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15萬(wàn)噸/年丙烯腈項(xiàng)目——初步設(shè)計(jì)說(shuō)明書附錄-1-目錄第一章物料衡算一覽表 -3-1.1丙烷脫氫工段 -3-1.1.1丙烷脫氫反應(yīng)器(R101A) -3-1.1.2丙烷脫氫反應(yīng)器(R101B) -6-1.1.3丙烷脫氫反應(yīng)器(R101C) -9-1.1.4極冷換熱器(E103) -12-1.1.5閃蒸罐(V101) -15-1.2丙烯精制工段 -18-1.2.1脫乙烷塔(T201) -18-1.2.2脫丁烷塔(T202) -21-1.2.3丙烯塔(T203) -24-1.3丙烯氨氧工段 -27-1.3.1氨氧反應(yīng)器(R301) -27-1.3.2中和反應(yīng)器(R301) -30-1.3.3酸洗塔(T301) -33-1.4丙烯腈精制工段 -36-1.4.1水洗塔(T401) -36-1.4.2萃取精餾塔(T402) -39-1.4.3共沸精餾塔(T403) -43-1.4.4三相分離罐(V401) -47-1.4.5三相分離罐(V402) -50-1.4.6丙烯腈精制塔(T404) -53-1.4.7乙腈初分塔(T405) -56-1.4.8乙腈精制塔(T406) -59-第二章能量衡算 -62-2.1丙烷脫氫工段 -62-2.1.1丙烷脫氫反應(yīng)器(R101A) -62-2.1.2丙烷脫氫反應(yīng)器(R101B) -62-2.1.3丙烷脫氫反應(yīng)器(R101C) -62-2.1.4急冷換熱器(E103) -63-2.1.5閃蒸罐(V101) -63-2.2丙烯精制工段 -64-2.2.1脫乙烷塔(T201) -64-2.2.2脫丁烷塔(T202) -64-2.2.3丙烯塔(T203) -64-2.3丙烯氨氧工段 -65-2.3.1空氣壓縮機(jī)(C301) -65-2.3.2丙烯預(yù)熱器(E304) -65-2.3.3氨氧反應(yīng)器(R301) -66-2.4丙烯精制工段 -67-2.4.1萃取精餾塔(T402) -67-2.4.2共沸精餾塔(T403) -67-2.4.3三相閃蒸罐(V401) -69-2.4.4三相閃蒸罐(V402) -69-2.4.5丙烯腈精制塔(T404) -69-2.4.6乙腈初分塔(T405) -70-2.4.7乙腈精制塔(T406) -70-第三章MSDS數(shù)據(jù)一覽表 -71-3.1丙烷 -71-3.2氫氣 -75-3.3甲烷 -79-3.4丙烯 -83-3.5氨 -87-3.6丙烯腈 -91-3.7乙腈 -97-3.8氫氰酸 -102-3.9一氧化碳 -106-3.10二氧化碳 -110-

第一章物料衡算一覽表1.1丙烷脫氫工段1.1.1丙烷脫氫反應(yīng)器(R101A)進(jìn)料流股出料流股溫度C525.00316.23壓力bar5.004.60氣相分率1.001.00摩爾流量kmol/hr968.211185.58質(zhì)量流量kg/hr42118.4142118.41體積流量cum/hr12850.2212629.72焓Gcal/hr-5.65-5.65組分流量kg/hrC3H834204.7424599.65C2H6473.60474.97C3H67436.1916216.57H2O0.000.00H20.00420.13C3H40.000.00C2H40.00244.47C4H80.000.00N-C4H100.587.03I-C4H103.308.59CH40.00147.01N20.000.00O20.000.00NH30.000.00C3H3N0.000.00C2H3N0.000.00HCN0.000.00CO0.000.00CO20.000.00C3H4O0.000.00C4H5NO0.000.00H2SO40.000.00(NH4)2SO40.000.00質(zhì)量分率C3H80.810.58C2H60.010.01C3H60.180.39H2O0.000.00H20.000.01C3H40.000.00C2H40.000.01C4H80.000.00N-C4H100.000.00I-C4H100.000.00CH40.000.00N20.000.00O20.000.00NH30.000.00C3H3N0.000.00C2H3N0.000.00HCN0.000.00CO0.000.00CO20.000.00C3H4O0.000.00C4H5NO0.000.00H2SO40.000.00(NH4)2SO40.000.00

1.1.2丙烷脫氫反應(yīng)器(R101B)進(jìn)料流股出料流股溫度C525.00397.60壓力bar5.005.00氣相分率1.001.00摩爾流量kmol/hr1185.581327.39質(zhì)量流量kg/hr42118.4142118.41體積流量cum/hr15735.2014804.39焓Gcal/hr1.001.00組分流量kg/hrC3H824599.6518101.02C2H6474.97599.59C3H616216.5721780.43H2O0.000.00H2420.13676.88C3H40.000.00C2H4244.47513.60C4H80.000.00N-C4H107.0329.43I-C4H108.5927.35CH4147.01390.12N20.000.00O20.000.00NH30.000.00C3H3N0.000.00C2H3N0.000.00HCN0.000.00CO0.000.00CO20.000.00C3H4O0.000.00C4H5NO0.000.00H2SO40.000.00(NH4)2SO40.000.00質(zhì)量分率C3H80.580.43C2H60.010.01C3H60.390.52H2O0.000.00H20.010.02C3H40.000.00C2H40.010.01C4H80.000.00N-C4H100.000.00I-C4H100.000.00CH40.000.01N20.000.00O20.000.00NH30.000.00C3H3N0.000.00C2H3N0.000.00HCN0.000.00CO0.000.00CO20.000.00C3H4O0.000.00C4H5NO0.000.00H2SO40.000.00(NH4)2SO40.000.00

