尼龍料的主要牌號與性能.doc

尼龍66的主要牌號與性能01.3.6.1國產(chǎn)尼龍66的主要性能指標國內(nèi)生產(chǎn)尼龍66的廠家有：黑龍江省尼龍廠、上海塑料制品十八廠、遼陽化纖工業(yè)總公司、太原合成纖維廠、神馬集團、浙江衢州化工廠、宜興太湖尼龍廠、江蘇海安化工廠。其產(chǎn)品主要用制造各種機械、汽車、化工、電子電氣裝置的零部件，特別適合用于高強度或耐磨部件，如各種齒輪、滑輪、輥軸、軸承、泵體中葉輪、風(fēng)箱葉片、高壓密封圈、閥座、墊片、襯套、各種殼體、工具手柄、支撐架、電纜包層、汽車燈罩等。在電子儀器設(shè)備、繼電器等電氣設(shè)備中制造零件、電梯導(dǎo)軌、建筑裝飾扶手等。在醫(yī)療器械、體育用品和日用品上也有廣泛應(yīng)用，如棒球棒、滑雪板等。也可制成薄膜后與鋁箔等形成復(fù)合膜用于食品包裝，如軟包裝飲料、罐頭等。表01-73列出了幾家企業(yè)的尼龍66產(chǎn)品指標。表01-73 國產(chǎn)尼龍66的性能指標項目黑龍江省尼龍廠上海塑料制品十八廠江蘇宜興化工二廠I型II型分子量(1.52)104(1.52)104(1.82.2)104外觀乳白色，微黃色乳白色，微黃色白色或帶黃色粒乳白至淡黃色相對密度1.101.151.101.151.101.141.131.15粒度，粒/克,4040含水量，%，0.30.152粘度比0.403.003.00小黑點含量，%，33熔點，238248238248255260脆化溫度，-35-35馬丁耐熱，5060拉伸強度，MPa657060807080彎曲強度，MPa100（不斷）110（不斷）10012080120彎曲彈性模量，GPa23沖擊強度，kJ/m2缺口無缺口810601008 12硬度，MPaR118體積電阻率，cm101410141.8301015介電常數(shù)（1MHz）1.63成型收縮率，%1.52.201.3.6.2阻燃增強尼龍66的主要性能指標目前，國內(nèi)尚有許多廠家從事改性尼龍66樹脂的生產(chǎn)。生產(chǎn)阻燃尼龍66和阻燃增強尼龍66的主要廠家有：黑龍江省尼龍廠、黑龍江省化工研究所、上海賽璐珞廠、廣州蓮花山工程塑料廠、江陰市永建化工有限公司等。阻燃尼龍66主要用于低壓電器、機床電器、廣播電視工業(yè)中，制造各種阻燃零件如調(diào)壓器開關(guān)、儀器儀表外殼和電子電氣連接器等；生產(chǎn)玻纖增強尼龍66的主要廠家有：黑龍江省尼龍廠、上海德勝塑料廠、廣州蓮花山工程塑料廠、蘇州塑料一廠等。產(chǎn)品主要應(yīng)用于低壓電器工業(yè)，如交流接觸器底座、線圈骨架、行程開關(guān)等各種要求耐火性能的介電零件中。黑龍江省化學(xué)研究所還生產(chǎn)防老化尼龍。其主要指標列于表01-74中。表01-74國產(chǎn)改性尼龍66樹脂的主要性能指標指標阻燃尼龍66阻燃增強尼龍66防老化尼龍66玻纖增強尼龍66熔點，245250247250250260相對密度1.421.451.501.101.151.39吸水率，%0.51.0拉伸強度，MPa6012060162彎曲強度，MPa10018090196缺口沖擊強度，kJ/m251059.8熱變形溫度（1.8MPa），6022060220阻燃等級，UL94V-0V-0體積電阻率，cm101510131.510151014介電常數(shù)3表面電阻率，101301.3.6.3杜邦公司系列尼龍66產(chǎn)品的基本性能指標杜邦公司是主要的尼龍66生產(chǎn)廠家之一，其產(chǎn)品型號齊全，覆蓋面廣，滿足各行各業(yè)對尼龍66樹脂的不同性能要求，見表01-75。表01-75 杜邦公司Zytel尼龍66樹脂型號與用途型號產(chǎn)品特點用途未增強級Zytel 101LZytel 101FZytel 103HSLZytel 103FHSZytel 105FZytel EFE1068Zytel 135F增潤PA66快速成型熱穩(wěn)定性增潤尼龍66快速成型熱穩(wěn)定性尼龍66抗紫外線增潤尼龍66核化尼龍66增潤成核型尼龍66機械零件、消費品等增韌級Zytel114BK97Zytel408Zytel450Zytel490抗沖改性PA66增韌PA66增韌PA66增韌PA66具優(yōu)越的韌性和成型性超韌級ZytelST801超韌PA66杰出的耐沖擊性特制品Zytel122LZytelEFE8073ZytelFN714ZytelFN718抗水解增潤PA66增韌PA66擠出級PA66尼龍合金PA66尼龍合金玻纖增強Zytel70G20HSLZytel70G25HSLZytel70G30HSLZytel70G35HSLZytel70G43HSLZytel70G50HSLZytel70G60HSL20%GF，熱穩(wěn)定性增潤PA6625%GF，熱穩(wěn)定性PA6630%GF，熱穩(wěn)定性PA6635%GF，熱穩(wěn)定性PA6643%GF，熱穩(wěn)定性PA6650%GF，熱穩(wěn)定性PA6660%GF，熱穩(wěn)定性PA66抗水解玻纖增強級Zytel70G25HSLRZytel70G30HSLRZytel70G30HSR225%GF，熱穩(wěn)定性增潤抗水解PA6630%GF，熱穩(wěn)定性增潤抗水解PA6630%GF，熱穩(wěn)定性增潤超高抗水解性能PA66玻纖增強特制品級Zytel70G33GRAZytel70G35HSLXZytel70G35HSLRA4Zytel70GB40HSLZytelEFE7267Zytel74G20HSLZytel74G30LZytel70G30W玻纖增強增潤PA6635%GF，抗熱油脂性PA66高流動性玻纖增強PA6640%GF，熱穩(wěn)定性PA66可焊接性玻纖增強PA6620%GF，熱穩(wěn)定性PA66/6共混20%GF，PA66/6共混玻纖增強耐侯性PA66/6共混增韌玻纖增強級Zytel79G13LZytel80G14Zytel80G25Zytel70G33HS1R13%GF，增韌PA6614%GF，增韌PA6625%GF，增韌PA6635%GF，熱穩(wěn)定性增韌PA66阻燃級ZytelFR7200V0FZytelFR72G25V0ZytelFR70G25GWZytelFR70G25V0ZytelFR70M30V0ZytelFR70M40GW未增強PA66/6共聚物，UL94V-0(0.5mm)25%GF PA66/6共聚物，UL94V-0(0.5mm)25%GFPA66，熾熱棒850（1mm）25%GF，PA66，UL94V-0(0.5mm)30%礦物增強PA66，UL94V-0(1.6mm)40%礦物增強，熾熱棒960（1.5mm）高粘擠出級ZytelE40ZytelE42AZytelE50ZytelE51HSBZytelE53高粘PA66（RV=95150）高粘PA66（RV=180310）高粘PA66（RV=240270）熱穩(wěn)定性高粘PA66（RV=240470）高粘PA66（RV=470600）長條狀、管狀以及其它復(fù)雜成型品擠出用，或用于耐沖擊之成型品杜邦公司Zytel系列尼龍66的基本性能指標、力學(xué)性能指標、熱性能指標、電性能指標分別列于表01-76表01-79中。表01-76杜邦公司Zytel系列尼龍66的基本性能指標密度阻燃性吸水率吸濕率洛氏硬度落球沖擊硬度成型收縮率測試條件1.6mm23，飽和2350%RHMR流動方向標準ISO1183UL94ISO 622039/22039294-4單位g/cm3%MPa%101L,DAM50%RH1.14V-28.52.87959121108160H961/3085 H358/301.3101F,DAM50%RH1.14V-28.52.81.3103HSL,DAM50%RH1.14V-28.52.81.3103FHS,DAM50%RH1.14V-28.52.81.3105F,DAM1.14V-28.52.81.5EFE1068,DAM50%RH1.14V-28.52.8135F,DAM50%RH1.14V-28.52.787641231160.7408,DAM50%RH1.09HB72.271501151021.5450,DAM50%RH1.08HB72.21.8490,DAM50%RH1.08HB7.12.31.6801,DAM50%RH1.08HB6.72.2112891.7EFE8073,DAM50%RH1.0770G20HSL,DAM50%RH1.29HB6.82.1102851221150.470G35HSL,DAM50%RH1.41HB5.51.7105891251172852030.370G60HSL,DAM50%RH1.70HB3.41.00.270G25HSLR,DAM50%RH1.33HB6.42.00.370GB40HSL,DAM50%RH1.46HB7.31.71.380G14,DAM50%RH1.18HB6.22.01030.4FR7200V0F,DAM50%RH1.19V-06.42.61.2FR72G25V0,DAM50%RH1.49V-04.11.12131060.2E40,DAM50%RH1.142.61.5E42A,DAM50%RH1.14HB8.52.61.5表01-77杜邦公司Zytel系列尼龍66的力學(xué)性能指標屈服應(yīng)力屈服應(yīng)變斷裂應(yīng)變標稱斷裂應(yīng)變拉伸模量沖擊強度（無缺口）缺口沖擊強度測試條件50mm/min1mm/min23-3023-30標準ISO527-1/2179/1eU180/1A單位MPa%MPakJ/m2kJ/m2101L,DAM50%RH83534.5254050225031001200NBNBNBNB5.411.73.72.7101F,DAM50%RH83534.4254050185031001200NBNBNBNB5.411.73.72.7103HSL,DAM50%RH85534.4254050185031001250NBNBNBNB510.62.83.1103FHS,DAM50%RH85554.4253550185031001350NBNBNBNB510105F,DAM50%RH8560525305024503200150045NB555554123EFE1068,DAM50%RH85594.5253560186031001500NBNB511.5135F,DAM50%RH98694.5181850135036002100NBNBNBNB32.8408,DAM50%RH614362655100355022001100NBNBNBNB1920114450,DAM50%RH55405.42450100285022001000NBNBNBNB1770109490,DAM50%RH55405.5295010033502100950NBNBNBNB66831716801