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1、HT8-PCBPOPs分析応用分析応用 松村千里、江崎達(dá)哉* 、鶴川正寛、中野武兵庫(kù)県立健康環(huán)境科學(xué)研究*SGE Japan株式會(huì)社 The Application to POPs Analysis with HT8-PCBChisato Matsumura, Tatsuya Ezaki*, Masahiro Tsurukawa, Takeshi Nakano ( Hyogo Prefectural Institute of Public Health and Environmental Sciences, * SGE Japan Inc.) 殘留性有機(jī)汚染物質(zhì)（POPs）條約対象物質(zhì)：対象物

2、質(zhì)：1212種類(lèi)種類(lèi)POPsPOPs (Persistent Organic (Persistent Organic Pollutants)Pollutants)、DDTDDT、PCBPCB、類(lèi)、類(lèi)、類(lèi)、類(lèi)20002000年末會(huì)議年末會(huì)議條約合意條約合意20012001年月會(huì)議條約締結(jié)年月會(huì)議條約締結(jié)長(zhǎng)距移動(dòng)性難分解性高蓄積性毒性殘留性有機(jī)汚染物質(zhì)（POPs）條約具體的規(guī)制方法1. 1.意図的生産対製造使用禁止意図的生産対製造使用禁止2. 2.使用継続必要時(shí)、物質(zhì)使使用継続必要時(shí)、物質(zhì)使用目的、使用期間特定上使用認(rèn)用目的、使用期間特定上使用認(rèn)3. 3.非意図的副生成物質(zhì)対、非意図的副生成物質(zhì)対

3、、 作成作成4. 4.國(guó)別年間排出量削減技術(shù)的利用國(guó)別年間排出量削減技術(shù)的利用最善技術(shù)排出基準(zhǔn)設(shè)定最善技術(shù)排出基準(zhǔn)設(shè)定5. 5.20252025年使用廃絶、年使用廃絶、20282028年適年適正処理行努力正処理行努力同一一斉分析検討 農(nóng)薬類(lèi)、変時(shí)間。 、7,8塩化物、同時(shí)分析試。表Hp/OCDD、Hp/OCDFCo-PCBs同時(shí)分析條件 Injector Injector : 280, Splitless Carrier GasHe 1.0ml/min, 27cm/sec,Constant flow mode（真空補(bǔ)正ON） Column Oven 130(1min)20/min2002/mi

4、n2404/min320(5min)表2 POPs類(lèi)分析條件（除） Injector Injector : 260, Splitless Carrier GasHe 1.0ml/min, 27cm/sec,Constant flow mode（真空補(bǔ)正ON） Column Oven 120(0min)20/min1802/min2105/min300(5min)1415161718192021222324Retention Time (min)02509010IntensityT4CB / 291.9195T4CB#77#81#79#68#56/#60#55#66#76#70#61/#74#6

5、7#63/#58#40/#57#64#72/#71#41#44#59#42#52/#69#43/#49#78#65/#75/#48/#47#73#62#8023.023.524.024.525.025.526.026.527.027.528.028.529.029.5 30.0Retention Time (min)01798016IntensityP5CB / 325.8805P5CB#82#124#109/#107#123#106#118#114#122#105#126#127H6CB29303132333435363738Retention Time (min)0478793Intens

6、ityH6CB / 361.8386#167#156#157#169313233343536373839Retention Time (min)0387474IntensityH7CB / 393.8025H7CB#189#170#190#172#192#193#191#18045.646.046.446.847.247.648.048.448.849.249.650.050.450.8Retention Time (min)01472777IntensityO8CDF / 443.739940.841.241.642.042.442.843.243.644.044.444.845.245.6

7、 46.0Retention Time (min)06177261IntensityH7CDF / 407.7818OCDF123467891234678HpCDF12347891234679123468945.646.046.446.847.247.648.048.448.849.249.650.050.450.8Retention Time (min)01511794IntensityO8CDD / 459.734840.841.241.642.042.442.843.243.644.044.444.845.245.6 46.0Retention Time (min)02778530Int

8、ensityH7CDD / 423.776612346789OCDDHpCDD123467912346781415161718192021222324Retention Time (min)02509010IntensityT4CB / 291.9195T4CB#77#81#79#68#56/#60#55#66#76#70#61/#74#67#63/#58#40/#57#64#72/#71#41#44#59#42#52/#69#43/#49#78#65/#75/#48/#47#73#62#8023.023.524.024.525.025.526.026.527.027.528.028.529.

