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1、IMDG/IMO危險品/海洋污染物的分類及安全、緊急處置(農(nóng)藥部分)A) 危險品分類1) 3類易燃液體2) 4類易燃固體3) 5類氧化物4) 6類有毒化合物5) 8類腐蝕品6) 9類環(huán)境污染物1)3類易燃品定義:定義:包括液體、混合液體、有固體物質(zhì)包含其中的溶液,懸浮液,但這些不包括那些含有其他危險類別的固體物質(zhì)。其閃點:3.1類:低閃點液體。閉杯閃點35C3.3類:高閃點液體。閉杯閃點23C61C(141F) c.c;初沸點35C包裝:包裝:3.1類:1類包裝(Packing group I),非常危險。如異丙胺3.2類:2類包裝(Packing group II),中等危險。如甲醇(12C
2、)、 丁醇、甲苯(7C)、二甲苯(1723C)3.3類:3類包裝(Packing group III),較小危險。如戊醇、己醇、 環(huán)己酮(3844C)2)4類易燃固體 4.1類: 易燃固體、自反應(yīng)固體 代表物質(zhì):鋁粉、二硝基苯酚(等硝基化合物)、六亞甲基四胺,硫,磷 4.3類: 與水接觸后,非常危險的物質(zhì)。 代表物質(zhì):磷化鋅、磷化鎂、磷化鋁,氰氨化鈣等3)5類氧化物 5.1類: 硝酸銨(化肥)、硝酸鉀(硝酸鹽)、次氯酸鈣(漂白粉)等 5.2類: 有機過氧化物 農(nóng)藥中很少涉及?;て烦隹诓糠稚婕啊?.1類:有毒化合物定義:有毒化合物的定義是以該產(chǎn)品的大鼠經(jīng)口(或經(jīng)皮,吸入。通常用經(jīng)口判斷就可以了
3、)的急性半致死中量(LD50)來判斷。包裝類別經(jīng)口急性LD50 (IMDG) I 5 mg/kg。非常嚴(yán)重的中毒危險性。該類的產(chǎn)品很少。 II 5 50 mg/kg。嚴(yán)重的中毒危險性。 如:Methomyl 90% SP,Carbofuran 48% SC III固體 50 200 mg/kg。低毒液體 50 500 mg/kg。低毒4)6類有毒化合物 即,理論上來說,固體貨物大鼠經(jīng)口即,理論上來說,固體貨物大鼠經(jīng)口LD50 200 mg/kg,液體貨物大鼠經(jīng)口,液體貨物大鼠經(jīng)口 LD50 500 mg/kg,就不歸,就不歸6.1。在沒有其他危險。在沒有其他危險性(如,非腐蝕性、非環(huán)境污染物等
4、)的性(如,非腐蝕性、非環(huán)境污染物等)的情況下,就可歸入普貨。但,在實際情況下,就可歸入普貨。但,在實際危包危包證的出具中,并沒有嚴(yán)格的遵循這個規(guī)則,證的出具中,并沒有嚴(yán)格的遵循這個規(guī)則,很多很多9類的固體類的固體/粉劑產(chǎn)品也給出具了粉劑產(chǎn)品也給出具了6.1類類的危包。但,這個標(biāo)準(zhǔn)可以作為在無需出的危包。但,這個標(biāo)準(zhǔn)可以作為在無需出具危包證的半危出運中作為參考。具危包證的半危出運中作為參考。6.1類產(chǎn)類產(chǎn)品比較多。詳見附件介紹!品比較多。詳見附件介紹! 6.2類: 傳染性物質(zhì) (農(nóng)藥幾無涉及) 對于農(nóng)藥品種來說,歸入該類別的主要產(chǎn)品是乙烯利水劑 (UN3265)。5)8類腐蝕品 UN3077(
5、S), UN3082 (L) 對于農(nóng)藥產(chǎn)品來說,絕大多數(shù)的產(chǎn)品,若沒有歸入其他的類別,均可歸入該類別中。9)9類環(huán)境污染物附:附:6.1類有毒化合物類有毒化合物 UN No / IMDG code概述:概述:如果在運輸過程中需要提供6.1類貨物的IMDG code,大部分的產(chǎn)品,只需要根據(jù)危包證上的UN No,在IMDG手冊上查找,就可以找到對應(yīng)的IMDG code。在收到的危包證上,各個產(chǎn)品的UN No,留意會發(fā)現(xiàn),有時不同的有效成分的號是一樣的,而同樣的有效成分的號反而會不一樣。當(dāng)然,不同的有效成分,UN No也有不一樣的,等等情況。這涉及到產(chǎn)品的不同劑型,毒性,化學(xué)類別。大類產(chǎn)品:1.