,DAM50%RH50406384050601002000900NBNBNBNB801002020EFE8073,DAM50%RH52375.53250100881002000950NBNB7593161570G20HSL,DAM50%RH1591032.87720053005469504310118870G35HSL,DAM50%RH2101553.241150089009810088771215101070G60HSL,DAM50%RH2301801.62.1200001500074806058129.587.570G25HSLR,DAM50%RH188115315860063005060604570GB40HSL,DAM50%RH904361350002700304025253.56.52.82.880G14,DAM50%RH110704105100340075758590141977FR7200V0F,DAM50%RH85504203900180050NB65653833FR72G25V0,DAM50%RH1351002.53.5920065005562706191288E40,DAM50%RH85554.428505030001200NBNBNBNB5.612.532.2E42A,DAM50%RH8652527505031001200NBNBNBNB5.611.94.34表01-78 杜邦公司Zytel系列尼龍66的熱學(xué)性能指標熔化溫度熱變形溫度維卡軟化點線性熱膨脹系數(shù)測試條件10K/min0.45MPa1.8MPa50N流動方向標準ISO3146C75-1/2306ASTM E831單位E-4 1/K101L262200702381.0101F262200702381.0103HSL262200702381.0103FHS262200702381.0105F262200702391.0EFE1068262700.85135F262210882431.21408262155662091.3245026292652001.6149026285682211.52801262132702131.2EFE80732621956570G20HSL2622602512550.3570G35HSL2622622542560.270G60HSL26226025524870G25HSLR2622622542570.3370GB40HSL2622201152460.680G142622552392400.39FR7200V0F255195752250.78FR72G25V02422412152200.27E40262205722421.0E42A262205722421.0表01-79 杜邦公司Zytel系列尼龍66的電學(xué)性能指標對比電弧徑跡指數(shù)介電強度表面電阻體積電阻相對介電率損耗因素測試條件100Hz1MHz100Hz1MHz標準IEC6011260243-160093600936025060250單位kV/mmcmE-4101L,DAM50%RH60031.5E12E15E16E133.810.93.54802100180750101F,DAM50%RH60051.5E12E12E16E133.810.93.54.614021001801000103HSL,DAM50%RH5253128E12E13E15E123.8133.54755800165700105F,DAM50%RH2731E15E13E15E123.64.6300600135F,DAM50%RH600253.98.73.83.9702400200600408,DAM50%RH60033.5E15E15E15E133.272.93.72001500200500450,DAM50%RH600E15E12490,DAM50%RH600801,DAM50%RH6003139E15E15E14E133.282.93.680180014055070G20HSL,DAM50%RH400E15E12E15E113.94.416070070G35HSL,DAM50%RH400E15E13E15E114.14.714062070G60HSL,DAM60070G25HSLR,DAME153.67070GB40HSL,DAM425E154.620080G14,DAM50%RH6003636.5E15E14E15E123.87.33.53.970180150580FR7200V0F,DAM50%RH5752623E14E14E15E114.13.8580160FR72G25V0,DAM50%RH3253525E154.260E40,DAM600E153.9100E42A,DAM50%RH30.5E15E134.310.33.64.2150200024075001.3.6.4 DSM公司的尼龍66樹脂的基本性能指標及用途DSM公司也是世界上著名的尼龍66樹脂生產(chǎn)商，其尼龍66樹脂分為Plaslube、Nylatron、Electrafil、Akulon等幾個系列，在汽車工業(yè)、電子電氣行業(yè)、消費品工業(yè)和機械制造行業(yè)得到廣泛應(yīng)用。表01-80DSM公司的尼龍66產(chǎn)品系列產(chǎn)品系列組成用途Akulon玻纖增強、增韌Electrafil碳纖維增強NylatronMoS2增潤滑、熱穩(wěn)定性拉伸強度、壓縮強度高，表面磨擦低，較高的熱穩(wěn)定性和尺寸穩(wěn)定性，高溫性能優(yōu)良，適合制造耐高溫的部件。