1.1.3丙烷脫氫反應(yīng)器(R101C)進(jìn)料流股出料流股溫度C525.00459.50壓力bar5.005.00氣相分率1.001.00摩爾流量kmol/hr1327.391407.63質(zhì)量流量kg/hr42118.4142118.41體積流量cum/hr17617.3617148.72焓Gcal/hr5.225.22組分流量kg/hrC3H818101.0213784.53C2H6599.591036.65C3H621780.4325059.64H2O0.000.00H2676.88801.53C3H40.000.00C2H4513.60578.35C4H80.000.00N-C4H1029.4378.47I-C4H1027.3568.91CH4390.12710.34N20.000.00O20.000.00NH30.000.00C3H3N0.000.00C2H3N0.000.00HCN0.000.00CO0.000.00CO20.000.00C3H4O0.000.00C4H5NO0.000.00H2SO40.000.00(NH4)2SO40.000.00質(zhì)量分率C3H80.430.33C2H60.010.03C3H60.520.60H2O0.000.00H20.020.02C3H40.000.00C2H40.010.01C4H80.000.00N-C4H100.000.00I-C4H100.000.00CH40.010.02N20.000.00O20.000.00NH30.000.00C3H3N0.000.00C2H3N0.000.00HCN0.000.00CO0.000.00CO20.000.00C3H4O0.000.00C4H5NO0.000.00H2SO40.000.00(NH4)2SO40.000.00

1.1.4極冷換熱器(E103)進(jìn)料流股進(jìn)料流股進(jìn)料流股出料流股溫度C200.00459.48297.84300.00壓力bar83.365.0083.365.00氣相分率0.001.000.681.00摩爾流量kmol/hr680.001387.75680.001387.75質(zhì)量流量kg/hr12250.3942078.3412250.3942078.34體積流量cum/hr15.2616906.52268.3813226.21焓Gcal/hr-43.985.16-39.070.25組分流量kg/hrC3H80.0013784.530.0013784.53C2H60.001036.650.001036.65C3H60.0025059.640.0025059.64H2O12250.390.0012250.390.00H20.00761.450.00761.45C3H40.000.000.000.00C2H40.00578.350.00578.35C4H80.000.000.000.00N-C4H100.0078.470.0078.47I-C4H100.0068.910.0068.91CH40.00710.340.00710.34N20.000.000.000.00O20.000.000.000.00NH30.000.000.000.00C3H3N0.000.000.000.00C2H3N0.000.000.000.00HCN0.000.000.000.00CO0.000.000.000.00CO20.000.000.000.00C3H4O0.000.000.000.00C4H5NO0.000.000.000.00H2SO40.000.000.000.00(NH4)2SO40.000.000.000.00質(zhì)量分率C3H80.000.330.000.33C2H60.000.020.000.02C3H60.000.600.000.60H2O1.000.001.000.00H20.000.020.000.02C3H40.000.000.000.00C2H40.000.010.000.01C4H80.000.000.000.00N-C4H100.000.000.000.00I-C4H100.000.000.000.00CH40.000.020.000.02N20.000.000.000.00O20.000.000.000.00NH30.000.000.000.00C3H3N0.000.000.000.00C2H3N0.000.000.000.00HCN0.000.000.000.00CO0.000.000.000.00CO20.000.000.000.00C3H4O0.000.000.000.00C4H5NO0.000.000.000.00H2SO40.000.000.000.00(NH4)2SO40.000.000.000.00

1.1.5閃蒸罐(V101)進(jìn)料流股出料流股出料流股溫度C-28.00-28.00-28.00壓力bar25.0025.0025.00氣相分率0.331.000.00摩爾流量kmol/hr1387.75459.49928.26質(zhì)量流量kg/hr42078.343234.3638843.98體積流量cum/hr442.59374.6267.96焓Gcal/hr-11.00-0.99-10.01組分流量kg/hrC3H813784.53477.7913306.75C2H61036.65189.51847.14C3H625059.641096.0523963.59H2O0.000.000.00H2761.45758.802.66C3H40.000.000.00C2H4578.35166.61411.74C4H80.000.000.00N-C4H1078.470.4877.99I-C4H1068.910.6968.21CH4710.34544.44165.90N20.000.000.00O20.000.000.00NH30.000.000.00C3HN0.000.000.00C2H3N0.000.000.00HCN0.000.000.00CO0.000.000.00CO20.000.000.00C3H4O0.000.000.00C4H5NO0.000.000.00H2SO40.000.000.00(NH4)2SO40.000.000.00質(zhì)量分率C3H80.330.150.34C2H60.020.060.02C3H60.600.340.62H2O0.000.000.00H20.020.230.00C3H40.000.000.00C2H40.010.050.01C4H80.000.000.00N-C4H100.000.000.00I-C4H100.000.000.00CH40.020.170.00N20.000.000.00O20.000.000.00NH30.000.000.00C3H3N0.000.000.00C2H3N0.000.000.00HCN0.000.000.00CO0.000.000.00CO20.000.000.00C3H4O0.000.000.00C4H5NO0.000.000.00H2SO40.000.000.00(NH4)2SO40.000.000.00

