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1、Mater., 2019, 31, 1904690中科院大連化物所 (2019)年度冠名獎(jiǎng)推薦表 (集體)被推薦集體名稱DNL17部負(fù)責(zé)人姓名李先鋒申報(bào)冠名獎(jiǎng)獎(jiǎng)項(xiàng)名稱科技創(chuàng)新獎(jiǎng)被推薦集體人員情況職工: 38 名;研究生: 29 名;返聘職工: 2 名主要事跡:(800 字,小四宋體,單倍行距。主要獲獎(jiǎng)、專利、專著、論文等,請(qǐng)列目錄附后)2019 年研究團(tuán)隊(duì)獲得了包括國家部委、中科院以及企業(yè)的各項(xiàng)支持,包括牽頭 1 項(xiàng)中科院先導(dǎo) A 項(xiàng)目,1 項(xiàng)中科院前沿科學(xué)重點(diǎn)研究項(xiàng)目, 2 項(xiàng)中科院 STS 項(xiàng)目,1 項(xiàng)中科院國際合作項(xiàng)目,主持 11 項(xiàng)國家自然科學(xué)基金,簽署 5 項(xiàng)企業(yè)合作項(xiàng)目,獲批中國科

2、學(xué)院儲(chǔ)能領(lǐng)域工程實(shí)驗(yàn)室。在上述項(xiàng)目的資助下,研究部在基礎(chǔ)研究領(lǐng)域取得了重要進(jìn)展,本年度研究部共發(fā)表 SCI 論文 30 余篇,其中包括 Energy Environ.Sci (1).、Nat Commun(1).、 Adv. Mater.(5)、Adv. Funct. Mater.(2)、ACS Energy Lett. (1)、 J. Mater. Chem. A (6)、Nano Energy (1)影響因子大于 10 的論文17 篇。共申請(qǐng)發(fā)明專利 100 余件,授權(quán)專利 60 件。引領(lǐng)液流電池國際標(biāo)準(zhǔn)、國家和行業(yè)標(biāo)準(zhǔn)制定工作。牽頭起草液流電池行業(yè)標(biāo)準(zhǔn) 5 項(xiàng),其中 2 項(xiàng)進(jìn)入征求意見稿

3、, 3 項(xiàng)進(jìn)入草案 3 稿;申報(bào)立項(xiàng)液流電池行業(yè)標(biāo)準(zhǔn)4 項(xiàng)。同時(shí)獲得大連市標(biāo)準(zhǔn)化資助獎(jiǎng)勵(lì)項(xiàng)目1 項(xiàng)。主要研究進(jìn)展如下:1)解決了全釩液流電池關(guān)鍵科學(xué)與技術(shù)問題,在此基礎(chǔ)上開發(fā)出 30kW 級(jí)高功率密度液流電池電堆樣機(jī),并與融科儲(chǔ)能合作實(shí)現(xiàn)技術(shù)轉(zhuǎn)化。其中 100 MW 級(jí)全釩液流電池儲(chǔ)能電站全面開工建設(shè)。2)在分布式儲(chǔ)能領(lǐng)域,解決了鋅基液流電池負(fù)極鋅枝晶、鋅累積等關(guān)鍵科學(xué)問題,大大提高了鋅基液流電池的功率密度和可靠性,開發(fā)出第二代用戶側(cè)鋅溴單液流電池系統(tǒng),正在與陜西華銀科技股份有限合作開展產(chǎn)業(yè)化推廣,目前已完成廠房建設(shè)。在液流電池新體系方面,探索開發(fā)出多個(gè)高能量密度、低成本液流電池新體系(Ene

4、rgy Environ.Sci., 2019, 12, 1834-1839, Adv.),其中鋅鐵液流電池已與金尚新能源。公司開展合作,成功開發(fā)出5kW級(jí)電堆,并得到山東省新舊動(dòng)能轉(zhuǎn)換重大項(xiàng)目支持。3)在其它儲(chǔ)能領(lǐng)域,研究部開展了包括鈉離子電池、鋰基電池以及鉛碳電池等研究工作,其中與中國動(dòng)力集團(tuán)合作開發(fā)的鉛炭電池關(guān)鍵技術(shù)已完成中試,并在所區(qū)完成 100kWh 系統(tǒng)示范。成功開發(fā)出 10Ah 級(jí)能量型鋰 /氟化碳電池,比能量達(dá)到 940Wh/kg,達(dá)到目前同類電池比能量的最高值。在人才團(tuán)隊(duì)建設(shè)方面, 1 人獲國家杰出青年基金資助,入選國家“萬人計(jì)劃”科技創(chuàng)新領(lǐng)軍人才,團(tuán)隊(duì)成員 1 人獲優(yōu)秀青年博

