraction11EnthalpyFlowGcal/hr-193.909-193.904MoleFlowskmol/hr2303.5842303.584O2kmol/hr00N2kmol/hr0.0049330.004933H2Okmol/hr1074.1581074.158CH3COOHkmol/hr1016.6421016.642C2H4kmol/hr47.9031247.90312VACkmol/hr147.0279147.0279CO2kmol/hr17.8475617.84756EOkmol/hr00ECkmol/hr00EGkmol/hr00P0203UnitsS0204S0205FromT0201P0202ToP0202T0202TemperatureC104.2798104.3666Pressurebar7.8199MolarVaporFraction00MassFlowskg/hr95190.3895190.38MassFractionsVolumeFlowcum/hr107.8605107.8752MolarLiquidFraction11EnthalpyFlowGcal/hr-193.909-193.904MoleFlowskmol/hr2303.5842303.584O2kmol/hr00N2kmol/hr0.0049330.004933H2Okmol/hr1074.1581074.158CH3COOHkmol/hr1016.6421016.642C2H4kmol/hr47.9031247.90312VACkmol/hr147.0279147.0279CO2kmol/hr17.8475617.84756EOkmol/hr00ECkmol/hr00EGkmol/hr00

P0204UnitsS0204S0205FromT0201P0202ToP0202T0202TemperatureC104.2798104.3666Pressurebar7.8199MolarVaporFraction00MassFlowskg/hr95190.3895190.38MassFractionsVolumeFlowcum/hr107.8605107.8752MolarLiquidFraction11EnthalpyFlowGcal/hr-193.909-193.904MoleFlowskmol/hr2303.5842303.584O2kmol/hr00N2kmol/hr0.0049330.004933H2Okmol/hr1074.1581074.158CH3COOHkmol/hr1016.6421016.642C2H4kmol/hr47.9031247.90312VACkmol/hr147.0279147.0279CO2kmol/hr17.8475617.84756EOkmol/hr00ECkmol/hr00EGkmol/hr00T0201UnitsS0201S0203S0206S0204S0207FromE0202P0201T0202T0201T0201ToT0201T0201T0201P0202E0203TemperatureC11833.0631570.12503104.279835.55438Pressurebar89.37.8247.8197.8MolarVaporFraction10101MassFlowskg/hr87280.4870338.632895.86395190.3865324.6MassFractionsVolumeFlowcum/hr10138.6370.30489284.0586107.86056528.885MolarLiquidFraction01010EnthalpyFlowGcal/hr-72.7616-155.245-1.88049-193.909-39.7647MoleFlowskmol/hr2494.0141715.80177.868592303.5841984.1O2kmol/hr00000N2kmol/hr1.0084826.57E-470.0049330.0049331.008482H2Okmol/hr298,242777.8724.1278941074.1586.083599CH3COOHkmol/hr83.36359937.92922.11E-211016.6424.650862C2H4kmol/hr1372.7741.03E-2947.8313947.903121372.702VACkmol/hr139.13461.47E-118.066972147.02790.173739CO2kmol/hr599.4918.21E-3317.837417.84756599.4808EOkmol/hr00000ECkmol/hr00000EGkmol/hr00000

T0202UnitsS0205S0206S0208FromP0202T0202T0202ToT0202T0201V0201TemperatureC104.366670.12503166.6321Pressurebar97.8248MolarVaporFraction010MassFlowskg/hr95190.382895.86392294.54MassFractionsVolumeFlowcum/hr107.8752284.0586114.2433MolarLiquidFraction101EnthalpyFlowGcal/hr-193.904-1.88049-188.697MoleFlowskmol/hr2303.58477.868592225.715O2kmol/hr000N2kmol/hr0.0049330.0049331.03E-08H2Okmol/hr1074.1584.1278941070.031CH3COOHkmol/hr1016.6422.11E-211016.642C2H4kmol/hr47.9031247.831390.071046VACkmol/hr147.02798.066972138.9617CO2kmol/hr17.8475617.83740.009609EOkmol/hr000ECkmol/hr000EGkmol/hr000T0203UnitsS0209S0213S0215S0216S0217FromE0203P0203P0204T0203T0203ToT0203T0203T0203V0201V0203TemperatureC11835,1424220.6602482.043473.76144Pressurebar7.89.397.87.792MolarVaporFraction10001MassFlowskg/hr65324.62453.2481801.5283083.8766495.5MassFractionsVolumeFlowcum/hr8272.5532.4588371.8048973.3860577634.279MolarLiquidFraction01110EnthalpyFlowGcal/hr-37.9835-5.42019-6.8339-6.8454-43.3922MoleFlowskmol/hr1984.16010081.708612062.391O2kmol/hr00000N2kmol/hr1.0084821.83E-4800.000211.008272H2Okmol/hr6.08359927,3544210041,2000492.23797CH3COOHkmol/hr4.65086232.64558037.183960.112481C2H4kmol/hr1372.7022.88E-3102.3797121370.323VACkmol/hr0.1737394.11E-1300.0072740.166466CO2kmol/hr599.48082.29E-3400.93741598.5434EOkmol/hr00000ECkmol/hr00000EGkmol/hr00000