6、有機磷農(nóng)藥有機磷農(nóng)藥根據(jù)產(chǎn)品的劑型(液體,還是固體),及閃點(液體)的不同。有機磷農(nóng)藥的歸入如下UN No:2783:ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC可濕性粉劑、可溶性粉機、顆粒劑、固體原藥等可濕性粉劑、可溶性粉機、顆粒劑、固體原藥等2784:ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point less than 23 C液體液體(一般是乳油一般是乳油),閃點低于,閃點低于23C c.c.3017:ORGANOPHOSPHORUS PESTICIDE, LIQUID,
7、 TOXIC, FLAMMABLE, flash point not less than 23 C液體液體(一般是乳油一般是乳油),閃點大于,閃點大于23C c.c.,小于,小于61C c.c.3018:ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC液體液體(一般是乳油一般是乳油, 液體農(nóng)藥液體農(nóng)藥),閃點高于,閃點高于61C c.c.有機磷農(nóng)藥產(chǎn)品列表:根據(jù)產(chǎn)品的劑型(液體,還是固體),及閃點(液體)的不同。氨基甲酸酯農(nóng)藥歸入如下UN No:2757:CARBAMATE PESTICIDE, SOLID, TOXIC可濕性粉劑、可溶性粉機、顆粒劑、固體原藥
8、等可濕性粉劑、可溶性粉機、顆粒劑、固體原藥等2758:CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point less than 23 C液體液體(一般是乳油一般是乳油),閃點低于,閃點低于23C c.c.2991:CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point not less than 23 C液體液體(一般是乳油一般是乳油),閃點大于,閃點大于23C c.c.,小于,小于61C c.c.2992:CARBAMATE PESTICIDE, LIQUID, TO
9、XIC液體液體(一般是乳油,液體農(nóng)藥一般是乳油,液體農(nóng)藥),閃點高于,閃點高于61C c.c.2. 氨基甲酸酯農(nóng)藥氨基甲酸酯農(nóng)藥氨基甲酸酯農(nóng)藥產(chǎn)品列表:根據(jù)產(chǎn)品的劑型(液體,還是固體),及閃點(液體)的不同。擬除蟲菊酯農(nóng)藥歸入如下UN No:3349:PYRETHROID PESTICIDE, SOLID, TOXIC可濕性粉劑、可溶性粉機、顆粒劑、固體原藥等可濕性粉劑、可溶性粉機、顆粒劑、固體原藥等3350:PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point less than 23 C液體液體(一般是乳油一般是乳油),閃點
10、低于,閃點低于23C c.c.3351:PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point not less than 23 C液體液體(一般是乳油一般是乳油),閃點大于,閃點大于23C c.c.,小于,小于61C c.c.3352:PYRETHROID PESTICIDE, LIQUID, TOXIC液體液體(一般是乳油,液體農(nóng)藥一般是乳油,液體農(nóng)藥),閃點高于,閃點高于61C c.c.3. 擬除蟲菊酯擬除蟲菊酯擬除蟲菊酯農(nóng)藥產(chǎn)品列表:根據(jù)產(chǎn)品的劑型(液體,還是固體),及閃點(液體)的不同。香豆素衍生物農(nóng)藥歸入如下UN No
11、:3024:COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flash point less than 23 C3025:COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point not less than 23 C液體液體(一般是母液一般是母液),閃點,閃點不低于不低于23C c.c.3026:COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC液體液體(一般是母液一般是母液),閃點高于,閃點高于61C c.c.