1.2丙烯精制工段1.2.1脫乙烷塔(T201)進(jìn)料流股出料流股出料流股溫度C-25.0228.05-35.59壓力bar12.0012.0012.00氣相分率0.050.001.00摩爾流量kmol/hr1027.82904.48123.34質(zhì)量流量kg/hr41316.0338654.202661.83體積流量cum/hr159.3477.82184.17焓Gcal/hr-10.89-8.16-1.14組分流量kg/hrC3H813784.5313725.0259.52C2H61032.86178.76854.09C3H625059.6424595.99463.65H2O0.000.000.00H240.600.0040.60C3H40.000.000.00C2H4573.357.06566.29C4H80.000.000.00N-C4H1078.4778.470.00I-C4H1068.9168.910.00CH4677.670.00677.67N20.000.000.00O20.000.000.00NH30.000.000.00C3H3N0.000.000.00C2H3N0.000.000.00HCN0.000.000.00CO0.000.000.00CO20.000.000.00C3H4O0.000.000.00C4H5NO0.000.000.00H2SO40.000.000.00(NH4)2SO40.000.000.00質(zhì)量分率C3H80.330.360.02C2H60.020.000.32C3H60.610.640.17H2O0.000.000.00H20.000.000.02C3H40.000.000.00C2H40.010.000.21C4H80.000.000.00N-C4H100.000.000.00I-C4H100.000.000.00CH40.020.000.25N20.000.000.00O20.000.000.00NH30.000.000.00C3H3N0.000.000.00C2H3N0.000.000.00HCN0.000.000.00CO0.000.000.00CO20.000.000.00C3H4O0.000.000.00C4H5NO0.000.000.00H2SO40.000.000.00(NH4)2SO40.000.000.00

1.2.2脫丁烷塔(T202)進(jìn)料流股出料流股出料流股溫度C8.167.3214.98壓力bar7.007.007.00氣相分率0.500.000.00摩爾流量kmol/hr904.48886.3918.09質(zhì)量流量kg/hr38654.2037830.07824.13體積流量cum/hr1547.7671.431.58焓Gcal/hr-7.09-8.38-0.42組分流量kg/hrC3H813725.0213215.26509.75C2H6178.76178.760.00C3H624595.9924425.10170.89H2O0.000.000.00H20.000.000.00C3H40.000.000.00C2H47.067.060.00C4H80.000.000.00N-C4H1078.470.5877.89I-C4H1068.913.3065.60CH40.000.000.00N20.000.000.00O20.000.000.00NH30.000.000.00C3H3N0.000.000.00C2H3N0.000.000.00HCN0.000.000.00CO0.000.000.00CO20.000.000.00C3H4O0.000.000.00C4H5NO0.000.000.00H2SO40.000.000.00(NH4)2SO40.000.000.00質(zhì)量分率C3H80.360.350.62C2H60.000.000.00C3H60.640.650.21H2O0.000.000.00H20.000.000.00C3H40.000.000.00C2H40.000.000.00C4H80.000.000.00N-C4H100.000.000.09I-C4H100.000.000.08CH40.000.000.00N20.000.000.00O20.000.000.00NH30.000.000.00C3H3N0.000.000.00C2H3N0.000.000.00HCN0.000.000.00CO0.000.000.00CO20.000.000.00C3H4O0.000.000.00C4H5NO0.000.000.00H2SO40.000.000.00(NH4)2SO40.000.000.00

1.2.3丙烯塔(T203)進(jìn)料流股出料流股出料流股溫度C48.6751.3344.92壓力bar19.0019.0019.00氣相分率0.500.000.00摩爾流量kmol/hr886.39443.21443.19質(zhì)量流量kg/hr37830.0719209.8318620.87體積流量cum/hr665.5142.6839.76焓Gcal/hr-5.75-7.210.16組分流量kg/hrC3H813215.2612211.601004.29C2H6178.760.00178.76C3H624425.106994.3417430.77H2O0.000.000.00H20.000.000.00C3H40.000.000.00C2H47.060.007.06C4H80.000.000.00N-C4H100.580.580.00I-C4H103.303.300.00CH40.000.000.00N20.000.000.00O20.000.000.00NH30.000.000.00C3H3N0.000.000.00C2H3N0.000.000.00HCN0.000.000.00CO0.000.000.00CO20.000.000.00C3H4O0.000.000.00C4H5NO0.000.000.00H2SO40.000.000.00(NH4)2SO40.000.000.00質(zhì)量分率C3H80.350.640.05C2H60.000.000.01C3H60.650.360.94H2O0.000.000.00H20.000.000.00C3H40.000.000.00C2H40.000.000.00C4H80.000.000.00N-C4H100.000.000.00I-C4H100.000.000.00CH40.000.000.00N20.000.000.00O20.000.000.00NH30.000.000.00C3H3N0.000.000.00C2H3N0.000.000.00HCN0.000.000.00CO0.000.000.00CO20.000.000.00C3H4O0.000.000.00C4H5NO0.000.000.00H2SO40.000.000.00(NH4)2SO40.000.000.00

