TPR物質(zhì)安全資料表

一：物品與廠商資料Productandcompanyinformation物品名稱:TPR噴漆ItemName：TPRrpaint物品編號(hào):TPR-**ItemNumber：TPR-**供給商名稱:東莞市臺(tái)寶涂料SupplierName：DongguanTaibaopaintCo.,Ltd.供給商地址:東莞市厚街鎮(zhèn)橋頭工業(yè)區(qū)SupplierAddress:Qiaotouindustialpark,Houjietown,Dongguancity緊急聯(lián)絡(luò)/號(hào)碼0769-85912902EmergencyContactPhone/Fax0769-85912902二：成份資料表Thesheetofcompositions成份類別Categories成份名稱CompositionnameCASNO比例Comparison樹(shù)脂Resin丁苯橡膠Butadienestyrenerubber9003-55-858%聚苯乙烯顏料Pigment無(wú)機(jī)顏料Inorganic7664-39-310%有機(jī)顏料pigment84632-65-5體質(zhì)顏料Extender64-17-5溶劑Solvent二甲苯XYL29%異丙醇IPA67-63-0助劑Additive分散劑Dispersant

26677-99-63%流平劑Flowagent100-64-1合計(jì)Sum100%三：危害辯識(shí)資料Informationforidentifinghazards健康危害效應(yīng):低毒性Healtheffect:Lowtoxicity環(huán)境影響：污染水源Environmentalimpact:Pollutingwatersources物理及化學(xué)危害：屬低毒物質(zhì)之合成物，易燃物質(zhì)Physicalandchemicalhazards:Theyarelowtoxicandflammablecompounds.特殊危害：皮膚長(zhǎng)期接觸后會(huì)損害皮膚或過(guò)敏，吸入會(huì)刺激中樞神經(jīng)，產(chǎn)生類似流感的病癥Specialhazards:Theskinwillbedamagedorirritatedafterlong-termcontact,nervuscentrailsstimulatedifinhaled,symptonslikeflu.主要病癥：疲倦、食欲不振，會(huì)刺激皮膚和呼吸道Mainsymptoms:Fatigue,lossofappetite,stimulatingtheskinandrespiratorytract物品危害分類：3.2Itemhazardclassification:3.2四：急救措施First-aidmeasures過(guò)量吸入：立即將患者移至空氣新鮮處，必要時(shí)給予人工呼吸或氧氣，并立即就醫(yī)Excessiveinhalation:Movepatientstofreshairimmediately,ifnecessary,giveartificialrespirationoroxygen,andseekmedicalcareimmediately眼睛接觸：立即將眼皮撐開(kāi)，以緩和流動(dòng)的水及非刺激性肥皂沖洗患部20分鐘以上，如疼痛不止，應(yīng)立即就醫(yī)Eyecontact:Distracttheeyelidimmediately,washtheaffectedpartfor20minutesormorewithmoderateflowingwaterandnon-irritatingsoap,seekmedicaltreatmentiffeelingpainfulforever.皮膚接觸：緩和流動(dòng)的水及非刺激性肥皂沖洗患部20分鐘以上，必要時(shí)應(yīng)立即就醫(yī)，如沾到工作服上應(yīng)立即換掉并清洗干凈方可使用Skincontact:Washtheaffectedpartsfor20minutesormorewitheasingflowingwaterandnon-irritatingsoap,ifnecessary,seekmedicialcareimmediately,replaceandwashthestainedclothesbeforeuse.食之：給患者喝下240-300毫升的水，以稀釋胃中物質(zhì)，不可催吐，立即就醫(yī)假設(shè)嘔吐，讓患者身體前傾，以防止吸入嘔吐物，并反覆漱口Swallow:Drinkpatients240-300mlofwatertodilutestomachsubstances,don’tinducevomiting,seekmedicalcareimmediatelyifthepatientsvomit,makepatientsleanforwardtoavoidinhalationofvomit,andgarglerepeatedly.五：滅火措施Fire-fightingmeasures適用滅火器：干粉(ABC)、二氧化碳、泡沫Suitableextingmedia:Drypowderextinguishers(ABC);carbondioxideextinguishers,foamextinguishers.滅火時(shí)最大危害：蒸氣比空氣重，可流向火源而發(fā)生回火，并有爆炸危害Themaximumfirehazards:Vaporisheavierthanair.Itmayflowtothefiresourceandcauseexplosion.特殊滅火方式：不宜用水滅火，如有溢物未著火，可以用水霧吸熱來(lái)冷卻容器，并保護(hù)止人員Specialfire-fightingmode:Don’twaterfire.Ifthereareexcessivematerialsnotonfire,youcanusewastermisttoadsorbheat,coolcontainersandprotectpersons.消防人員防護(hù)：戴防毒面具和手套，穿保護(hù)服裝Fireprotection:Weargasmasks,glovesandprotectiveclothing.