12、3027:COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC餌劑、固體原藥等餌劑、固體原藥等4. 香豆素衍生物香豆素衍生物香豆素衍生物農(nóng)藥產(chǎn)品列表:中文名稱英文名稱1溴鼠靈Brodifacoum2溴敵隆Bromadiolone3殺鼠醚Coumatetralyl4氟鼠靈Flocoumafen5殺鼠靈Warfarin根據(jù)產(chǎn)品的劑型(液體,還是固體),及閃點(液體)的不同。有機氯農(nóng)藥歸入如下UN No:2761:ORGANOCHLORINE PESTICIDE, SOLID, TOXIC 2762:ORGANOCHLORINE PESTICIDE, LIQUID,
13、 FLAMMABLE, TOXIC, flash point less than 23 C2995:ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, Flash point not less than 23 C2996:ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC5. 有機氯農(nóng)藥有機氯農(nóng)藥背景小知識及產(chǎn)品:背景小知識:背景小知識:有機氯農(nóng)藥是農(nóng)藥發(fā)展史上最為重要的一類化合物,其代表產(chǎn)品為六六六,DDT。而DDT因其在健康方面的貢獻(殺除蚊蟲,控制瘧疾),其發(fā)明人與1948年獲得了諾貝爾生理/醫(yī)學(xué)獎。在二戰(zhàn)期
14、間,因DDT的使用,挽救了成千上萬的性命。DDT后來因發(fā)現(xiàn)其不易降解,在生物體內(nèi)的富集,從而對人和環(huán)境生物造成更為嚴(yán)重要的危害而被禁用。若不考慮累計毒性的話,到目前為止,還沒有找到其他能夠與之匹敵的產(chǎn)品:可以在人或人類生活環(huán)境中隨意使用,而不會造成中毒,但卻能夠有效的殺滅蚊蟲,從而取得良好的衛(wèi)生防疫效果。由于殘留嚴(yán)重,目前市場上的有機氯產(chǎn)品剩下已經(jīng)不多了。產(chǎn)品:產(chǎn)品:三氯殺螨醇/dicofol、硫丹/endosulfan、三氯殺螨砜/tetradifon根據(jù)產(chǎn)品的劑型(液體,還是固體),及閃點(液體)的不同。有機錫農(nóng)藥歸入如下UN No:2786:ORGANOTIN PESTICIDE, SO
15、LID, TOXIC 2787:ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC,flash point less than 23 C3019:ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, Flash point not less than 23 C3020:ORGANOTIN PESTICIDE, LIQUID, TOXIC實際產(chǎn)品中,只有UN2786(WP)、UN3020(SC)6. 有機錫農(nóng)藥有機錫農(nóng)藥有機錫農(nóng)藥產(chǎn)品列表:中文名稱英文名稱1三唑錫Azocyclotin2三環(huán)錫Cyhexatin3苯丁
16、錫Fenbutatin Oxide4三苯基氫氧化錫三苯基氫醋酸錫Fentin hydroxideFentin Acetate5三磷錫Phostin根據(jù)產(chǎn)品的劑型(液體,還是固體),及閃點(液體)的不同。未歸類6.1農(nóng)藥如下UN No:2588:PESTICIDE, SOLID, TOXIC, N.O.S.2902:PESTICIDE, LIQUID, TOXIC, N.O.S.2903:PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S.Flash point not less than 23 C 3021:PESTICIDE, LIQUID, FLAMMAB