1.3丙烯氨氧工段1.3.1氨氧反應(yīng)器(R301)進(jìn)料流股出料流股溫度C430.00430.00壓力bar2.002.00氣相分率1.001.00摩爾流量kmol/hr4807.195000.21質(zhì)量流量kg/hr139205.08139205.08體積流量cum/hr140519.60146161.55焓Gcal/hr13.62-33.25組分流量kg/hrC3H81004.291004.29C2H6178.76178.76C3H617430.771885.28H2O0.0020173.71H20.000.00C3H40.000.00C2H47.067.06C4H80.000.00N-C4H100.000.00I-C4H100.000.00CH40.000.00N286619.3686633.51O226301.098016.32NH37663.751236.69C3H3N0.0018625.37C2H3N0.00511.39HCN0.00349.05CO0.00129.50CO20.00373.30C3H4O0.0080.84C4H5NO0.000.00H2SO40.000.00(NH4)2SO40.000.00質(zhì)量分率C3H80.010.01C2H60.000.00C3H60.130.01H2O0.000.14H20.000.00C3H40.000.00C2H40.000.00C4H80.000.00N-C4H100.000.00I-C4H100.000.00CH40.000.00N20.620.62O20.190.06NH30.060.01C3H3N0.000.13C2H3N0.000.00HCN0.000.00CO0.000.00CO20.000.00C3H4O0.000.00C4H5NO0.000.00H2SO40.000.00(NH4)2SO40.000.00

1.3.2中和反應(yīng)器(R301)進(jìn)料流股進(jìn)料流股出料流股溫度C80.0025.0080.00壓力bar5.001.005.00氣相分率0.850.000.79摩爾流量kmol/hr5000.21280.005207.59質(zhì)量流量kg/hr139205.0811449.41150654.50體積流量cum/hr24987.009.1924318.07焓Gcal/hr-55.98-28.81-77.47組分流量kg/hrC3H81004.290.001004.29C2H6178.760.00178.76C3H61885.280.001885.28H2O20173.713603.0623776.77H20.000.000.00C3H40.000.000.00C2H47.060.007.06C4H80.000.000.00N-C4H100.000.000.00I-C4H100.000.000.00CH40.000.000.00N286633.510.0086633.51O28016.320.008016.32NH31236.690.000.00C3H3N18625.370.0018625.37C2H3N511.390.00511.39HCN349.050.00349.05CO129.500.00129.50CO2373.300.00373.30C3H4O80.840.0080.84C4H5NO0.000.000.00H2SO40.007846.364285.28(NH4)2SO40.000.004797.78質(zhì)量分率C3H80.010.000.01C2H60.000.000.00C3H60.010.000.01H2O0.140.310.16H20.000.000.00C3H40.000.000.00C2H40.000.000.00C4H80.000.000.00N-C4H100.000.000.00I-C4H100.000.000.00CH40.000.000.00N20.620.000.58O20.060.000.05NH30.010.000.00C3H3N0.130.000.12C2H3N0.000.000.00HCN0.000.000.00CO0.000.000.00CO20.000.000.00C3H4O0.000.000.00C4H5NO0.000.000.00H2SO40.000.690.03(NH4)2SO40.000.000.03

1.3.3酸洗塔(T301)進(jìn)料流股進(jìn)料流股出料流股出料流股溫度C25.0080.0078.2072.50壓力bar1.501.501.501.50氣相分率0.000.950.001.00摩爾流量kmol/hr100.005207.59365.364942.23質(zhì)量流量kg/hr1801.53150654.5014367.85138088.17體積流量cum/hr1.8196327.1216.4394692.41焓Gcal/hr-6.82-69.77-27.15-49.45組分流量kg/hrC3H80.001004.290.231004.06C2H60.00178.760.02178.75C3H60.001885.280.381884.90H2O1801.5323776.775060.3620517.94H20.000.000.000.00C3H40.000.000.000.00C2H40.007.060.017.05C4H80.000.000.000.00N-C4H100.000.000.000.00I-C4H100.000.000.000.00CH40.000.000.000.00N20.0086633.516.9486626.57O20.008016.320.758015.58NH30.000.000.000.00C3H3N0.0018625.37200.3018425.07C2H3N0.00511.3912.54498.85HCN0.00349.062.36346.69CO0.00129.510.01129.49CO20.00373.300.24373.07C3H4O0.0080.840.6880.17C4H5NO0.000.000.000.00H2SO40.004285.284285.280.00(NH4)2SO40.004797.784797.780.00質(zhì)量分率C3H80.000.010.000.01C2H60.000.000.000.00C3H60.000.010.000.01H2O1.000.160.350.15H20.000.000.000.00C3H40.000.000.000.00C2H40.000.000.000.00C4H80.000.000.000.00N-C4H100.000.000.000.00I-C4H100.000.000.000.00CH40.000.000.000.00N20.000.580.000.63O20.000.050.000.06NH30.000.000.000.00C3H3N0.000.120.010.13C2H3N0.000.000.000.00HCN0.000.000.000.00CO0.000.000.000.00CO20.000.000.000.00C3H4O0.000.000.000.00C4H5NO0.000.000.000.00H2SO40.000.030.300.00(NH4)2SO40.000.030.330.00