9、029.5 30.0Retention Time (min)01798016IntensityP5CB / 325.8805P5CB#82#124#109/#107#123#106#118#114#122#105#126#127H6CB29303132333435363738Retention Time (min)0478793IntensityH6CB / 361.8386#167#156#157#169313233343536373839Retention Time (min)0387474IntensityH7CB / 393.8025H7CB#189#170#190#172#192#1

10、93#191#18045.646.046.446.847.247.648.048.448.849.249.650.050.450.8Retention Time (min)01472777IntensityO8CDF / 443.739940.841.241.642.042.442.843.243.644.044.444.845.245.6 46.0Retention Time (min)06177261IntensityH7CDF / 407.7818OCDF123467891234678HpCDF12347891234679123468945.646.046.446.847.247.648

11、.048.448.849.249.650.050.450.8Retention Time (min)01511794IntensityO8CDD / 459.734840.841.241.642.042.442.843.243.644.044.444.845.245.6 46.0Retention Time (min)02778530IntensityH7CDD / 423.776612346789OCDDHpCDD123467912346787 8塩化塩化同時(shí)分析時(shí)同時(shí)分析時(shí) Compound View Page 1 DqData : f:0308POPsLow0308POPsLow-001

12、 Injection : POPs all mix 100ppb10121416182022242628303234Retention Time (min)01413806IntensityHCH / Average10121416182022242628303234Retention Time (min)02094465IntensityHeptachlor / Average10121416182022242628303234Retention Time (min)01466941Intensityaldrin_dieldrin_endrin / Average Compound View

13、 Page 1 DqData : f:0308POPsLow0308POPsLow-001 Injection : POPs all mix 100ppb10121416182022242628303234Retention Time (min)0221130Intensityendrin / Average10121416182022242628303234Retention Time (min)04982791IntensityDDE / Average10121416182022242628303234Retention Time (min)06211533IntensityDDT /

14、Average-HCH-HCH-HCH-HCH-HCH-HCH-HCH-HCHHeptachlorHeptachlorAldrineAldrineDieldrineDieldrineEndrineEndrineEndrineEndrineDieldrineDieldrine2,4-DDE2,4-DDE4,4-DDE4,4-DDE2,4-DDD2,4-DDD4,4-DDD4,4-DDD2,4-DDT2,4-DDT4,4-DDT4,4-DDT Compound View Page 1 DqData : f:0308POPsHigh-20308POPsHigh-20309HT8-POPsHi-2 I

15、njection : POPs all mix 100ppb10121416182022242628303234Retention Time (min)011170766IntensityHCB / Average10121416182022242628303234Retention Time (min)0392549IntensityOxy-CHL / Average10121416182022242628303234Retention Time (min)08010167Intensityheptachlor-epoxide / Average10121416182022242628303

16、234Retention Time (min)04883096Intensitychlordane / Average Compound View Page 1 DqData : f:0308POPsHigh-20308POPsHigh-20309HT8-POPsHi-2 Injection : POPs all mix 100ppb10121416182022242628303234Retention Time (min)04921122Intensitynonachlor / Average10121416182022242628303234Retention Time (min)0361

17、958IntensityENDRIN / Average10121416182022242628303234Retention Time (min)0151222IntensityENDRIN-2 / Average10121416182022242628303234Retention Time (min)08189238IntensityMirex / AverageHCBHCBOxychlordaneOxychlordanetrans-Chlordanetrans-Chlordaneciscis-Chlordane-ChlordaneHeptachlor-Heptachlor-epoxideepoxide（exoexo：isomerBisomerB）trans-Heptachlor-tra

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