17、LE, TOXIC, N.O.S., Flash point less than 23 7. 其他未歸類其他未歸類6.1農(nóng)藥農(nóng)藥 復(fù)配產(chǎn)品 煙堿類產(chǎn)品,如吡蟲啉、啶蟲脒等 其他產(chǎn)品,如氟蟲腈、蟲螨腈、多殺菌素、阿維菌素、甲氨基阿維菌素、茚蟲威等未歸類6.1農(nóng)藥產(chǎn)品列表:B) EMS NO. EMS Emergency Schedules 危險品應(yīng)急措施危險品應(yīng)急措施代碼代碼總論EMS(危險品應(yīng)急措施危險品應(yīng)急措施),著重關(guān)注兩個應(yīng)急措施的方面:1)火險情況下的緊急應(yīng)對。即,IMO應(yīng)對措施“F - ?”中的“F”2)泄露情況下的緊急應(yīng)對。即,IMO應(yīng)對措施“S - ?”中的“S”Emergenc
18、y Schedules for FireEMS code for fire as below:F A:GENERAL FIRE SCHEDULEF B:EXPLOSIVE SUBSTANCES AND ARTICLESF C:NON-FLAMMABLE GASESF D:FLAMMABLE GASESF E:NON-WATER REACTIVE FLAMMABLE LIQUIDSF F:TEMPERATURE CONTROLLED SELF-REACTIVES AND ORGANIC PEROXIDESF G:WATER REACTIVE SUBSTANCESF H:OXIDIZING SUB
19、STANCES WITH EXPLOSIVE POTENTIALF I:RADIOACTIVE MATERIALF J:NON-TEMPERATURE CONTROLLED SELF-REACTIVES AND ORGANIC PEROXIDES 從對F A到 F J的適用對象定義,可以看出,農(nóng)藥產(chǎn)品適用的代碼/Code 為“F A”和“F E”。 F A:水劑、懸浮劑、固體、高閃點液體農(nóng)藥:水劑、懸浮劑、固體、高閃點液體農(nóng)藥:如如2588、2902 F E:乳油等含低閃點溶劑易燃農(nóng)藥:乳油等含低閃點溶劑易燃農(nóng)藥:如如2903、3021、1993Emergency Schedules for
20、SpillageS A:TOXIC SUBSTANCESS B: CORROSIVE SUBSTANCESS C: FLAMMABLE, CORROSIVE LIQUIDSS D: FLAMMABLE LIQUIDSS E: FLAMMABLE LIQUIDS, FLOATING ON WATERS F: WATER SOLUBLE MARINE POLLUTANTSS G: FLAMMABLE SOLIDS AND SELF-REACTIVE SUBSTANCESS H:FLAMMABLE SOLIDS (MOLTEN MATERIAL)S I:FLAMMABLE SOLIDS (REPAC
21、KING POSSIBLE)S J:WETTED EXPLOSIVES AND CERTAIN SELF-HEATING SUBSTANCESS K:TEMPERATURE-CONTROLLED SELF-REACTIVE SUBSTANCESS L:SPONTANEOUSLY COMBUSTIBLE, WATER-REACTIVE MATERIAL S M:HAZARD OF SPONTANEOUS IGNITIONEMS code for spillage as below:S N:SUBSTANCES REACTING VIGOROUSLY WITH WATERS O:SUBSTANCE
22、S DANGEROUS WHEN WET (NON-COLLECTABLE ARTICLES)S P:SUBSTANCES DANGEROUS WHEN WET (COLLECTABLE ARTICLES) S Q:OXIDIZING SUBSTANCES S R:ORGANIC PEROXIDES S S:RADIOACTIVE MATERIAL S T:DANGEROUS GOODS WITH BIOHAZARD S U:GASES (FLAMMABLE, TOXIC OR CORROSIVE) S V:GASES (NON-FLAMMABLE, NON-TOXIC) S W:OXIDIZ
23、ING GASES S X:EXPLOSIVE ITEMS AND ARTICLES S Y:EXPLOSIVE CHEMICALS S Z:TOXIC EXPLOSIVES 從對S A到 S Z的適用對象定義,可以看出,農(nóng)藥產(chǎn)品適用的代碼/Code 為:S A, S B, S D, S E, S F S A: 6.1類的水劑、懸浮劑、固體、高閃點液體農(nóng)藥。如UN2588、2902、2783、3018、2757、2992等 S B:乙烯利水劑,UN3265。 S D:易/可燃液體農(nóng)藥:如UN2903、3021、2784、3017、2758、2991等 S E:UN1993 S F:UN3077
24、、3082 EMS code for FireF A、F EF A:GENERAL FIRE SCHEDULEF E:NON-WATER REACTIVE FLAMMABLE LIQUIDSConclusion on EMS code for fire and spillage EMS code for SpillageS A、S B、S D、S E、S FS A:TOXIC SUBSTANCESS B: CORROSIVE SUBSTANCESS D: FLAMMABLE LIQUIDSS E: FLAMMABLE LIQUIDS, FLOATING ON WATERS F: WATER S
25、OLUBLE MARINE POLLUTANTSConclusion on EMS code for fire and spillage其他 危險品貨物描述、順序及其他信息危險品貨物描述、順序及其他信息 UN Number Proper Shipping Name, technical name (if have), IMO Class (sub risk), Packing Group, Flash point (if have), Marine pollutant (if have) Package quantity (please remarks, if have inter packa
26、ge)1、The UN number (聯(lián)合國編碼聯(lián)合國編碼) :例如,聯(lián)合國編碼是:例如,聯(lián)合國編碼是2588,請?zhí)顚憺?,請?zhí)顚憺閁N2588; 2、Proper Shipping Name (危險貨物正確學(xué)名危險貨物正確學(xué)名), 如果該貨物有如果該貨物有Technical name (Imidacloprid 70% WG), 請?zhí)顚懻執(zhí)顚慣echnical name一欄,以下是范例一欄,以下是范例: PESTICIDE, SOLID, TOXIC, N.O.S. (Imidacloprid)Proper shipping name Technical name 3、IMO Class (
27、危險貨物等級危險貨物等級) :例如,危險等級是:例如,危險等級是6.1,請?zhí)顚憺?,請?zhí)顚憺镃lass 6.1.;如果該類危;如果該類危險品有附險品有附 危險等級,請?zhí)钤谥魑kU等級后面,例如:危險等級,請?zhí)钤谥魑kU等級后面,例如:5.1(3) 。 4、Packing group (包裝類別包裝類別) :如果該危險品貨物有包裝類別:如果該危險品貨物有包裝類別, 請?zhí)峁┌b類別并在前加請?zhí)峁┌b類別并在前加PG; 例如,包裝類別是例如,包裝類別是III,請?zhí)顚憺?,請?zhí)顚憺镻G III。Packing group分為三種:分為三種:I, II, III. 如果沒有如果沒有包裝類別,無需提供包裝包裝類別
28、,無需提供包裝 5、Flash Point (閃點閃點): 如果該危險品貨物有閃點,請?zhí)峁╅W點。如果該危險品貨物有閃點,請?zhí)峁╅W點。 6、Marine Pollutant (海洋污染海洋污染): 有有N, P, PP三種類別。三種類別。 N:無污染的物質(zhì):無污染的物質(zhì) P: 有污染性的物質(zhì)有污染性的物質(zhì) PP: 有嚴(yán)重污染性的物質(zhì)有嚴(yán)重污染性的物質(zhì) 其他常見農(nóng)藥產(chǎn)品危險性描述及其常見農(nóng)藥產(chǎn)品危險性描述及其EmsGLYPHOSATEUN Number3077Proper Shipping NameEnvironmentally Hazardous Substance, Solid, N.O.S.