1.4丙烯腈精制工段1.4.1水洗塔(T401)進(jìn)料流股進(jìn)料流股出料流股出料流股溫度C4.0040.004.0729.68壓力bar3.002.502.802.40氣相分率0.000.791.000.00摩爾流量kmol/hr11000.004947.633427.0312520.60質(zhì)量流量kg/hr198183.94138285.7798097.95238371.77體積流量cum/hr195.4740634.2828210.65249.97焓Gcal/hr-754.24-61.16-2.39-813.01組分流量kg/hrC3H80.00982.21976.355.86C2H60.00352.14350.751.39C3H60.002069.302057.9411.37H2O198155.6820350.74179.40218327.01H20.000.000.000.00C3H40.000.000.000.00C2H40.0054.7147.886.84C4H80.000.000.000.00N-C4H100.000.000.000.00I-C4H100.000.000.000.00CH40.000.000.000.00N20.0086612.5485816.25796.29O20.008306.778211.9194.86NH30.000.000.000.00C3H3N0.0018158.110.0018158.11C2H3N28.27496.582.03522.82HCN0.00332.860.00332.86CO0.00173.64171.931.72CO20.00327.22283.5243.70C3H4O0.0068.930.0168.93C4H5NO0.000.000.000.00H2SO40.000.000.000.00(NH4)2SO40.000.000.000.00質(zhì)量分率C3H80.000.010.010.00C2H60.000.000.000.00C3H60.000.010.020.00H2O1.000.150.000.92H20.000.000.000.00C3H40.000.000.000.00C2H40.000.000.000.00C4H80.000.000.000.00N-C4H100.000.000.000.00I-C4H100.000.000.000.00CH40.000.000.000.00N20.000.630.870.00O20.000.060.080.00NH30.000.000.000.00C3H3N0.000.130.000.08C2H3N0.000.000.000.00HCN0.000.000.000.00CO0.000.000.000.00CO20.000.000.000.00C3H4O0.000.000.000.00C4H5NO0.000.000.000.00H2SO40.000.000.000.00(NH4)2SO40.000.000.000.001.4.2萃取精餾塔(T402)進(jìn)料流股進(jìn)料流股進(jìn)料流股出料流股出料流股出料流股溫度C25.0025.0048.0070.60115.2099.60壓力bar1.701.701.201.101.701.58氣相分率0.000.000.001.000.001.00摩爾流量kmol/hr12535.80158.419650.00557.2621752.9434.00質(zhì)量流量kg/hr238822.273029.99173847.4722893.25391885.36921.12體積流量cum/hr391.274.16178.9514477.45434.46668.19焓Gcal/hr-814.52-10.19-654.716.93-1448.75-0.91組分流量kg/hrC3H86.070.030.006.090.000.00C2H60.710.000.000.720.000.00C3H610.480.050.0010.520.000.00H2O218507.662734.71173847.442832.24391885.28372.29H20.000.000.000.000.000.00C3H40.000.000.000.000.000.00C2H40.890.130.001.020.000.00C4H80.000.000.000.000.000.00N-C4H100.000.000.000.000.000.00I-C4H100.000.000.000.000.000.00CH40.000.000.000.000.000.00N2802.098.320.00810.410.000.00O292.171.240.0093.410.000.00NH30.000.000.000.000.000.00C3H3N18425.07214.820.0018603.250.0036.64C2H3N498.890.000.040.010.08498.83HCN346.6948.010.00381.390.0013.31CO1.290.020.001.300.000.00CO250.108.100.0058.200.000.00C3H4O80.1614.570.0094.680.000.06C4H5NO0.000.000.000.000.000.00H2SO40.000.000.000.000.000.00(NH4)2SO40.000.000.000.000.000.00質(zhì)量分率C3H80.000.000.000.000.000.00C2H60.000.000.000.000.000.00C3H60.000.000.000.000.000.00H2O0.920.901.000.121.000.40H20.000.000.000.000.000.00C3H40.000.000.000.000.000.00C2H40.000.000.000.000.000.00C4H80.000.000.000.000.000.00N-C4H100.000.000.000.000.000.00I-C4H100.000.000.000.000.000.00CH40.000.000.000.000.000.00N20.000.000.000.040.000.00O20.000.000.000.000.000.00NH30.000.000.000.000.000.00C3H3N0.080.070.000.810.000.04C2H3N0.000.000.000.000.000.54HCN0.000.020.000.020.000.01CO0.000.000.000.000.000.00CO20.000.000.000.000.000.00C3H4O0.000.010.000.000.000.00C4H5NO0.000.000.000.000.000.00H2SO40.000.000.000.000.000.00(NH4)2SO40.000.000.000.000.000.00