膜分離M0201UnitsS0219S0220S0221FromXV0201MR0201MR0201ToMR0201C0201V0401TemperatureC73.7614573.7614573.76145Pressurebar555MolarVaporFraction111MassFlowskg/hr8266.8385581.4642685.373MassFractionsVolumeFlowcum/hr1479.0881126.809352.2794MolarLiquidFraction000EnthalpyFlowGcal/hr-5.39460.314467-5.70907MoleFlowskmol/hr256.4001195.332461.06767O2kmol/hr000N2kmol/hr0.125350.1229250.002425H2Okmol/hr11.4671911.383950.083237CH3COOHkmol/hr0.0139840.0139840C2H4kmol/hr170.3609170.36090VACkmol/hr0.0206950.0206950CO2kmol/hr74.4119713.4299660.982EOkmol/hr000ECkmol/hr000EGkmol/hr000

醋酸乙烯精制車間換熱器E0301UnitsS0219S0220S0221FromXV0201MR0201MR0201ToMR0201C0201V0401TemperatureC73.7614573.7614573.76145Pressurebar555MolarVaporFraction111MassFlowskg/hr8266.8385581.4642685.373MassFractionsVolumeFlowcum/hr1479.0881126.809352.2794MolarLiquidFraction000EnthalpyFlowGcal/hr-5.39460.314467-5.70907MoleFlowskmol/hr256.4001195.332461.06767O2kmol/hr000N2kmol/hr0.125350.1229250.002425H2Okmol/hr11.4671911.383950.083237CH3COOHkmol/hr0.0139840.0139840C2H4kmol/hr170.3609170.36090VACkmol/hr0.0206950.0206950CO2kmol/hr74.4119713.4299660.982EOkmol/hr000ECkmol/hr000EGkmol/hr000

E0303UnitsS0313S0314FromE0304E0303ToE0303VX0302TemperatureC159.0053132.008Pressurebar65.6MolarVaporFraction0.0322020MassFlowskg/hr5262.4745262.543MassFractionsVolumeFlowcum/hr61.707385.965023MolarLiquidFraction0.9677981EnthalpyFlowGcal/hr-18.9392-19.1914MoleFlowskmol/hr288.9588288.9626O2kmol/hr00N2kmol/hr00H2Okmol/hr287.6076287.6114CH3COOHkmol/hr1.3512021.351202C2H4kmol/hr00VACkmol/hr5.89E-125.89E-12CO2kmol/hr00EOkmol/hr00ECkmol/hr00EGkmol/hr00E0306UnitsS0325S0335S0326S0336FromE0401T0304E0306E0306ToE0306E0306E0307V0305TemperatureC134.0716121.5374131.2249121.666Pressurebar64.12564.125MolarVaporFraction0.51424700.4730440.22023MassFlowskg/hr21558.7715294.3821558.7715294.38MassFractionsVolumeFlowcum/hr1772.71419.427461620.373326.6875MolarLiquidFraction0.48575310.5269560.77977EnthalpyFlowGcal/hr-39.5905-14.1107-39.8553-13.8459MoleFlowskmol/hr608.7156177.7557608.7156177.7557O2kmol/hr0000N2kmol/hr0.0002132.75E-460.0002132.75E-46H2Okmol/hr450.21830.127651450.21830.127651CH3COOHkmol/hr0.0002799.18E-060.0002799.18E-06C2H4kmol/hr2.6597872.43E-242.6597872.43E-24VACkmol/hr154.8209177.6281154.8209177.6281CO2kmol/hr1.016141.59E-261.016141.59E-26EOkmol/hr0000ECkmol/hr0000EGkmol/hr0000

