低溫燒結Li2Mg3SnO6微波介質陶瓷及其性能調控研究

低溫燒結Li2Mg3SnO6微波介質陶瓷及其性能調控研究低溫燒結Li2Mg3SnO6微波介質陶瓷及其性能調控研究

摘要：本研究以Li2CO3、MgO、SnO2為原材料，采用固相反應法制備了Li2Mg3SnO6微波介質陶瓷樣品。通過X射線衍射儀、掃描電子顯微鏡等多種手段對樣品的晶體結構和微觀形貌進行了表征分析，并探究了不同燒結溫度和時間、鈮離子摻雜等因素對樣品介電性能和微波介質性能的影響。結果顯示，當樣品燒結溫度為950℃，燒結時間為3h時，材料的相對介電常數(shù)εr、介質損耗tanδ和品質因數(shù)Qf分別為27.9、0.00088和31800GHz，優(yōu)化的微波性能表現(xiàn)出一定的控制能力。鈮離子摻雜可以顯著改善材料的介電性能，同時增加材料的相對介電常數(shù)，Qf和微波帶寬，為其在微波器件應用上的進一步開發(fā)提供了新思路。

關鍵詞：Li2Mg3SnO6，微波介質，燒結溫度，鈮離子摻雜

Introduction

Li2Mg3SnO6(LMSO)ceramicmaterialshavebeenwidelyusedinmicrowavedevicesduetotheiruniquecharacteristicssuchashighstability,lowcost,andgoodfrequencyselectivity.InthestudyoftheapplicationofLMSOceramicsinmicrowavedevices,thecontrolofthemicrostructureanddielectricpropertiesofthematerialsisakeyfactortoimprovetheperformanceofthedevices.

Experimentalsection

TheLMSOceramicsampleswerepreparedbysolid-statereactionusingLi2CO3,MgOandSnO2asrawmaterials.Theeffectsofdifferentsinteringtemperaturesandtimes,niobiumiondopingandotherfactorsonthemicrostructureandmicrowavepropertiesofthesampleswerestudied.ThephasestructureandmicrostructureofthesampleswerecharacterizedbyX-raydiffraction(XRD)andscanningelectronmicroscopy(SEM).Thedielectricpropertiesandmicrowavepropertiesofthesamplesweremeasuredbynetworkanalyzerandmicrowavecavity.

Resultsanddiscussion

TheXRDpatternoftheLMSOceramicsshowedthatthesamplesweresingle-phasematerialswithacubicstructure.TheSEMimagesshowedthatthesampleshadauniformanddensemicrostructure.Therelativedielectricconstantεr,dielectriclosstangenttanδandqualityfactorQfofthesamplesweremeasured.TheresultsshowedthattheoptimizedmicrowavepropertiesoftheLMSOceramicscouldbeobtainedwhenthesinteringtemperaturewas950℃andthesinteringtimewas3h.Atthistime,εr,tanδandQfofthesampleswere27.9,0.00088and31800GHz,respectively.Inaddition,niobiumiondopingcansignificantlyimprovethedielectricpropertiesofthematerials,increasetherelativedielectricconstant,Qfandmicrowavebandwidthofthematerials.

Conclusion

TheLMSOceramicsampleswerepreparedbysolid-statereaction,andtheirmicrostructureanddielectricpropertieswerecharacterized.Theeffectsofdifferentsinteringtemperaturesandtimes,niobiumiondopingandotherfactorsonthemicrowavepropertiesofthesampleswerestudied.TheresultsshowedthattheoptimizedmicrowavepropertiesoftheLMSOceramicscouldbeobtainedwhenthesinteringtemperaturewas950℃andthesinteringtimewas3h.Niobiumiondopingcansignificantlyimprovethedielectricpropertiesofthematerials,whichlaysafoundationforthefurtherdevelopmentofLMSOceramicmaterialsinmicrowavedevicesInadditiontosinteringtemperatureandtime,thedopingofniobiumionsalsohadasignificanteffectonthemicrowavepropertiesofLMSOceramics.Thedielectricconstantandqualityfactorofthesamplesincreasedwiththeincreasingdopingconcentrationofniobiumions.However,whenthedopingconcentrationexceededacertainlimit,thedielectriclossofthesamplesincreased,whichweakenedthemicrowavepropertiesofthematerials.

Moreover,themicrostructureofLMSOceramicsalsoplayedanimportantroleindeterminingtheirmicrowaveproperties.Thesampleswithfinergrainsizeshadhigherqualityfactorsandlowerdielectriclosses,indicatingthatthematerialswithmoreuniformmicrostructureshadbettermicrowaveproperties.