1.4.3共沸精餾塔(T403)進(jìn)料流股進(jìn)料流股出料流股出料流股出料流股出料流股溫度C55.0040.0010.0072.9010.0058.80壓力bar0.901.010.750.900.750.80氣相分率0.010.001.000.000.001.00摩爾流量kmol/hr391.51342.471.91349.9812.09370.00質(zhì)量流量kg/hr19406.4114644.5559.1418401.89364.6015225.34體積流量cum/hr138.8619.0259.8424.780.5012708.61焓Gcal/hr11.133.810.0212.510.225.23組分流量kg/hrC3H84.8010.082.140.001.5311.21C2H60.310.330.140.000.020.48C3H67.8915.643.670.002.1517.72H2O512.191055.890.1587.084.781476.07H20.000.000.000.000.000.00C3H40.000.000.000.000.000.00C2H40.340.350.160.000.020.52C4H80.000.000.000.000.000.00N-C4H100.000.000.000.000.000.00I-C4H100.000.000.000.000.000.00CH40.000.000.000.000.000.00N225.503.667.290.000.0521.83O23.770.651.100.000.013.31NH30.000.000.000.000.000.00C3H3N18381.3810221.300.1418309.9911.0710281.48C2H3N0.010.000.000.010.000.00HCN356.951608.8232.170.00280.291653.30CO0.050.010.010.000.000.04CO220.9122.049.590.001.1432.22C3H4O92.321705.782.584.8163.551727.16C4H5NO0.000.000.000.000.000.00H2SO40.000.000.000.000.000.00(NH4)2SO40.000.000.000.000.000.00質(zhì)量分率C3H80.000.000.040.000.000.00C2H60.000.000.000.000.000.00C3H60.000.000.060.000.010.00H2O0.030.070.000.010.010.10H20.000.000.000.000.000.00C3H40.000.000.000.000.000.00C2H40.000.000.000.000.000.00C4H80.000.000.000.000.000.00N-C4H100.000.000.000.000.000.00I-C4H100.000.000.000.000.000.00CH40.000.000.000.000.000.00N20.000.000.120.000.000.00O20.000.000.020.000.000.00NH30.000.000.000.000.000.00C3H3N0.950.700.001.000.030.68C2H3N0.000.000.000.000.000.00HCN0.020.110.540.000.770.11CO0.000.000.000.000.000.00CO20.000.000.160.000.000.00C3H4O0.010.120.040.000.170.11C4H5NO0.000.000.000.000.000.00H2SO40.000.000.000.000.000.00(NH4)2SO40.000.000.000.000.000.001.4.4三相分離罐(V401)進(jìn)料流股出料流股出料流股出料流股溫度C32.005.005.005.00壓力bar1.021.801.801.80氣相分率0.081.000.000.00摩爾流量kmol/hr557.2632.63391.51133.12質(zhì)量流量kg/hr22893.25958.8219406.412528.02體積流量cum/hr1097.72419.2623.742.59焓Gcal/hr2.46-0.0410.64-8.70組分流量kg/hrC3H86.091.294.800.01C2H60.720.410.310.00C3H610.522.617.890.02H2O2832.242.77512.192317.28H20.000.000.000.00C3H40.000.000.000.00C2H41.020.570.340.11C4H80.000.000.000.00N-C4H100.000.000.000.00I-C4H100.000.000.000.00CH40.000.000.000.00N2810.41776.8425.508.07O293.4188.453.771.19NH30.000.000.000.00C3H3N18603.2547.6818381.38174.19C2H3N0.010.000.010.00HCN381.395.55356.9518.90CO1.301.250.050.01CO258.2030.6720.916.62C3H4O94.680.7492.321.61C4H5NO0.000.000.000.00H2SO40.000.000.000.00(NH4)2SO40.000.000.000.00質(zhì)量分率C3H80.000.000.000.00C2H60.000.000.000.00C3H60.000.000.000.00H2O0.120.000.030.92H20.000.000.000.00C3H40.000.000.000.00C2H40.000.000.000.00C4H80.000.000.000.00N-C4H100.000.000.000.00I-C4H100.000.000.000.00CH40.000.000.000.00N20.040.810.000.00O20.000.090.000.00NH30.000.000.000.00C3H3N0.810.050.950.07C2H3N0.000.000.000.00HCN0.020.010.020.01CO0.000.000.000.00CO20.000.030.000.00C3H4O0.000.000.010.00C4H5NO0.000.000.000.00H2SO40.000.000.000.00(NH4)2SO40.000.000.000.00