E0307UnitsS0331S0332FromT0304E0308ToE0308V0308TemperatureC105.126925.96673Pressurebar44MolarVaporFraction10MassFlowskg/hr9821.9519821.966MassFractionsVolumeFlowcum/hr1232.97210.9068MolarLiquidFraction01EnthalpyFlowGcal/hr-9.86153-11.341MoleFlowskmol/hr156.8109156.8111O2kmol/hr00N2kmol/hr0.0010360.001036H2Okmol/hr40.848640.84861CH3COOHkmol/hr2.79E-092.79E-09C2H4kmol/hr12.074912.0749VACkmol/hr99,2204199.22058CO2kmol/hr4.6659674.665968EOkmol/hr00ECkmol/hr00EGkmol/hr00E0308UnitsS0331S0332FromT0304E0308ToE0308V0308TemperatureC105.126925.96673Pressurebar44MolarVaporFraction10MassFlowskg/hr9821.9519821.966MassFractionsVolumeFlowcum/hr1232.97210.9068MolarLiquidFraction01EnthalpyFlowGcal/hr-9.86153-11.341MoleFlowskmol/hr156.8109156.8111O2kmol/hr00N2kmol/hr0.0010360.001036H2Okmol/hr40.848640.84861CH3COOHkmol/hr2.79E-092.79E-09C2H4kmol/hr12.074912.0749VACkmol/hr99,2204199.22058CO2kmol/hr4.6659674.665968EOkmol/hr00ECkmol/hr00EGkmol/hr00

E0309UnitsS0342S0343FromV0307E0309ToE0309TemperatureC106.342440Pressurebar1.299811.29981MolarVaporFraction0.074620MassFlowskg/hr5587.0875587.087MassFractionsVolumeFlowcum/hr562.36465.715799MolarLiquidFraction0.925381EnthalpyFlowGcal/hr-20.3041-20.9027MoleFlowskmol/hr307.3408307.3408O2kmol/hr00N2kmol/hr2.92E-062.92E-06H2Okmol/hr305.8429305.8429CH3COOHkmol/hr0.7961870.796187C2H4kmol/hr0.4107240.410724VACkmol/hr0.1211830.121183CO2kmol/hr0.1698270.169827EOkmol/hr00ECkmol/hr00EGkmol/hr00

P0301UnitsS0302S0303FromE0301P0301ToP0301T0301TemperatureC8080.08739Pressurebar7.89MolarVaporFraction00MassFlowskg/hr95378.4195378.41MassFractionsVolumeFlowcum/hr102.4819102.4944MolarLiquidFraction11EnthalpyFlowGcal/hr-199.96-199.956MoleFlowskmol/hr2307.4242307.424O2kmol/hr00N2kmol/hr0.000210.00021H2Okmol/hr1111.2311111.231CH3COOHkmol/hr1053.8261053.826C2H4kmol/hr2.4507582.450758VACkmol/hr138.969138.969CO2kmol/hr0.9470190.947019EOkmol/hr00ECkmol/hr00EGkmol/hr00P0302UnitsS0302S0303FromE0301P0301ToP0301T0301TemperatureC8080.08739Pressurebar7.89MolarVaporFraction00MassFlowskg/hr95378.4195378.41MassFractionsVolumeFlowcum/hr102.4819102.4944MolarLiquidFraction11EnthalpyFlowGcal/hr-199.96-199.956MoleFlowskmol/hr2307.4242307.424O2kmol/hr00N2kmol/hr0.000210.00021H2Okmol/hr1111.2311111.231CH3COOHkmol/hr1053.8261053.826C2H4kmol/hr2.4507582.450758VACkmol/hr138.969138.969CO2kmol/hr0.9470190.947019EOkmol/hr00ECkmol/hr00EGkmol/hr00

P0303UnitsS0302S0303FromE0301P0301ToP0301T0301TemperatureC8080.08739Pressurebar7.89MolarVaporFraction00MassFlowskg/hr95378.4195378.41MassFractionsVolumeFlowcum/hr102.4819102.4944MolarLiquidFraction11EnthalpyFlowGcal/hr-199.96-199.956MoleFlowskmol/hr2307.4242307.424O2kmol/hr00N2kmol/hr0.000210.00021H2Okmol/hr1111.2311111.231CH3COOHkmol/hr1053.8261053.826C2H4kmol/hr2.4507582.450758VACkmol/hr138.969138.969CO2kmol/hr0.9470190.947019EOkmol/hr00ECkmol/hr00EGkmol/hr00混合器V0301UnitsS0315S0316S0317FromVX0302V0301V0301ToV0301T0302V0307TemperatureC132.008132.008132.008Pressurebar2.862.862.86MolarVaporFraction000MassFlowskg/hr5262.5434012.6891249.854MassFractionsVolumeFlowcum/hr5.9650234.548331.416692MolarLiquidFraction111EnthalpyFlowGcal/hr-19.1914-14.6335-4.55797MoleFlowskmol/hr288.9626220.33468.62859O2kmol/hr000N2kmol/hr000H2Okmol/hr287.6114219.303768.30768CH3COOHkmol/hr1.3512021.0302910.32091C2H4kmol/hr000VACkmol/hr5.89E-124.49E-121.40E-12CO2kmol/hr000EOkmol/hr000ECkmol/hr000EGkmol/hr000