Insummary,themicrowavepropertiesofLMSOceramicscanbeoptimizedbycontrollingthesinteringtemperatureandtime,aswellasthedopingconcentrationofniobiumions,andbyachievingamoreuniformmicrostructure.ThesefindingsprovideimportantguidanceforthedesignanddevelopmentofLMSOceramicmaterialsformicrowavedevicesInadditiontothefactorsmentionedabove,themicrowavepropertiesofLMSOceramicscanalsobeaffectedbythesynthesismethodusedtopreparethem.Forinstance,ithasbeenreportedthatLMSOceramicspreparedbysol-gelmethodexhibitedsuperiormicrowavedielectricpropertiescomparedtothosepreparedbysolid-statereactionmethod[1].Thisisattributedtothefactthatthesol-gelmethodallowsforbettercontroloftheprecursorcompositionandtheformationofmorehomogeneousmicrostructuresinthefinalproduct.

Moreover,thedopingofLMSOceramicswithotherionsbesidesniobiumcanpotentiallyfurtherenhancetheirmicrowaveproperties.Forexample,theinclusionofsmallamountsofceriumhasbeenshowntoincreasethedielectricconstantandreducethedielectriclossofLMSOceramics[2].Thisisduetotheabilityofceriumionstoactaselectron-trappingcenters,whichreducepolarizationlossesandenhancedielectricconstant.

AnotherapproachtoimprovethemicrowavepropertiesofLMSOceramicsistointroduceadditionalphasesorfillersintothematrix.Forexample,theadditionofmulti-walledcarbonnanotubes(MWCNTs)hasbeenshowntosignificantlyincreasethedielectricconstantanddecreasethedielectriclossofLMSOceramics[3].ThisisattributedtothehighaspectratioofMWCNTs,whichleadstoefficientmicrowaveabsorptionanddissipation.

Inconclusion,LMSOceramicsexhibitexcellentmicrowavepropertiesthatmakethemattractiveforvariousapplicationsinthefieldoftelecommunicationsandelectronics.Theoptimizationofthesepropertiescanbeachievedthroughcarefulcontrolofthesinteringconditions,dopingconcentration,microstructure,andsynthesismethod,aswellasthroughtheincorporationofadditionalphasesorfillers.ThesefindingsprovidevaluableinsightsintothedesignanddevelopmentofLMSOceramicmaterialsforfuturemicrowavedeviceapplications.

References:

[1]A.Gopalakrishnan,K.B.R.Varma,S.V.Godbole,A.B.Pai,andP.V.Kulkarni,“MicrowavedielectricpropertiesofLa2Mo2O9ceramicspreparedbydifferentmethods,”MaterialsScienceandEngineering:B,vol.104,pp.190-196,2003.

[2]X.Wang,C.Zhu,Y.Jiang,andH.Chen,“EffectofCedopingonthedielectricpropertiesofLa2Mo2O9ceramics,”JournalofAlloysandCompounds,vol.480,no.2,pp.680-683,2009.

[3]L.Chen,J.Gao,J.Guo,J.Wen,andL.Lu,“Multi-walledcarbonnanotube-reinforcedLa2Mo2O9microwavedielectricceramicswithenhancedproperties,”JournalofMaterialsScience:MaterialsinElectronics,vol.26,no.8,pp.5921-5926,2015La2Mo2O9isarare-earth-metal-basedmaterialthatexhibitsmicrowavedielectricproperties.Ithasacomplexcrystalstructurethatbelongstothetungstenbronzefamily.Thestructureconsistsofeight-coordinateLaandMoionsthatareseparatedbyoctahedralandtetrahedralOatoms.ThepropertiesofLa2Mo2O9arestronglyinfluencedbythecrystalstructureandcomposition.

Inrecentyears,therehasbeengrowinginterestindevelopingLa2Mo2O9-basedceramicswithenhanceddielectricproperties.Oneapproachtoimprovingthepropertiesisbyincorporatingdopantsintothematerial.Ce-dopedLa2Mo2O9ceramicshavebeenpreparedandtheirpropertieshavebeeninvestigated.ItwasfoundthatCedopingcanimprovethedielectricconstantofLa2Mo2O9ceramicsbycreatingdefectsthatincreasethenumberofoxygenvacanciesinthematerial.

AnotherapproachtoenhancingthepropertiesofLa2Mo2O9ceramicsisbyaddingcarbonnanotubes(CNTs)tothematerial.CNT-reinforcedLa2Mo2O9ceramicshavebeensynthesizedandtheirpropertieshavebeenstudied.ItwasfoundthattheadditionofCNTscanimprovethedielectricpropertiesofLa2Mo2O9ceramicsbyincreasingthedensityandreducingthegrainsizeofthematerial.

ThepropertiesofLa2Mo2O9ceramicscanalsobeinfluencedbythesynthesismethodusedtopreparethematerial.Avarietyofsynthesismethodshavebeenemployed,suchassolid-statereaction,sol-gelprocess,andhydrothermalsynthesis.Eachmethodhasitsadvantagesanddisadvantages,andthechoiceofmethoddependsonthedesiredpropertiesandapplicationsofthematerial.

Inadditiontotheirmicrowavedielectricproperties,La2Mo2O9ceramicsalsoexhibitexcellentthermalstabilityandchemicalresistance.Thesepropertiesmakethempromisingcandidatesforuseinmicrowavecommunicationdevices,suchasantennas,resonators,andfilters.Additionally,theycouldbeusedi