六：泄露處理方法Thetreatmentmethodofdisclosure個(gè)人考前須知:確定清理工作是由受過(guò)訓(xùn)練的人員負(fù)責(zé)；穿戴適當(dāng)?shù)膫€(gè)人防護(hù)用品Personalprotection:tobesurethattheclean-upworkisundertakenbytrainedofficers;wearingappropriatepersonalprotectivedevices環(huán)境考前須知:移開(kāi)所有的引火源；對(duì)漏區(qū)通風(fēng)換氣；通知政府與職業(yè)平安衛(wèi)生及環(huán)保相關(guān)單位Environmentalprotection:Removeallofthefiresources;ventilatethedrainingregions;informthegovernment,occupationalHealthandSafetyandreleatedenvironmentalprotectiondepartment.清理方式:不要碰觸外泄物；防止外泄物進(jìn)入下水道或狹隘的空間內(nèi)；在平安許可的情形下，設(shè)法阻止，一般用砂土掩蓋或減少溢漏；大量泄漏時(shí)，聯(lián)絡(luò)消防、緊急處理單位和供給商以求協(xié)助Methodsforcleaningup:Don’ttouchtheleakedmaterials;preventtheleakedmaterialsfromthesewerornarrowspace;trytostopinthecaseofsecuritylicense;contactthefire,emergencyhandledunitsandsupplierstogethelp.七：平安處理與儲(chǔ)存Safehandlingandstorage處理：此物質(zhì)是易燃性和毒性液體；工作場(chǎng)所保持通風(fēng)并隔離火源、熱源；工作區(qū)應(yīng)有“禁止煙火〞標(biāo)識(shí)Handling:Theliquidmaterialsisflammableandtoxic;maintainventilationintheworkplace,andisolatethefireandheatsources.Thereshouldbea“non-pyrotechnic〞logointheworkplace.儲(chǔ)存：容器保持密封并存放于陰涼、枯燥、通風(fēng)以及陽(yáng)光無(wú)法直射的地方；防止熱源，火源；貯存區(qū)與工作區(qū)應(yīng)分開(kāi)并有適當(dāng)?shù)臏缁鹌骱颓謇硪缏┑脑O(shè)備；限量貯存Storage:Containersremainsealedandstoredinacool,dry,ventilatedplacewherenodirectsunlight;avoidheatandfiresources;storageareasandworkareasonthesub-switcheshavingappropriatefireextinguishersandspillclean-upequipments;limitedstorage八：接觸控制/個(gè)人防護(hù)Contactcontrol/Personalprotection呼吸防護(hù)：防護(hù)口罩Respirationprotection:Protectivemasks手部防護(hù)：防滲手套,材質(zhì)以聚乙烯醇,Viton,4H,Barricade,CPF3為佳Handsprotection:wearingimprerviousglovesbettermadewithpolyvinylalcoholViton,4H,Barricade,CPF3眼睛防護(hù)：化學(xué)防濺護(hù)目鏡或全面型面罩Eyesprotection:Chemicalsplash-proofgogglesorcomprehensive-typemasks皮膚及身體防護(hù)：材質(zhì)以聚乙烯醇,Viton,4H,Barricade,CPF3的防護(hù)連身工作服Skinandbodyprotection:wearingprotectivecoverallsmadewithpolyvinylalcohol,Viton,4H,BarricadeorCPF3衛(wèi)生措施：一般防護(hù)措施，衣服被污染后及時(shí)更換，操作后務(wù)必以水清洗臉部及手部HygieneProcedures:Generalprotectivemeasures,washthecontaminatedclothingpromptly,besuretowashfaceandhandsafteroperation九：物理及化學(xué)性質(zhì)Physicalandchemicalproperties密度：0.95±0.028g/cmThickness:0.95±0.028g蒸氣壓：7-9mmHg/20Vapor:7-9mmHg/20顏色：各類顏色Colour:Allkindsofcolors沸點(diǎn)范圍：9Bolingrange:95PH值：——PHvalue:——爆炸界限：1.1%-9.4%Exploisivelimits:1.1%-9.4%分解溫度：——Decompositiontemperature:——蒸氣壓密度：3.38Vaporpressdensity:3.38自燃溫度：420Autoignitiontemperature:42溶解度：不溶于水Solubility:Notdissolvedinwater氣味：少許刺激性O(shè)rdor:Alittleirritant十：安定性及反響性Stabilityandreactivity安定性：正常情況下較穩(wěn)定Stability:Relativelystableundernormalconditions特殊情況下可能之危害反響：發(fā)生爆炸Pssiblehazardresponseunderspecialcircumstances:Explosion應(yīng)防止之狀況：1、火花、明火，高溫和其它著火條件2、強(qiáng)氧化劑：可能引起爆炸Situationshouldbeavoided:1.Spark,openfires,heatandotherfireconditions2.Strongoxidizers:possibleexplosion應(yīng)防止之物質(zhì)1、氧化物2、硝酸和二氫乙內(nèi)醯脲3、溶劑會(huì)侵蝕某些塑料、橡膠Materialsshouldbeavoided:1.Oxides2.Solventserodingsomeplasticsandrubber危害分解物：二氧化碳Hazardousdicompositions:CO2十一：毒性資料Toxicologicalinformation急毒性：揮發(fā)氣體會(huì)刺激眼睛,粘膜和皮膚;高濃度會(huì)引起麻醉吸入:1、短暫的暴露于200ppm濃度，會(huì)刺激鼻和咽喉2、暴露于高濃度〔大約10000ppm〕，會(huì)引起動(dòng)作不協(xié)調(diào)、失去意識(shí)、呼吸衰竭甚至死亡皮膚：液體會(huì)刺激皮膚引起紅斑、枯燥脫脂，長(zhǎng)期接觸會(huì)引起皮膚炎眼睛：其液體揮發(fā)氣體會(huì)刺激眼睛食入：1、因食入而吸收，產(chǎn)生抑制中樞神經(jīng)，病癥如吸入所述2、假設(shè)吸入,食入或嘔吐時(shí)將物質(zhì)吸入肺部，可能導(dǎo)致肺部刺激，肺部組織受損或死亡死亡:人類或動(dòng)物誤食或吸入量超過(guò)一定量會(huì)導(dǎo)致死亡LDld：50mg/kg〔白鼠，吞食〕LDld：10000ppm/6H〔白鼠，吸入〕Acutetoxicity:Volatilegaswillstimulatetheeyes,mucousmembranesandskin,highconcentrationgasmaycausenarcosis.Inspiroation:1.Exposuredto200ppmconcentrationinashortperiod,noseandthroatwillbestimulated2.Exposedtohighconcentration(about10000ppm),maycauseincoordination,lossofconsciousness,respirtatoryfailureandevendeath.Skin:Liquidwillstimulatetheskin,causingerythema.Theskinwillbedryandskimmed.Long-termexposuremaycausedermafitis.Eyes:Thevolatilegasofliquidwillirriatetheeyes.Ingestion:1.Adsorptionduetoingestionwouldpressnervuscentralis,symptomsasdescribedininspiroation.2.Materialsinhaledintothelungmaycauselungstimulation,lungtissuedamageandevendeathatthetimeofinhalation,ingestionorvomiting.Death:MankindortheanimalmistakefoodorinhalethequantityexceedcertainthequantitywillcausetodieLDM：50mg/kg〔Whiterat，devour〕LDM：10000ppm/6H〔Whiterat,inspiroation〕局部反響：500mg/24H〔兔子，皮膚〕造成中度刺激87mg〔兔子，眼睛〕造成輕微刺激Localresponse:500mg/24H(rabbit,skin)causemoderatestimulation87mg(rabbit,eyes)causeminorstimulation致敏感性：——Sensitization:慢毒性或長(zhǎng)期毒性：1、長(zhǎng)期暴露可能起皮膚炎2、肝臟或腎臟損害Chronictoxicityorlong-termtoxicity:1.Long-termexposuremayhavecauseddermatitis.2.causeliverorkidneydamage十二：生態(tài)資料：Ecologicalinformation環(huán)境影響：1、可能不會(huì)蓄積，要體內(nèi)會(huì)被分解排出2、釋放至土壤中，預(yù)期會(huì)滲入地下水或進(jìn)行生物分解，也可能揮發(fā)掉3、釋放在水中，預(yù)期會(huì)進(jìn)行生物分解Enviromentalimpacts:1.willbebrokendownanddischarged,maynotbeaccumulatedinthebody.2.releasedintothesoil,beexpectedtoinfiltrateintogroundwaterorbologicaldecomposition,maybevolatilizedoff.3.releasedintowater,expectingtobebiodegradable十三：廢棄須知Abandonedknow廢棄處理方法：1、參考相關(guān)法規(guī)要求2、可采用特定的焚化或沙土掩埋法處理3、不可同民用垃圾一同處理，務(wù)必作環(huán)保處理，有必要時(shí)請(qǐng)洽供給商協(xié)助處理Disposalconsideration1.referencetotherelevantregulatoryrequirments2.useaparticulartreatmentbyincinerationorsanitarylandfill3.can’tbehandledwiththeciviliangarbagetogether,besuretomakeenvironmentaltreatment,ifnecessary,contactthesuppliersplease十四：運(yùn)送資料Transportinformation國(guó)際運(yùn)送規(guī)定：1、DOT49CFR將之列為第三類易燃液體、包裝等級(jí)Ⅱ〔美國(guó)交通部〕2、IATA/ICAO分級(jí)：3〔國(guó)際航運(yùn)組織〕3、IMDG分級(jí)：無(wú)分類規(guī)定〔國(guó)際海運(yùn)組織〕Internationaltransportregulations:1.It’slistedasthethirdflammableliquids,packagiggradeⅡbytheDOT49〔U.S.DepartmentOfTransportation〕2.IATA/ICAOclassification:3(Internationalnavigatiiontransportationorganization)3.IMDGc