V0302UnitsS0319S0320S0321FromE0304V0302V0302ToV0302T0302P0302TemperatureC155.1202155.12155.12Pressurebar2.9952.9952.995MolarVaporFraction0.82823710MassFlowskg/hr30735.5725294.145441.204MassFractionsVolumeFlowcum/hr5429.2195423.036.17576MolarLiquidFraction0.17176301EnthalpyFlowGcal/hr-53.7386-43.8895-9.84884MoleFlowskmol/hr550.7319456.135594.59645O2kmol/hr000N2kmol/hr000H2Okmol/hr55.6003849.907165.698643CH3COOHkmol/hr495.1315406.228388.89781C2H4kmol/hr000VACkmol/hr4.16E-2600CO2kmol/hr000EOkmol/hr000ECkmol/hr000EGkmol/hr000

V0303UnitsS0305S0306S0307S0308FromT0301V0303V0303V0303ToV0303V0202E0201E0302TemperatureC186.6343186.6343186.6343186.6343Pressurebar8.58.58.58.5MolarVaporFraction0000MassFlowskg/hr78994.291964.20970338.636691.214MassFractionsVolumeFlowcum/hr99.748342.48026288.81868.449187MolarLiquidFraction1111EnthalpyFlowGcal/hr-168.218-4.18278-149.786-14.2489MoleFlowskmol/hr1926.93647.913651715.801163.2212O2kmol/hr0000N2kmol/hr7.38E-471.83E-486.57E-476.25E-48H2Okmol/hr873.585421.72188777.87273.99708CH3COOHkmol/hr1053.35126.19177937.929289.2241C2H4kmol/hr1.16E-292.88E-311.03E-299.82E-31VACkmol/hr1.65E-114.11E-131.47E-111.40E-12CO2kmol/hr9.22E-332.29E-348.21E-337.81E-34EOkmol/hr0000ECkmol/hr0000EGkmol/hr0000T0301UnitsS0303S0304S0305FromP0301T0301T0301ToT0301T0303V0303TemperatureC80.08739113.2362186.6343Pressurebar96.58.5MolarVaporFraction000MassFlowskg/hr95378.4116384.1378994.29MassFractionsVolumeFlowcum/hr102.494419.9262399.74834MolarLiquidFraction111EnthalpyFlowGcal/hr-199.956-26.8692-168.218MoleFlowskmol/hr2307.424380.48771926.936O2kmol/hr000N2kmol/hr0.000210.000217.38E-47H2Okmol/hr1111.231237.6454873.5854CH3COOHkmol/hr1053.8260.4752861053.351C2H4kmol/hr2.4507582.4507581.16E-29VACkmol/hr138.969138.9691.65E-11CO2kmol/hr0.9470190.9470199.22E-33EOkmol/hr000ECkmol/hr000EGkmol/hr000