29、IMO Class9Packing GroupIIIEms CodeF-A S-FGlyphosate TC and SG:UN Number3082Proper Shipping NameEnvironmentally Hazardous Substance, Liquid, N.O.S.IMO Class9Packing GroupIIIEms CodeF-A S-FGlyphosate SL2,4-D & ITS ESTERUN Number33453077Proper Shipping NamePhenoxyacetic Acid Derivative Pesticide, S
30、olid, ToxicEnvironmentally Hazardous Substance, Solid, N.O.S.IMO Class6.19Packing GroupIIIIIIEms CodeF-A S-AF-A S-F2,4-D (acid & salt) TC & SP formulationUN Number3082Proper Shipping NameEnvironmentally Hazardous Substance, Liquid, N.O.S.IMO Class9Packing GroupIIIEms CodeF-A S-F2,4-D salt SL
31、, 2,4-D ester TC, 2,4-D ester EC (F.p. 61)UN Number1993Proper Shipping NameFlammable Liquid, N.O.S.IMO Class3Packing GroupI IIIEms CodeF-E S-E2,4-D ester EC (F.p. 61)Dicamba, MCPA, Picloram, Triclopyr產(chǎn)品危險性分類,除沒有UN3345的類別外,其他同2,4-D產(chǎn)品系列!PARAQUAT DICHLORIDE DIQUAT DIBROMIDEUN Number3016Proper Shipping
32、NameBipyridilium Pesticide, Liquid, ToxicIMO Class6.1Packing GroupIIIEms CodeF-A S-ATK and SLFIPRONILUN Number2588Proper Shipping NamePesticide, Solid, Toxic, N.O.S.IMO Class6.1Packing GroupIIIEms CodeF-A S-AUN Number2902Proper Shipping NamePesticide, Liquid, Toxic, N.O.S.IMO Class6.1Packing GroupII
33、IEms CodeF-A S-ATechnical material and WDG formulationSC formulationETHEPHONUN Number3265Proper Shipping Name8IMO ClassIIIPacking GroupCORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.Ems CodeF-A S-BEthephon TC and SLIMIDACLOPRID, ACETAMIPRID, THIAMETHOXAM, NITENPYRAM, THIACLOPRIDUN Number2588Proper Shippin
34、g NamePesticide, Solid, Toxic, N.O.S.IMO Class6.1Packing GroupIIIEms CodeF-A S-ATechnical material and WP, SP, WG, GR, WS formulationUN Number2902Proper Shipping NamePesticide, Liquid, Toxic, N.O.S.IMO Class6.1Packing GroupIIIEms CodeF-A S-ASL, SC formulationCARTAP HYDROCHLORIDEUN Number2771Proper S
35、hipping NameThiocarbamate Pesticide, Solid, ToxicIMO Class6.1Packing GroupIIIEms CodeF-A S-AUN Number3077Proper Shipping NameEnvironmentally Hazardous Substance, Solid, N.O.S.IMO Class9Packing GroupIIIEms CodeF-A S-FUN Number2588Proper Shipping NamePesticide, Solid, Toxic, n.o.s.IMO Class6.1Packing
36、GroupIIIEms CodeF-A S-A由于產(chǎn)品的化學(xué)分類不明確,及急性毒數(shù)據(jù)介于低毒中等毒。這個產(chǎn)品原藥、SP的歸類比較亂。所列的3個UN NO.均可用。4% GR原則上應(yīng)該是UN3077。但,實際操作時,也有可能被歸入6.1的UN NO.中!Cartap Hydrochloride TC and SP formulationCartap Hydrochloride 4% GRUN Number3077Proper Shipping NameEnvironmentally Hazardous Substance, Solid, N.O.S.IMO Class9Packing Group
37、IIIEms CodeF-A S-FABAMECTIN, EMAMECTINUN Number2588Proper Shipping NamePesticide, Solid, Toxic, N.O.S.IMO Class6.1Packing GroupIIIEms CodeF-A S-ATechnical material and WP, SG formulationUN Number2902Proper Shipping NamePesticide, Liquid, Toxic, N.O.S. IMO Class6.1Packing GroupIIIEms CodeF-A S-AEC fo
38、rmulationUN Number29033021Proper Shipping NamePesticide, Liquid, Toxic, Flammable, N.O.S. (F.p.: not less than 23 C)Pesticide, Liquid, Toxic, Flammable, N.O.S. (F.p.: less than 23 C)IMO Class6.1 (3)3 (6.1)Packing GroupIIIIIIEms CodeF-E S-DF-E S-DACETOCHLOR, ALACHLOR, BUTACHLOR, METOLACHLOR, PRETILAC