5、士人才,在讀研究生 1 人獲中科院院長特別獎(jiǎng)和中國化學(xué)會(huì)“菁青化學(xué)星火獎(jiǎng)” 。團(tuán)隊(duì)獲 2019 年大連市高??蒲性核诙脛?chuàng)新創(chuàng)業(yè)大賽一等獎(jiǎng)。以上成果為團(tuán)隊(duì)開展產(chǎn)、學(xué)、研合作奠定了堅(jiān)實(shí)基礎(chǔ),與融科公司、風(fēng)帆集團(tuán)、華秦儲(chǔ)能、以化集團(tuán)、華銀科技、金尚新能源等公司建立了長期的合作關(guān)系,有效促進(jìn)了儲(chǔ)能技術(shù)的產(chǎn)業(yè)化發(fā)展。2019 年發(fā)表論文目錄1. Huamin Zhang*, Wenjing Lu, Xianfeng Li, Progress and Perspectives of Flow Battery Technologies. Electrochemical Energy Reviews. 2

6、019, 2, 3, 492-5062. Yanbin Yin, Shengnan Wang, Qi Zhang, Yang Song, Nana Chang, Yanwei Pan, Huamin Zhang, Xianfeng Li*, Dendrite-Free Zinc Deposition Induced by Tin-Modified Multifunctional 3D Host for Stable Zinc-Based Flow Battery. AcceptedAdv. Mater. 20193. Qing Dai, Zhiqiang Liu, Ling Huang, Ch

7、ao Wang, Yuyue Zhao, Qiang Fu, Anmin Zheng*, Huamin Zhang, Xianfeng Li*, Thin-film composite membrane breaking the trade-off between Conductivity and Selectivity for a flow battery. AcceptedNat. Commun. 20194.5. Yuxiao Wang, Ying Yu, Yeqiang Tan*, Tianyu Li, Yanbing Chen, Shuang Wang, Kunyan Sui, Ho

8、ngzhang Zhang,* Yang Luo, Xianfeng Li*, Affinity Laminated Chromatography Membrane Built-in Electrodes for Suppressing PolysulfideShuttling in Lithium-SulfurBatteries. Online Adv. Energy Mater. 2019, DOI:10.1002/aenm.2019032336.Xianfeng Li*, Electrochemically assisted interfacial growth of defect-fr

9、ee MOF membranes. Accepted Matter, 20197. Zhizhang Yuan, Yanbin Yin, Congxin Xie, Huamin Zhang, Yan Yao, Xianfeng Li*, Advanced materials for zinc-based flow battery: development and challenge. Adv. Mater. 2019, 31, 50, 19020258. Chenhui Wang, Wenjing Lu, Qinzhi Lai, Pengcheng Xu, Huamin Zhang, Xian

10、feng Li*, TiN Nanorods Array 3D Hierarchical Composite Electrode for Ultrahigh Power Density Bromine-based Flow Battery. Adv. Mater. 2019, 31, 46, 19046909. Zihan Song, Kai Feng, Hongzhang Zhang*, Peng Guo, Lihua Jiang, Qingsong Wang*, Huamin Zhang, Xianfeng Li*, “ Givingcomes before receiving ”High

11、: performance wide temperature range Li-ion battery with Li5V2(PO4)3 as both cathode material and extra Li donor. Nano Energy. 2019, 66, 10417510. Xianfeng Li*, Redox Targeting Improves Flow Batteries. Joule. 2019, 3, 9, 2066-207511. Hongming Yi, Dan Li, Zhiqiang Lv, Rui Li, Moxiang Ling, Huamin Zha

12、ng, Qiong Zheng,* Xianfeng Li*, Constructing high-performance 3D porous self-standing electrodes with various morphologies and shapes by a flexible phase separation-derived method. J. Mater. Chem. A. 2019, 7, 22550-2255812. Taotao Zhang, Yanling Qiu, Pengfei Yao, Xianfeng Li*, Huamin Zhang*, Bi-Modi