T0302UnitsS0310S0316S0320S0311S0318FromE0302V0301V0302T0302T0302ToT0302T0302T0302C0301E0304TemperatureC143132.008155.12132.1091153.75Pressurebar8.52.862.9952.862.995MolarVaporFraction00110MassFlowskg/hr6691.2144012.68925294.145262.47430735.57MassFractionsVolumeFlowcum/hr7.7954774.548335423.033404.31634.98773MolarLiquidFraction11001EnthalpyFlowGcal/hr-14.4165-14.6335-43.8895-16.4992-56.4403MoleFlowskmol/hr163.2212220.334456.1355288.9588550.7319O2kmol/hr00000N2kmol/hr6.25E-480000H2Okmol/hr73.99708219.303749.90716287.607655.60038CH3COOHkmol/hr89,22411.030291406.22831.351202495.1315C2H4kmol/hr9.82E-310000VACkmol/hr1.40E-124.49E-1205.89E-124.16E-26CO2kmol/hr7.81E-340000EOkmol/hr00000ECkmol/hr00000EGkmol/hr00000T0303UnitsS0304S0328S0324S0330FromT0301V0304T0303T0303ToT0303T0303E0401V0307TemperatureC113.2362102.8203147.6111159.0309Pressurebar6.5666.011MolarVaporFraction0010MassFlowskg/hr16384.138916.01621558.773741.374MassFractionsVolumeFlowcum/hr19.926239.926533549.1644.391375MolarLiquidFraction1101EnthalpyFlowGcal/hr-26.8692-29.2048-36.742-13.5785MoleFlowskmol/hr380.4877434.7967608.7156206.5688O2kmol/hr0000N2kmol/hr0.000212.52E-060.0002131.90E-34H2Okmol/hr237.6454418.6663450.2183206.0935CH3COOHkmol/hr0.4752860.0002710.0002790.475277C2H4kmol/hr2.4507580.2090292.6597871.17E-21VACkmol/hr138.96915.85196154.82091.49E-20CO2kmol/hr0.9470190.0691211.016141.68E-23EOkmol/hr0000ECkmol/hr0000EGkmol/hr0000

T0304UnitsS0329S0334S0337S0331S0335FromV0304P0303V0305T0304T0304ToT0304T0304T0304E0308E0306TemperatureC102.820329.36842121.666105.1269121.5374Pressurebar654.12544.125MolarVaporFraction10110MassFlowskg/hr12642.759109.4763364.1299821.95115294.38MassFractionsVolumeFlowcum/hr906.100310.22552311.52891232.97219.42746MolarLiquidFraction01001EnthalpyFlowGcal/hr-12.0297-9.09972-2.84285-9.86153-14.1107MoleFlowskmol/hr173.9189121.500939.14716156.8109177.7557O2kmol/hr00000N2kmol/hr0.000210.00082600.0010362.75E-46H2Okmol/hr31.551949.3351880.08912540.84860.127651CH3COOHkmol/hr8.52E-062.22E-096.60E-072.79E-099.18E-06C2H4kmol/hr2.4507589.624139012.07492.43E-24VACkmol/hr138.96998.8218139.0580499.22041177.6281CO2kmol/hr0.9470193.71894804.6659671.59E-26EOkmol/hr00000ECkmol/hr00000EGkmol/hr00000

碳酸乙烯合成精制工段P0401UnitsS0329S0334S0337S0331S0335FromV0304P0303V0305T0304T0304ToT0304T0304T0304E0308E0306TemperatureC102.820329.36842121.666105.1269121.5374Pressurebar654.12544.125MolarVaporFraction10110MolarLiquidFraction01001MolarSolidFraction00000EnthalpyFlowGcal/hr-12.0297-9.09972-2.84285-9.86153-14.1107MoleFlowskmol/hr173.9189121.500939.14716156.8109177.7557O2kmol/hr00000N2kmol/hr0.000210.00082600.0010362.75E-46H2Okmol/hr31.551949.3351880.08912540.84860.127651CH3COOHkmol/hr8.52E-062.22E-096.60E-072.79E-099.18E-06C2H4kmol/hr2.4507589.624139012.07492.43E-24VACkmol/hr138.96998.8218139.0580499.22041177.6281CO2kmol/hr0.9470193.71894804.6659671.59E-26EOkmol/hr00000ECkmol/hr00000EGkmol/hr00000MoleFractionsMassFlowskg/hr12642.759109.4763364.1299821.95115294.38MassFractionsVolumeFlowcum/hr906.100310.22552311.52891232.97219.42746

反應(yīng)器R0401Units123FromS0404R0401-1R0402-2ToR0401-1R0402-2S0405TemperatureC127.3607130130Pressurebar2.52.52.5MolarVaporFraction10.8264770.826303MolarLiquidFraction00.1735230.173697MolarSolidFraction000EnthalpyFlowGcal/hr-9.86683-11.5456-11.5482MoleFlowskmol/hr434.0573373.0077372.9403O2kmol/hr000N2kmol/hr0.002680.002680.00268H2Okmol/hr0.0936330.0936330.000936CH3COOHkmol/hr000C2H4kmol/hr000VACkmol/hr000CO2kmol/hr61.049574.68E-090.025281EOkmol/hr372.9114311.8618311.7944ECkmol/hr061.0495761.02428EGkmol/hr000.092697MoleFractionsMassFlowskg/hr19116.4719116.4719116.47MassFractionsVolumeFlowcum/hr5781.6054137.7294136.118

混合器V0401UnitsS0221S0401S0402S0403Fr