39、HLORUN Number3082Proper Shipping NameEnvironmentally Hazardous Substance, Liquid, N.O.S.IMO Class9Packing GroupIIIEms CodeF-A S-FTechnical MaterialUN Number3082Proper Shipping NameEnvironmentally Hazardous Substance, Liquid, N.O.S.IMO Class9Packing GroupIIIEms CodeF-A S-FUN Number1993Proper Shipping
40、 NameFlammable Liquid, N.O.S. (F.p. 61)IMO Class3Packing GroupIIIEms CodeF-E S-EEC FormulationATRAZINE, AMETRYNE, CYANAZINE, HEXAZINONE, METRIBUZIN, PROMETRYN, PROPAZINE, SIMAZINE, SIMETRYN, TERBUTHYLAZINE, TERBUTRYNUN Number3077Proper Shipping NameEnvironmentally Hazardous Substance, solid, N.O.S.I
41、MO Class9Packing GroupIIIEms CodeF-A S-FTechnical Material and WP, WG formulationUN Number3082Proper Shipping NameEnvironmentally Hazardous Substance, Liquid, N.O.S.IMO Class9Packing GroupIIIEms CodeF-A S-FSC FormulationCYPROCONAZOLE, DIFENOCONAZOLE, DINICONAZOLE(-M), FENBUCONAZOLE, FLUSILAZOLE, FLU
42、TRIAFOL, HEXACONAZOLE, MYCLOBUTANIL, PACLOBUTRAZOL, PROPICONAZOLE, TEBUCONAZOLE, TRIADIMEFON, TRIADIMENOL, TRICYCLZOLE, TRITICONAZOLE, UNICONAZOLEUN Number3077Proper Shipping NameEnvironmentally Hazardous Substance, solid, N.O.S.IMO Class9Packing GroupIIIEms CodeF-A S-FTechnical Material (Solid) and
43、 WP, WG, WS formulationUN Number3082Proper Shipping NameEnvironmentally Hazardous Substance, Liquid, N.O.S.IMO Class9Packing GroupIIIEms CodeF-A S-FSC, FS FormulationUN Number30821993Proper Shipping NameEnvironmentally Hazardous Substance, Liquid, N.O.S.Flammable Liquid, N.O.S.(F.p. 61)IMO Class93Pa
44、cking GroupIIIIIIEms CodeF-A S-FF-E S-EEC FormulationAZOXYSTROBIN, KRESOXIM-METHYL, TRIFLOXYSTROBIN, PYRACLOSTROBINUN Number3077Proper Shipping NameEnvironmentally Hazardous Substance, solid, N.O.S.IMO Class9Packing GroupIIIEms CodeF-A S-FTechnical Material and WG, WS formulationUN Number3082Proper
45、Shipping NameEnvironmentally Hazardous Substance, Liquid, N.O.S.IMO Class9Packing GroupIIIEms CodeF-A S-FSC, FS FormulationDICLOFOP-METHYL, FENOXAPROP-P-ETHYL, FLUAZIFOP-P-BUTYL, HALOXYFOP-R-METHYL, QUIZALOFOP-P-ETHYL, CYHALOFOP-BUTYL, QUIZALOFOP-P-TEFURYL, CLODINAFOP-PROPARGYLUN Number3077Proper Sh
46、ipping NameEnvironmentally Hazardous Substance, solid, N.O.S.IMO Class9Packing GroupIIIEms CodeF-A S-FTechnical MaterialUN Number30821993Proper Shipping NameEnvironmentally Hazardous Substance, Liquid, N.O.S.Flammable Liquid, N.O.S.(F.p. 61LIQUID FORMULATION*EC FORMULATIONUN Number30172784Proper Shi
47、pping NameOrganophosphorus Pesticide, Liquid, Toxic, Flammable, (F.p. Not less than 23 C)Organophosphorus Pesticide, Liquid, Flammable, Toxic, (F.p.: Less than 23 C)IMO Class6.1 (3)3 (6.1)Packing GroupIIIIIIEms CodeF-E S-DF-E S-DUN Number2783Proper Shipping NameOrganophosphorus Pesticide, Solid, Tox