13、fied Zn Catalyst for Efficient CO2 Electrochemical Reduction to Formate. ACS Sustainable Chem. Eng. 2019, 7, 18, 15190-1519613. Nana Chang, Yanbin Yin, Meng Yue, Zhizhang Yuan, Huamin Zhang, Qinzhi Lai*, Xianfeng Li*, A Cost-effective Mixed Matrix Polyethylene PorousMembrane for Long-cycle High Powe

14、r Density Alkaline Zinc based Flow Batteries. Adv. Funct. Mater. 2019, 25, 1901674.14. Lin Qiao, Huamin Zhang, Wenjing Lu, Qing Dai, Xianfeng Li*, Advanced porous membranes with tunable morphology regulated by ionic strength of nonsolvent for flow battery. ACS Appl. Mater. Interfaces. 2019, 11, 2410

15、7-24113.15. Yuqing Chen, Yang Luo, Hongzhang Zhang,* Chao Qu, Huamin Zhang, Xianfeng Li*, The Challenge of Lithium Metal Anodes for Practical Applications. Small Methods. 2019, 1800551.16. Hongming Yi, Le Lin, Moxiang Ling, Zhiqiang Lv, Rui Li, Qiang Fu, Huamin Zhang, Qiong Zheng*, Xianfeng Li*, Sca

16、lable and Economic Synthesis of High Performance Na3V2(PO4)2F3 by a Solvothermal-ball-milling Method. ACS Energy Lett. 2019, 4, 1565-1571.17. Congxin Xie, Yun Liu, Wenjing Lu, Huamin Zhang, Xianfeng Li*, Highly Stable Zinc-Iodine Single Flow Battery with Super High Energy Density for Stationary Ener

17、gy Storage. Energy Environ. Sci. 2019, 12, 1834-1839.18. Huaiqing Wang, Renhe Wang, Zihan Song, Huamin Zhang, hongzhang zhang, Yonggang Wang*, Xianfeng Li*, Novel Aqueous Li+ (or Na+)/Br- Hybrid-ion Battery with Super High Areal Capacity and Energy Density. J. Mater. Chem. A. 2019, 7, 13050-13059.19

18、. Ying Yu, Hongzhang Zhang*, Xiaofei Yang, Jian Gou, Xili Tong, Xianfeng Li,* Huamin Zhang, Vertically Aligned Laminate Porous Electrode: Amaze the Performance with a Maze Structure. Energy Storage Materials. 2019, 19, 88-93.20. Wanqiu Liu, Yun Liu, Huamin Zhang, Congxin Xie, Lei Shi, Yonggui Zhou,

19、Xianfeng Li*, A Highly Stable Neutral Viologen/Bromine Aqueous Flow Battery with High Energy and Power Density. Chem. Commun. 2019, 55, 4801-4804.21.Muhammad Rashad, Hongzhang Zhang, Xianfeng Li*, Huamin Zhang*, Fastkinetics of Mg2+/Li+ hybrid ions in polyanion Li3V2(PO4)3 cathode in widetemperature

20、 range. J. Mater. Chem. A. 2019, 7, 9968-9976.22.Yuqing Chen, Meng Yue, Cuilian Liu, Hongzhang Zhang,* Ying Yu, XianfengLi*, Huamin Zhang, Long Cycle Life Lithium l Batteries enabled with UprightLithium Anode. Adv. Funct. Mater. 2019, 29, 1806752.23. Pengfei Yao, Yanling Qiu, Taotao Zhang, Panpan Su

21、, Xianfeng Li*, Huamin Zhang*, N-doped nanoporous carbon from biomass as a highly efficient electrocatalysts for CO2 reduction reaction. ACS Sustainable Chem. Eng. 2019, 7, 5249- 5255.24. Yanling Qiu, Hexiang Zhong, Wenbin Xu, Taotao Zhang, Xianfeng Li*, Huamin Zhang*, Tuning the Electrocatalytic Pr

22、operties of a Cu Electrode with Organic Additives Containing Amine Group for CO2 Reduction. J. Mater. Chem. A. 2019, 7, 5453-5462.25. Wenjing Lu, Huamin Zhang, Xianfeng Li*, Membranes Fabricated by Solvent treatment for Flow Battery: Effects of initial structures and intrinsic properties. J. Membr.