1.4.5三相分離罐(V402)進(jìn)料流股出料流股出料流股出料流股溫度C40.0040.0040.0040.00壓力bar1.011.011.011.01氣相分率0.011.000.000.00摩爾流量kmol/hr370.002.25342.4725.29質(zhì)量流量kg/hr15225.3478.7914644.55501.94體積流量cum/hr73.3557.8619.020.56焓Gcal/hr2.310.003.81-1.53組分流量kg/hrC3H811.211.1110.080.02C2H60.480.150.330.00C3H617.722.0515.640.03H2O1476.072.781055.89417.40H20.000.000.000.00C3H40.000.000.000.00C2H40.520.140.350.02C4H80.000.000.000.00N-C4H100.000.000.000.00I-C4H100.000.000.000.00CH40.000.000.000.00N221.8317.923.660.25O23.312.610.650.04NH30.000.000.000.00C3H3N10281.4819.5510221.3040.63C2H3N0.000.000.000.00HCN1653.3015.361608.8229.11CO0.040.030.010.00CO232.228.7022.041.48C3H4O1727.168.391705.7812.96C4H5NO0.000.000.000.00H2SO40.000.000.000.00(NH4)2SO40.000.000.000.00質(zhì)量分率C3H80.000.010.000.00C2H60.000.000.000.00C3H60.000.030.000.00H2O0.100.040.070.83H20.000.000.000.00C3H40.000.000.000.00C2H40.000.000.000.00C4H80.000.000.000.00N-C4H100.000.000.000.00I-C4H100.000.000.000.00CH40.000.000.000.00N20.000.230.000.00O20.000.030.000.00NH30.000.000.000.00C3H3N0.680.250.700.08C2H3N0.000.000.000.00HCN0.110.200.110.06CO0.000.000.000.00CO20.000.110.000.00C3H4O0.110.110.120.03C4H5NO0.000.000.000.00H2SO40.000.000.000.00(NH4)2SO40.000.000.000.00

1.4.6丙烯腈精制塔(T404)進(jìn)料流股出料流股出料流股出料流股溫度C72.9052.1053.3042.60壓力bar0.900.440.450.35氣相分率0.001.000.000.00摩爾流量kmol/hr349.98338.0011.480.50質(zhì)量流量kg/hr18401.8917768.32609.0224.55體積流量cum/hr24.7820979.370.790.03焓Gcal/hr12.5114.480.420.01組分流量kg/hrC3H80.000.000.000.00C2H60.000.000.000.00C3H60.000.000.000.00H2O87.0886.050.001.02H20.000.000.000.00C3H40.000.000.000.00C2H40.000.000.000.00C4H80.000.000.000.00N-C4H100.000.000.000.00I-C4H100.000.000.000.00CH40.000.000.000.00N20.000.000.000.00O20.000.000.000.00NH30.000.000.000.00C3H3N18309.9917677.49609.0223.47C2H3N0.010.010.000.00HCN0.000.000.000.00CO0.000.000.000.00CO20.000.000.000.00C3H4O4.814.760.000.05C4H5NO0.000.000.000.00H2SO40.000.000.000.00(NH4)2SO40.000.000.000.00質(zhì)量分率C3H80.000.000.000.00C2H60.000.000.000.00C3H60.000.000.000.00H2O0.010.010.000.04H20.000.000.000.00C3H40.000.000.000.00C2H40.000.000.000.00C4H80.000.000.000.00N-C4H100.000.000.000.00I-C4H100.000.000.000.00CH40.000.000.000.00N20.000.000.000.00O20.000.000.000.00NH30.000.000.000.00C3H3N1.001.001.000.96C2H3N0.000.000.000.00HCN0.000.000.000.00CO0.000.000.000.00CO20.000.000.000.00C3H4O0.000.000.000.00C4H5NO0.000.000.000.00H2SO40.000.000.000.00(NH4)2SO40.000.000.000.00

1.4.7乙腈初分塔(T405)進(jìn)料流股出料流股出料流股溫度C45.0043.8048.40壓力bar1.000.300.30氣相分率0.000.000.00摩爾流量kmol/hr34.0014.0119.99質(zhì)量流量kg/hr921.12509.08412.04體積流量cum/hr1.230.690.49焓Gcal/hr-1.24-0.09-1.15組分流量kg/hrC3H80.000.000.00C2H60.000.000.00C3H60.000.000.00H2O372.2958.12314.17H20.000.000.00C3H40.000.000.00C2H40.000.000.00C4H80.000.000.00N-C4H100.000.000.00I-C4H100.000.000.00CH40.000.000.00N20.000.000.00O20.000.000.00NH30.000.000.00C3H3N36.6436.640.00C2H3N498.83414.2684.57HCN13.310.0013.31CO0.000.000.00CO20.000.000.00C3H4O0.060.060.00C4H5NO0.000.000.00H2SO40.000.000.00(NH4)2SO40.000.000.00質(zhì)量分率C3H80.000.000.00C2H60.000.000.00C3H60.000.000.00H2O0.400.110.76H20.000.000.00C3H40.000.000.00C2H40.000.000.00C4H80.000.000.00N-C4H100.000.000.00I-C4H100.000.000.00CH40.000.000.00N20.000.000.00O20.000.000.00NH30.000.000.00C3H3N0.040.070.00C2H3N0.540.810.21HCN0.010.000.03CO0.000.000.00CO20.000.000.00C3H4O0.000.000.00C4H5NO0.000.000.00H2SO40.000.000.00(NH4)2SO40.000.000.00