48、icIMO Class6.1Packing GroupIIIEms CodeF-A S-AWP, SP, GR FORMULATIONLIQUID: Benfuracarb, Fenobucarb, CarbosulfanSOLID: Carbaryl, Carbofuran, Isoprocarb, Methomyl, Propoxur, ThiodicarbCARBAMATE PESTICIDE 氨基甲酸酯農(nóng)藥氨基甲酸酯農(nóng)藥UN Number29922757Proper Shipping NameCarbamate Pesticide, Liquid, Toxic Carbamate Pe
49、sticide, Solid, ToxicIMO Class6.16.1Packing GroupIIIIII*Ems CodeF-A S-AF-A S-ATECHNICAL MATERIAL *) Carbofuran & Methomyl: Packing group IIUN Number2992Proper Shipping NameCarbamate Pesticide, Liquid, Toxic IMO Class6.1Packing GroupIIIEms CodeF-A S-ALIQUID FORMULATION*) Including EC, SC, EW form
50、ulation (if any) F.p. 61 UN Number27582991Proper Shipping NameCarbamate Pesticide, Liquid, Flammable, Toxic (F.p.: Less than 23 C)Carbamate Pesticide, Liquid, Flammable, Toxic (F.p.: Not less than 23 C)IMO Class3 (6.1)6.1(3)Packing GroupIIIIIIEms CodeF-E S-DF-E S-DEC FORMULATIONUN Number2757Proper S
51、hipping NameCarbamate Pesticide, Solid, ToxicIMO Class6.1Packing GroupIII*Ems CodeF-A S-A*) Methomyl SP/WP: Packing group IIWP, WDG/DF, SP, GR FORMULATIONLIQUID: Bioallethrin, Cypermethrin, Cyfluthrin, D-allethrin, D-phenothrin, Esbiothrin, Fenpropathrin, Fenvalerate, Esfenvalerate, PermethrinSOLID:
52、 Alpha-cypermethrin, Beta-cyfluthrin, Beta-cypermethrin, Bifenthrin, Deltamethrin, Etofenprox, Lambda-cyhalothrin, Tetremethrin, PYRETHROID PESTICIDE擬除蟲菊酯農(nóng)藥擬除蟲菊酯農(nóng)藥UN Number33523349Proper Shipping NamePyrethroid Pesticide, Liquid, ToxicPyrethroid Pesticide, Solid, ToxicIMO Class6.16.1Packing GroupIII
53、IIIEms CodeF-A S-AF-A S-ATECHNICAL MATERIALUN Number3352Proper Shipping NamePyrethroid Pesticide, Liquid, ToxicIMO Class6.1Packing GroupIIIEms CodeF-A S-A*) Including EC, SC, EW formulation (if any). F.p. 61 LIQUID FORMULATION*UN Number33503351Proper Shipping NamePyrethroid Pesticide, Liquid, Flamma
54、ble, Toxic,(F.p.: Less than 23 C)Pyrethroid Pesticide, Liquid, Flammable, Toxic,(F.p.: Not less than 23 C)IMO Class3 (6.1)6.1 (3)Packing GroupIIIIIIEms CodeF-E S-DF-E S-DEC FORMULATIONUN Number3349Proper Shipping NamePyrethroid Pesticide, Solid, ToxicIMO Class6.1Packing GroupIIIEms CodeF-A S-AWP, WD
55、G/DF, GR FORMULATIONCoumatetralyl/殺鼠醚、Brodifacoum/溴鼠靈、Bromadiolone/溴敵隆、Warfarin/殺鼠靈殺鼠劑 / Rodenticide (香豆素類)UN Number3027Proper Shipping NameCoumarin Derivative Pesticide, Solid, ToxicIMO Class6.1Packing GroupIIEms CodeF-A S-ATECHNICAL MATERIAL:UN Number30273025Proper Shipping NameCoumarin Derivative
56、 Pesticide, Solid, ToxicCoumarin Derivative Pesticide, Solid, ToxicIMO Class6.16.1Packing GroupIIIIIIEms CodeF-A S-AF-A S-ATECHNICAL CONCENTRATEUN Number3027Proper Shipping NameCoumarin Derivative Pesticide, Solid, ToxicIMO Class6.1Packing GroupIIIEms CodeF-A S-ABLOCK BAIT*) 因餌劑的含量很低(主流含量0.005%),該產(chǎn)品的急性毒性很低,可歸入普貨。題外:Warfarin是一種治療心臟病的藥物,用于預(yù)防血管栓塞 Dicofol / 三氯殺螨醇、Endosulfan / 硫丹、Tetradifon /三氯殺螨砜ORGANOCHLORINE PESTICIDE / 有機氯農(nóng)藥UN Number2996Proper Shipping NameOrganochlorine Pesticide, Liquid, ToxicIMO Class6.1Pac
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