23、Sci. 577, 2019, 212-218.26. Wanqiu Liu, Wenjing Lu, Huamin Zhang*, Xianfeng Li*, Aqueous Flow Batteries: Research and Development. Chem. Eur. J. 2019, 25, 1649-1664.27. Wenjing Lu, Dingqin Shi, Huamin Zhang, Xianfeng Li*, Highly SelectiveCore-shell Structural Membrane withCage-shaped Pores for FlowB

24、attery.Energy Storage Materials. 2019, 17, 325-333.28. Meng Yue, Zhiqiang Lv, Qiong Zheng*, Xianfeng Li, Huamin Zhang*, Battery assembly optimization: Tailoring the electrode compression ratio d on the polarization analysis in vanadium flow batteries. Applied Energy. 235, 2019, 495-508.29. 李先鋒 ,張洪章

25、,鄭瓊 ,閻景旺 ,郭玉國 ,胡勇勝 , 能源革命中的電化學(xué)儲(chǔ)能技術(shù) .中國科學(xué)院院刊 . 2019, 34, 4, 443-449.30. Zhong-Shuai Wu,* Xianfeng Li*, Feng Wang*, Xinhe Bao*, DICP's 70th Anniversary Special Issue on Advanced Materials for Clean Energy. Adv. Mater. 2019, 31, 50, 1905710.31. Dongju Chen, Hainan Qi, Tingting Sun, Chang Yan, Yingy

26、ing He, Chengzi Kang, Zhizhang Yuan, Xianfeng Li, Polybenzimidazole membrane with dual proton transport channels for vanadium flow battery applications. J. Membr. Sci. 586, 2019, 202-210.32. Qian Zhou, Jun Ma, Shanmu Dong, Xianfeng Li, Guanglei Cui, Intermolecular Chemistry in Solid Polymer Electrol

27、ytes for High-Energy-Density Lithium Batteries. Adv. Mater. 2019, 31, 50, 1902029.33. Xiaofei Yang, Xuejie Gao, Qian Sun, Sara Panahian Jand, Ying Yu, Yang Zhao, Xia Li, Keegan Adair, Liang Yin Kuo, Jochen Rohrer, Jianneng Liang, Xiaoting Lin, Mohammad Norouzi Banis, Yongfeng Hu, Hongzhang Zhang, Xi

28、anfeng Li, Ruying Li, Huamin Zhang, Payam Kaghazchi, Tsun Kong Sham, Xueliang Sun, Promoting the Transformation of Li 2S2 to Li 2S: Significantly Increasing Utilization of Active Materials for High-Sulfur-Loading Li-S Batteries. Adv. Mater. 2019, 31, 25, 1901220.34. Dongju Chen, Chang Yan, Xiaonan L

29、i, Lin Liu, Danni Wu, Xianfeng Li, A highly stable PBI solvent resistant nanofiltration membrane prepared via versatile and simple crosslinking process. Separation and Purification Technology. 2019, 224, 15-22.35. Yi Cheng, Hongqian Sang, Qike Jiang, Haisong Wang,* Huamin Zhang,Xianfeng Li*, Going n

30、ano with confined effects to construct pomegranates-like cathode for high-energy and high-power lithium-ion batteries. ACS Applied Materials & Interfaces. 2019, 11, 32, 28934-28942.36. Kai Feng, Fuxiang Wang, Xin Yang, Hongzhang Zhang, Xianfeng Li, Huamin Zhang, LiCr(MoO 4)2: a new high specific

31、 capacity cathode material for lithium ion batteries. J. Mater. Chem. A. 2019, 7, 2, 567-573.2019 年授權(quán)專利目錄序?qū)@Q授權(quán)號(hào)授權(quán)日發(fā)明人號(hào)1一種醌多鹵化物液流電US15/302,4402019/10/15張華民;賴勤志;李先池鋒;程元徽2一種醌多鹵化物液流電EU15861860.32019/11/13張華民;賴勤志;李先池鋒;程元徽有序介孔碳生長碳納米張華民 ;鄧呈維 ;鐘和3管催化劑的制備及催化CN201510924846.92019/12/3香 ;李先鋒 ;張?zhí)姨覄┖蛻?yīng)用4一種液流電池用梯

32、度電CN201510621446.02019/11/12劉濤 ;張華民 ; 李先鋒極及其應(yīng)用5一種液流電池電極框結(jié)CN201510926102.02019/11/12邢楓 ;張華民 ;李先構(gòu)鋒; 劉濤Li4Ti5O12/ 石墨烯復(fù)合閻景旺 ;程敏 ;張華6材料和制備方法及其負(fù)CN201611056705.02019/9/27民 ;李先鋒 ;張洪章極和應(yīng)用7一種鋰離子超級(jí)電容器CN201611098898.62019/9/27張洪章 ;張華民 ;曲負(fù)極預(yù)嵌鋰的方法超 ;李先鋒 ;劉翠連8一種含添加劑的全釩液CN201510927528.82019/9/24孫佳偉 ;張華民 ;李先流電池正極電解液