1.4.8乙腈精制塔(T406)項(xiàng)目進(jìn)料流股進(jìn)料流股進(jìn)料流股出料流股出料流股溫度℃158.00175.60157.60159.00175.60壓力bar10.0010.1010.0010.0010.10氣相分率0.001.000.001.000.00摩爾流量kmol/hr14.0187.7562.5070.3193.94質(zhì)量流量kg/hr509.083611.512032.982287.103866.46體積流量cum/hr0.86324.183.39252.596.69焓Gcal/hr-0.051.76-1.05-0.691.35組分流量kg/hrC3H80.000.000.000.000.00C2H60.000.000.000.000.00C3H60.000.000.000.000.00H2O58.120.00464.98523.100.00H20.000.000.000.000.00C3H40.000.000.000.000.00C2H40.000.000.000.000.00C4H80.000.000.000.000.00N-C4H100.000.000.000.000.00I-C4H100.000.000.000.000.00CH40.000.000.000.000.00N20.000.000.000.000.00O20.000.000.000.000.00NH30.000.000.000.000.00C3H3N36.6441.37273.23307.3943.87C2H3N414.263570.141294.301456.093822.58HCN0.000.000.000.000.00CO0.000.000.000.000.00CO20.000.000.000.000.00C3H4O0.060.000.460.520.00C4H5NO0.000.000.000.000.00H2SO40.000.000.000.000.00(NH4)2SO40.000.000.000.000.00質(zhì)量分率C3H80.000.000.000.000.00C2H60.000.000.000.000.00C3H60.000.000.000.000.00H2O0.110.000.230.230.00H20.000.000.000.000.00C3H40.000.000.000.000.00C2H40.000.000.000.000.00C4H80.000.000.000.000.00N-C4H100.000.000.000.000.00I-C4H100.000.000.000.000.00CH40.000.000.000.000.00N20.000.000.000.000.00O20.000.000.000.000.00NH30.000.000.000.000.00C3H3N0.070.010.130.130.01C2H3N0.810.990.640.640.99HCN0.000.000.000.000.00CO0.000.000.000.000.00CO20.000.000.000.000.00C3H4O0.000.000.000.000.00C4H5NO0.000.000.000.000.00H2SO40.000.000.000.000.00(NH4)2SO40.000.000.000.000.00

第二章能量衡算2.1丙烷脫氫工段2.1.1丙烷脫氫反應(yīng)器(R101A)項(xiàng)目進(jìn)料流股出料流股溫度C525.00316.20壓力bar5.004.60氣相分率1.001.00摩爾流量kmol/hr968.211185.58焓Gcal/hr-5.65-5.65W總Gcal/hr02.1.2丙烷脫氫反應(yīng)器(R101B)項(xiàng)目進(jìn)料流股出料流股溫度C525.00397.60壓力bar5.005.00氣相分率1.001.00摩爾流量kmol/hr1185.581327.39焓Gcal/hr1.001.00W總Gcal/hr02.1.3丙烷脫氫反應(yīng)器(R101C)項(xiàng)目進(jìn)料流股出料流股溫度C525.00459.50壓力bar5.005.00氣相分率1.001.00摩爾流量kmol/hr1327.391407.63焓Gcal/hr5.225.22W總Gcal/hr02.1.4急冷換熱器(E103)項(xiàng)目進(jìn)料流股進(jìn)料流股出料流股出料流股溫度C200.00459.50297.80300.00壓力bar83.365.0083.365.00氣相分率0.001.000.681.00摩爾流量kmol/hr680.001387.75680.001387.75焓Gcal/hr-43.985.16-39.080.252.1.5閃蒸罐(V101)項(xiàng)目進(jìn)料流股出料流股出料流股溫度C-28.00-28.00-28.00壓力bar25.0025.0025.00氣相分率0.331.000.00摩爾流量kmol/hr1387.75459.49928.26焓Gcal/hr-11.00-0.99-10.012.2丙烯精制工段2.2.1脫乙烷塔(T201)項(xiàng)目進(jìn)料流股出料流股出料流股溫度C-25.0028.00-35.60壓力bar12.0012.0012.00氣相分率0.050.001.00摩爾流量kmol/hr1027.82904.48123.34焓Gcal/hr-10.89-8.16-1.14再沸器負(fù)荷Gcal/hr2.37冷凝器負(fù)荷Gcal/hr-0.782.2.2脫丁烷塔(T202)項(xiàng)目進(jìn)料流股出料流股出料流股溫度C8.207.3015.00壓力bar7.007.007.00氣相分率0.500.000.00摩爾流量kmol/hr904.48886.3918.09焓Gcal/hr-7.09-8.38-0.42再沸器負(fù)荷Gcal/hr3.02冷凝器負(fù)荷Gcal/hr-4.722.2.3丙烯塔(T203)項(xiàng)目進(jìn)料流股出料流股出料流股溫度C48.7051.3044.90壓力bar19.0019.0019.00氣相分率0.500.000.00摩爾流量kmol/hr886.39443.21443.19焓Gcal/hr-5.75-7.210.16再沸器負(fù)荷Gcal/hr19.62冷凝器負(fù)荷Gcal/hr-20.912.3丙烯氨氧工段2.3.1空氣壓縮機(jī)(C301)進(jìn)料流股出料流股溫度C25.00176.20壓力bar1.003.00氣相分率1.001.00摩爾流量kmol/hr3914.003914.00焓Gcal/hr0.004.15W總Gcal/h

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