PlaslubePTFE增潤滑優(yōu)秀的耐磨性能和耐摩擦性能，制造軸承、軸襯、套管的理想材料表01-81DSM公司的尼龍66樹脂的基本性能力學(xué)性質(zhì)拉伸強度伸長率拉伸模量撓曲強度撓曲模量沖擊強度(1/8)洛氏硬度壓縮強度剪切強度載荷變形測試條件缺口無缺口*單位MPa%GPaMPaMPakJ/m2-MPaMPa%ASTMD638D790D256D785D695D732D621J-1/101173.05.81765.52.1-J-1/201383.07.22076.93.2E60J-1/301972.510.32769.75.3E65J-1/402143.512.833112.46.3E70J-1/15/MF/251383.510.02149.72.3NY-16/MF/40973.07.21526.92.1J-1/30/HS1862629.54.6J-8/1397564.81384.16.340R115J-8/33134468.32077.68.642R107J-8/431584.0112288.98.4R109M-10161699.54.4NY-85450.0621.738NBR104NY-8/HS4950.0621.738NBR104S223D83701243.01.7D82J-1/CF/101384.07.62076.91.716.8E52124690.3J-1/CF/201933.013.829015.22.721E67172830.20J-1/CF/302482.020.735218.63.227E70200900.15/CF/30/TF/152072.629717.93.8138/CF/30/TF/13/SI/21932.527615.23.8172J-1/CF/402761.828.340721.43.831.5E7020789.60.12GS-512073.031010.34.6R120193GS/GS-HS93101383.41.5R11990NY-1/SI/274451002.8J-1/30/SI/2179232489.33.24.6J-1/30/TF/SI/2162232419.43.8R11950J-1/30/TF/15159-2389.35.3NY-1/TF/15614.3972.82.1基本性質(zhì)密度添加劑含量吸水率線性成型收縮率載荷變形溫度測試條件水，24hrs平衡1/8試條1/4試條1.8MPa0.45MPa單位-%cm/cmcm/cmASTMD792D570D955D955D645J-1/101.231.10.005243249J-1/201.301.00.004249254J-1/301.390.90.002252260J-1/401.500.80.001252260J-1/15/MF/251.500.70.002243260NY-16/MF/401.500.060.010221J-1/30/HS1.390.90.002252J-8/131.180.750.0040.007243254J-8/331.320.570.0020.004243257J-8/431.430.600.001243M-10161.39249NY-81.080.80.0200.02866221NY-8/HS1.080.82.02.866221S223D1.141.151.0074221J-1/CF/101.181.00.003249260J-1/CF/201.231.00.002254260J-1/CF/301.280.70.001254263J-1/CF/30/TF/151.380.60.001254J-1/CF/30/TF/13/SI/21.360.60.001252J-1/CF/401.330.60.0005257263GS-511.400.64.80.002252GS/GS-HS1.160.98.00.01484NY-1/SI/21.142(SI)1.00.01579J-1/30/SI/21.372(SI)30(GF)0.80.003252J-1/30/TF/SI/21.490.50.002254J-1/30/TF/151.5230(GF)15(PTFE)0.60.002254260NY-1/TF/151.2315(PTFE)0.70.01593阻燃性和電性質(zhì)UL指數(shù)表面電阻體積電阻屏蔽系數(shù)磨耗系數(shù)靜摩擦系數(shù)動摩擦系數(shù)測試條件1/161000MHz2000PV，環(huán)境溫度1300PV,1490.28MPa環(huán)境溫度0.28MPa環(huán)境溫度50ft/min單位-Ohms/sqOhm-cmdB10-10in3min/ft-lb-hr-ASTMUL94D4496C611ES7-83D3702DSM內(nèi)部標準J-8/13HBJ-8/33HBJ-8/43HBNY-8HBJ-1/CF/10HB104105102103-J-1/CF/20HB10310410100-J-1/CF/30HB1021031102030J-1/CF/30/TF-1/CF/30/TF/13/SI/2102103110J-1/CF/40HB101000.113040GS-51HB551000.240.28GS/GS-HSHB40900.260.25NY-1/SI/23000.140.15J-1/30/SI/2HBJ-1/30/TF/SI/2170.200.25NY-1/TF/1