33、鋒 ;劉濤 ;史丁秦9一種 NaV2BO5化合物及CN201510586972.82019/9/6馮凱 ;張華民 ;李先其制備和應(yīng)用鋒; 程意一種離子交換膜在鋰硫張洪章 ;張華民 ;晏10CN201510936934.02019/9/6娜 ;李先鋒 ;曲超 ;王二次電池中的應(yīng)用美日一種液流電池用具有分李先鋒 ;張華民 ;袁治11級(jí)孔結(jié)構(gòu)的多孔膜及其CN201510571868.12019/8/27章 ;趙于月制備和應(yīng)用一種金屬元素?fù)诫s碳包閻景旺 ;張華民 ;張洪12覆的鉛粉及其制備和應(yīng)CN201510924114.X2019/8/9章 ;李先鋒 ;劉翠連 ;用黃安然 ;李丹13一種液流電池電堆

34、CN201510924092.72019/8/9劉濤 ;張華民 ; 李先鋒氟化物包覆的劉翠連 ;張華民 ;張洪Li4Ti5O12/ 碳納米管復(fù)14CN201611062259.42019/8/2章 ;李先鋒 ;閻景旺 ;合負(fù)極材料及其制備和曲超應(yīng)用一種柔性自支撐多孔電劉翠連 ;張華民 ;張洪15CN201611062257.52019/8/2章 ;李先鋒 ;閻景旺 ;極及其制備和應(yīng)用曲超一種二氧化碳電化學(xué)還鐘和香 ;張華民 ;邱艷16原用氣體擴(kuò)散電極及其CN201510924113.52019/7/26玲; 鄧呈維 ;李先鋒制備和應(yīng)用17一種全釩液流電池CN201510926333.12019

35、/7/26劉濤 ;張華民 ;李先鋒18一種液流電池電堆結(jié)構(gòu)CN201821954573.82019/7/26邢楓 ;李先鋒 ;張華民鄭瓊 ;李先鋒 ;苑辰19一種液流電池用液流框CN201821954419.02019/7/19光; 張華民; 岳孟; 呂志強(qiáng)20一種制備磷酸釩鋰正極CN201510567876.92019/7/16馮凱 ;程意 ;張華民 ;材料的方法李先鋒21一種有機(jī)體系鋰醌液流CN201510605137.42019/7/16張華民 ;席曉麗 ;賴勤電池志 ;李先鋒22一種適用于液流電池或CN201821972232.32019/7/12鄭瓊 ;李先鋒 ;岳孟 ;電堆的雙極板

36、張華民23一種適用于梯形液流電CN201821972330.72019/7/12鄭瓊 ;李先鋒 ;岳孟 ;池的雙極板張華民24一種適用于矩形液流電CN201821972326.02019/7/12鄭瓊 ;李先鋒 ;岳孟 ;池的雙極板張華民全釩液流電池用多孔碳25纖維紙電極材料及其制CN201510623111.22019/7/5劉濤 ;張華民 ;李先鋒備和應(yīng)用26一種液流電池電堆中防CN201510676675.22019/7/5邢楓 ;張華民 ;李先鋒止雙極板腐蝕的結(jié)構(gòu)一種交聯(lián)聚醚酰亞胺多史丁秦 ;張華民 ;李先27孔隔膜在鋰離子電池中CN201510924057.52019/7/5鋒 ;段

37、寅琦的應(yīng)用28一種用于鋰硫電池的電CN201610833354.32019/7/5王美日 ;張華民 ;張洪解液章 ;李先鋒29一種液流電池結(jié)構(gòu)CN201510676711.52019/7/2邢楓 ;張華民 ;李先鋒30一種液流電池結(jié)構(gòu)CN201821996833.82019/6/28邢楓 ;李先鋒 ;張華民一維取向有序交聯(lián)纖維張華民 ;楊曉飛 ;張洪31狀分級(jí)孔碳材料的制備CN201510926177.92019/6/25章; 李先鋒 ;王美日 ;及應(yīng)用晏娜; 周偉二氧化碳電化學(xué)還原用張華民 ;張?zhí)姨?;鐘和32納米多孔鋅電極及其制CN201610830096.32019/6/18香; 邱艷玲

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